Process for converting phenolic compounds into aromatic hydrocarbons
AssigneeStudiengesellschaft Kohle mbH
InventorsRoberto Rinaldi, Xingyu Wang
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Abstract
The present invention discloses a process for the conversion of phenolics into aromatic hydrocarbons. In more detail, the present invention refers to a process for the selective hydrodeoxygenation of phenolic feeds into aromatic hydrocarbons, such as benzene, toluene, alkylbenzenes and others. The selective catalytic hydrodeoxygenation is performed in absence of external supply of molecular hydrogen.
Claims17
A process for the selective hydrodeoxygenation of phenolic feeds into aromatic hydrocarbons by subjecting the phenolic feeds to a one-pot hydrotreatment in absence of external supply of molecular hydrogen, where the hydrotreatment comprises a step of contacting the phenolic feeds with a transition metal catalyst and a solid acid catalyst in the presence of a hydrogen donor (H-donor) at an autogenous pressure of 5 to 150 bar and at a temperature of 60° C. to 280° C. in a first reactor to produce a reaction mixture comprising reaction products and recovering the reaction products from the reaction mixture, wherein the H-donor is selected from secondary alcohols having 3 to 8 carbon atoms, cyclic alkenes having 3 to 10 carbon atoms, polyols comprising 2 to 9 carbon atoms, saccharides, formic acid or mixtures thereof, wherein the phenolic feeds are selected from lignin, phenolics derived from lignocellulosic materials selected from wood, switchgrass, sugarcane bagasse, crop residues and mixtures thereof, and bio-oils obtained by the pyrolysis of lignocellulosic materials.
A process for the selective hydrodeoxygenation of phenolic feeds into aromatic hydrocarbons by subjecting the phenolic feeds to a one-pot hydrotreatment in absence of external supply of molecular hydrogen, where the hydrotreatment comprises a step of contacting the phenolic feeds with a transition metal catalyst and a solid acid catalyst in the presence of a hydrogen donor (H-donor) at an autogenous pressure of 5 to 150 bar and at a temperature of 50° C. to 300° C. in a first reactor to yield oxidized H-donor, separating the oxidized H-donor from the reaction mixture and transferring the oxidized H-donor into a second reactor, contacting said oxidized H-donor with molecular hydrogen in the presence of a hydrogenation catalyst in said second reactor to yield a regenerated H-donor, and transferring said regenerated H-donor into the first reactor, which operates in absence of external supply of molecular hydrogen, wherein the H-donor is selected from secondary alcohols having 3 to 8 carbon atoms, cyclic alkenes having 3 to 10 carbon atoms, polyols comprising 2 to 9 carbon atoms, saccharides, formic acid or mixtures thereof, wherein the phenolic feeds are selected from lignin, phenolics derived from lignocellulosic materials selected from wood, switchgrass, sugarcane bagasse, crop residues and mixtures thereof, and bio-oils obtained by the pyrolysis of lignocellulosic materials.
Dependencies are inferred from the claim text.