Method for producing foamed molded bodies
AssigneeCovestro Deutschland AG
InventorsReinhard Albers, Hans-Guido Wirtz, Michael Loof, Andreas Pielasch
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Abstract
The invention relates to a method for producing foamed molded bodies comprising the steps of A) providing a mold, and B) introducing a foam-forming reaction mixture into the mold under variable pressure of injection, wherein the method is characterized in that the foam-forming reaction mixture has a fiber time of ≧20 s to ≦60 s.
Claims23
A method for producing foamed molded bodies comprising the steps of
- A) providing a mold, and
- B) introducing a foam-forming reaction mixture from a mixing head into the mold under variable pressure of injection, wherein the foam-forming reaction mixture exits the mixing head at a speed which decreases over time from an initial exit speed to a decreased exit speed, wherein the initial exit speed and the decreased exit speed are each in the range of >1 m/s to <5 m/s,
- and
- wherein the foam-forming reaction mixture has a fiber time at 20° C. of ≧20 s to ≦60 s
- wherein the foam-forming reaction mixture comprises an emulsion, and wherein the emulsion contains the following constituents:
- (I) an isocyanate-reactive composition A containing a polyol mixture A1 of at least three polyols A1a, A1 and A1e as continuous phase
- and
- (II) at least one physical blowing agent T as disperse phase,
- wherein:
- (i) A1a is a polyether polyol having a hydroxyl number of 15 mg KOH/g to 550 mg KOH/g and having a functionality of 1.5 to 6.0, obtained by addition reaction of an epoxide onto one or more starter compounds selected from the group consisting of carbohydrates and di- or higher-functional alcohols;
- (ii) A1b is a polyether polyol having a hydroxyl number of 100 mg KOH/g to 550 mg KOH/g and having a functionality of 1.5 to 5.0, obtained by addition reaction of an epoxide onto an aromatic amine;
- and
- (iii) A1e is a polyester polyether polyol having a hydroxyl number of 100 mg KOH/g to 450 mg KOH/g and having a functionality of 1.5 to 3.5, obtained by addition reaction of an epoxide onto the esterification product of an aromatic dicarboxylic acid derivative and a di- or more highly functional alcohol.
The method as claimed in 1, wherein the injection pressure is reduced over time in step B).
The method as claimed in 7, wherein the injection pressure is reduced over time in step B) in a very substantially linear manner.
Dependencies are inferred from the claim text.