A fused amine compound including a furan ring or a thiophene ring and an organic electroluminescence device employing the amine compound. The organic electroluminescence device includes a cathode, an anode, and one or more organic thin film layers which are disposed between the cathode and the anode. The organic thin film layers include a light emitting layer and at least one layer of the organic thin film layers includes at least one amine compound.
Drawings
Claims25
An amine compound represented by formula (1):
BA)n (1)
wherein:
n is an integer of 2 to 4;
B represents a structure represented by formula (2) shown below;
A represents a group represented by formula (4) shown below;
and
two or more groups A may be the same or different:
wherein two adjacent groups in at least one pair of R1 and R2, R2 and R3, R3 and R4, R5 and R6, R6 and R7, and R7 and R8 are bonded to each other to form a divalent group represented by formula (3):
n group of R1 to R8 and Ra to Rd represents a single bond which is bonded to the group A represented by formula (4);
each of R1 to R8 which does not form the divalent group and does not represent the single bond bonded to the group A represented by formula (4), and each of Ra to Rd which does not represent the single bond bonded to the group A represented by formula (4) are independently selected from a hydrogen atom, a fluorine atom, a cyano group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 ring carbon atoms, a substituted or unsubstituted alkylthio group having 1 to 20 carbon atoms, a substituted or unsubstituted arylthio group having 6 to 30 ring carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 50 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 50 ring carbon atoms, and a substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms;
and
X represents an oxygen atom or a sulfur atom;
and
wherein:
each of Ar1 and Ar2 independently represents a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms or a substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms;
each of L, L1 and L2 independently represents a single bond, an arylene group having 6 to 30 ring carbon atoms, a heteroarylene group having 5 to 30 ring atoms, or a divalent linking group formed by bonding 2 to 4 groups selected from the arylene groups and the heteroarylene groups;
provided that when Ar1 and Ar2 both represent substituted or unsubstituted aryl groups each having 6 to 30 ring carbon atoms, L represents a single bond.
18 Sep 2035Estimated · howhide20 years from earliest known nonprovisional domestic filing plus recorded patent term adjustment, including 631 days of adjustment. Maintenance-fee lapses, terminal disclaimers and statutory extensions have not been checked. The continuity chain may be incomplete; this is not an enforceability determination.
Ortho- or peri-condensed with carbocyclic rings or ring systems: dibenzofurans; Hydrogenated dibenzofurans
Life of this patent
About 8 years 11 months of term left · ends 18 Sep 2035 (estimated)
Priority, Japan26 Dec 2012
Filed26 Dec 2013
Granted5 Sep 2017
Today12 Oct 2026
Term ends18 Sep 2035
Priority, Japan26 Dec 2012
Granted5 Sep 2017
Term ends18 Sep 2035
Priority claimedJP 2012-282908
Application filedUS 14/140,806
Assigned to Idemitsu Kosan Co., Ltd.assignment of assignor's interest
PublishedUS 2014/0183500 A1
GrantedUS 9,755,156 B2
TodayWithin its term
Term endsEstimated, includes 631 days of adjustment
Description14,232 words
Summary962 words
#This application is based upon and claims the benefit of priority from the prior Japanese Patent Application No. 2012-282908, filed on Dec. 26, 2012; the entire contents of which are incorporated herein by reference.
#In an embodiment, the present invention relates to an oxygen-containing fused ring amine compound and a sulfur-containing fused ring amine compound, more in detail, an amine compound having a fused ring comprising a furan ring or a thiophene ring. In another embodiment, the present invention relates to an organic electroluminescence device employing the oxygen-containing fused ring amine compound and/or the sulfur-containing fused ring amine compound.
#Generally, an organic electroluminescence device (organic EL device) is composed of an anode, a cathode, and one or more organic thin film layers sandwiched between the anode and the cathode. When a voltage is applied between the electrodes, electrons are injected from a cathode and holes are injected from an anode into a light emitting region. The injected electrons recombine with the injected holes in the light emitting region to form excited states. When the excited states return to the ground state, the energy is released as light.
Brief description of the drawings1 figure
#FIG. 1 is a schematic cross-sectional view of an example of the organic electroluminescence device in an aspect of the invention.
Detailed description13,249 words
#The carbon number of a to b in the expression of “a substituted or unsubstituted X group having a to b carbon atoms” referred to herein is the carbon number of the unsubstituted X group and does not include the carbon atom or atoms of the optional substituent of the X group.
#The definition of hydrogen atom includes isotopes different in the neutron numbers, i.e., light hydrogen (protium), heavy hydrogen (deuterium), and tritium.
#Examples of the optional substituent when saying “substituted or unsubstituted” herein include an alkyl group having 1 to 50, preferably 1 to 10, more preferably 1 to 5 carbon atoms; a cycloalkyl group having 3 to 50, preferably 3 to 6, more preferably 5 or 6 ring carbon atoms; an aryl group having 6 to 50, preferably 6 to 24, more preferably 6 to 12 ring carbon atoms; an aralkyl group composed of an aryl group having 6 to 50, preferably 6 to 24, more preferably 6 to 12 ring carbon atoms and an alkyl portion having 1 to 50, preferably 1 to 10, more preferably 1 to 5 carbon atoms; an amino group; a mono- or dialkylamino group having an alkyl group having 1 to 50, preferably 1 to 10, more preferably 1 to 5 carbon atoms; a mono- or diarylamino group having an aryl group having 6 to 50, preferably 6 to 24, more preferably 6 to 12 ring carbon atoms; an alkoxy group having an alkyl group having 1 to 50, preferably 1 to 10, more preferably 1 to 5 carbon atoms; an aryloxy group having an aryl group having 6 to 50, preferably 6 to 24, more preferably 6 to 12 ring carbon atoms; a mono-, di- or tri-substituted silyl group having a group selected from an alkyl group having 1 to 50, preferably 1 to 10, more preferably 1 to 5 carbon atoms and an aryl group having 6 to 50, preferably 6 to 24, more preferably 6 to 12 ring carbon atoms; a heterocyclic group having 5 to 50, preferably 5 to 24, more preferably 5 to 12 ring atoms and 1 to 5, preferably 1 to 3, more preferably 1 to 2 hetero atoms, such as a nitrogen atom, an oxygen atom and a sulfur atom; a haloalkyl group having 1 to 50, preferably 1 to 10, more preferably 1 to 5 carbon atoms and 1 to 8, preferably 1 to 5, more preferably 1 to 3 halogen atoms, such as a fluorine atom, a chlorine atom, a bromine atom and an iodine atom; a halogen atom, such as a fluorine atom, a chlorine atom, a bromine atom and an iodine atom; a cyano group; and a nitro group.