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US 9,754,726 B2Granted
Nonaqueous electrolytic capacitor element
AssigneesRicoh Company, Ltd., Kyushu University
InventorsNobuaki Onagi, Okitoshi Kimura, Eiko Hibino, Hisamitsu Kamezaki, Tatsumi Ishihara
Life of this patent
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Abstract
To provide a nonaqueous electrolytic capacitor element, which contains: a positive electrode containing a positive electrode active material capable of intercalating or deintercalating anions; a negative electrode containing a negative electrode active material; and a nonaqueous electrolyte, which contains a nonaqueous solvent, an electrolyte salt containing a halogen atom, and a compound having a site capable of bonding to an anion containing a halogen atom.
Claims5
A nonaqueous electrolytic capacitor element, comprising:
- a positive electrode comprising a positive electrode active material capable of intercalating or deintercalating anions,
- a negative electrode comprising carbon powder as a negative electrode active material, wherein the carbon powder of the negative electrode active material has a BET specific surface area by nitrogen adsorption of 4,600 m2/g, and
- a nonaqueous electrolyte, which comprises a nonaqueous solvent, an electrolyte salt consisting of LiPF6, and a compound comprising a site capable of bonding to a halogen-containing anion, wherein the compound comprising a site capable of bonding to a halogen-containing anion is at least one member selected from the group consisting of a compound represented by formula (1), and a compound represented by formula (2):
- where R1, R2 and R3 are independently an alkyl group, an aryl group, or a heteroaryl group, each of which is optionally substituted with a halogen atom, an alkyl group, an alkoxide group, a thiol group, a thioalkoxide group, an aryl group, an ether group, or a thioether group,
- where R4, R5 and R6 are independently an alkyl group, an aryl group, or a heteroaryl group, each of which is optionally substituted with a halogen atom, an alkyl group, an alkoxide group, a thiol group, a thioalkoxide group, an aryl group, an ether group, or a thioether group;
- and wherein an amount of the compound comprising a site capable of bonding to an a halogen containing anion comprising a halogen atom is 0.5% by mass or greater and 5% by mass or less relative to an amount of the nonaqueous electrolyte;
- wherein the electrolyte salt is present in an amount higher than 2 mol/L, and wherein the capacitor element has a maximum voltage during charging that is higher than 4.5 V.
4 more elements
Dependencies are inferred from the claim text.