# US 9,753,291 B2 · Antistatic film, method for manufacturing the same, and display device including the same > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 9,753,291 B2 - Document ID: US9753291B2 - Status: Granted - Kind: B2 - Application number: 14/098,854 - Filed: 2013-12-06 - Published: 2014-10-30 - Granted: 2017-09-05 - Earliest claimed: 2013-04-29 - Assignees: LG Display Co., Ltd. - Applicants: LG Display Co., Ltd. - Inventors: Taehwan Jun; Sunghee Kim; Junsik Hwang; Kwihong Park; Yuseon Kho - Web page: https://patentgrep.com/patent/US9753291B2 ## CPC - G02B 1/16: having an anti-static effect, e.g. electrically conducting coatings - Y10T 428/2495: Thickness [relative or absolute] - Y10T 428/31663: As siloxane, silicone or silane - G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract An antistatic film includes a substrate, a lower coating layer positioned on the substrate and including a conductive material, tetraethyl orthosilicate (TEOS), and silsesquioxane (SSQ), and an upper coating layer positioned on the lower coating layer and including the conductive material and tetraethyl orthosilicate. ## Claims ### Claim 1 An antistatic film comprising: a substrate; a lower coating layer positioned on the substrate and consisting of a conductive material, tetraethyl orthosilicate (TEOS), and silsesquioxane (SSQ); and an upper coating layer positioned on the lower coating layer and consisting of the conductive material and tetraethyl orthosilicate, wherein the conductive material in the lower coating layer as the conductive material in the upper coating layer are a same material and the conductive material in the lower coating layer has a higher parts by weight than that in the upper coating layer, based on 100 parts by weight of the lower and the upper coating layer on the substrate, respectively. ### Claim 2 (depends on 1) The antistatic film of claim 1, wherein the conductive material is any one selected from the group consisting of a carbon nanotube (CNT), metal oxide, graphene, and a conductive polymer. ### Claim 3 (depends on 2) The antistatic film of claim 2, wherein the conductive polymer is one or more selected from the group consisting of polyfluorene, polyphenylene, polypyrene, polyazulene, polynaphthalene, polyacetylene (PAC), poly(p-phenylene vinylene) (PPV), polypyrrole (PPY), polycarbazole, polyindole, polyazepine, poly(thienylene vinylene), polyaniline (PANI), poly(thiophene), poly(p-phenylene sulfide) (PPS), poly(3,4-ethylenedioxy thiophene) (PEDOT), poly(3,4-ethylenedioxy thiophene) doped with poly(styrene sulfonate) (PSS) (PEDOT:PSS), poly(3,4-ethylenedioxy thiophene)-tetramethacrylate (PEDOT-TMA), polyfuran, and a combination thereof. ### Claim 4 (depends on 1) The antistatic film of claim 1, wherein a thickness of the lower coating layer is larger than the thickness of the upper coating layer. ### Claim 5 (depends on 1) The antistatic film of claim 1, wherein the lower coating layer contacts the upper coating layer. ### Claim 6 (depends on 1) The antistatic film of claim 1, wherein the upper and lower coating layers include same constituent materials except that the lower coating layer further includes silisesquioxane and except that the constituent materials in the upper and lower coating layers have different parts by weight. ### Claim 7 A method for manufacturing an antistatic film, comprising: preparing a substrate; applying a lower coating layer composition consisting of 20 to 25 parts by weight of a conductive material, 7 to 11 parts by weight of tetraethyl orthosilicate, 20 to 30 parts by weight of silsesquioxane, 25 to 40 parts by weight of a solvent, and 8 to 16 parts by weight of an additive based on 100 parts by weight of the lower coating layer composition on the substrate, and heat-treating the lower coating layer composition to form a lower coating layer; and applying an upper coating layer composition consisting of 0.1 to 10 parts by weight of the conductive material, 5 to 30 parts by weight of tetraethyl orthosilicate, 30 to 60 parts by weight of the solvent, and 8 to 16 parts by weight of the additive based on 100 parts by weight of the upper coating layer composition on the lower coating layer, and heat-treating the upper coating layer composition to form an upper coating layer, wherein the conductive material in the lower coating layer is the same as the conductive material in the upper coating layer and the conductive material in the lower coating layer has a higher parts by weight than that in the upper coating layer. ### Claim 8 (depends on 7) The method of claim 7, wherein the conductive material is any one selected from the group consisting of a carbon nanotube (CNT), metal oxide, graphene, and a conductive polymer. ### Claim 9 (depends on 7) The method of claim 7, wherein the conductive material is one or more selected from the group consisting of polyfluorene, polyphenylene, polypyrene, polyazulene, polynaphthalene, polyacetylene (PAC), poly(p-phenylene vinylene) (PPV), polypyrrole (PPY), polycarbazole, polyindole, polyazepine, poly(thienylene vinylene), polyaniline (PANI), poly(thiophene), poly(p-phenylene sulfide) (PPS), poly(3,4-ethylenedioxy thiophene) (PEDOT), poly(3,4-ethylenedioxy thiophene) doped with poly(styrene sulfonate) (PSS) (PEDOT:PSS), poly(3,4-ethylenedioxy thiophene)-tetramethacrylate (PEDOT-TMA), polyfuran, and a combination thereof. ### Claim 10 (depends on 7) The method of claim 7, wherein the heat-treating is performed a 140 to 230° C. for 10 to 20 minutes. ### Claim 11 (depends on 7) The method of claim 7, wherein the lower coating layer composition or the upper coating layer composition is applied by slit coating or spin coating. ### Claim 12 A stereoscopic display device comprising: a thin film transistor array substrate; a color filter substrate facing the thin film transistor array substrate and including a black matrix; a black stripe on the color filter substrate and corresponding to the black matrix; and an antistatic film on the black stripe, wherein the antistatic film includes: a lower coating layer consisting of a conductive material, tetraethyl orthosilicate (TEOS), and silsesquioxane (SSQ); and an upper coating layer positioned on the lower coating layer and consisting of the conductive material and tetraethyl orthosilicate, wherein the conductive material in the lower coating layer is the same as the conductive material in the upper coating layer and the conductive material in the lower coating layer has a higher parts by weight than that in the upper coating layer.