# US 9,753,191 B2 · Light diffusion film and light diffusion film manufacturing method

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- Number: US 9,753,191 B2
- Document ID: US9753191B2
- Status: Granted
- Kind: B2
- Application number: 14/774,920
- Filed: 2014-02-25
- Published: 2016-01-28
- Granted: 2017-09-05
- Earliest claimed: 2013-03-29
- Assignees: Lintec Corporation
- Applicants: LINTEC Corporation
- Inventors: Kentaro Kusama; Baku Katagiri; Tomoo Orui; Satoru Shoshi
- Web page: https://patentgrep.com/patent/US9753191B2

## CPC

- G02B 5/0247: {by means of voids or pores}
- C08F 299/065: {from polyurethanes with side or terminal unsaturations}
- C08L 33/14: of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
- C08L 55/005: {Homopolymers or copolymers obtained by polymerisation of macromolecular compounds terminated by a carbon-to-carbon double bond}
- G02B 5/0236: {the diffusion taking place within the volume of the element}
- G02B 5/0257: {creating an anisotropic diffusion characteristic, i.e. distributing output differently in two perpendicular axes}
- G02B 5/0268: {characterized by the fabrication or manufacturing method}
- G02B 5/0278: {used in transmission}
- G02F 1/133504: {Diffusing, scattering, diffracting elements (associated to illuminating devices G02F1/133606)}
- G02B 2207/123: Optical louvre elements, e.g. for directional light blocking
- G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)
- G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS

## Abstract

Provided are a light diffusion film having a single-layered light diffusion layer, in which the uniformity of the intensity of diffused light in the light diffusion angle region can be increased, or the light diffusion angle region can be expanded effectively, by regulating the combination of the angles of inclination of pillar-shaped objects in plural columnar structure regions, and a method for manufacturing a light diffusion film. Disclosed is a light diffusion film having a single-layered light diffusion layer, the light diffusion film having a first columnar structure region and a second columnar structure region, in which plural pillar-shaped objects having a relatively high refractive index are arranged to stand close together in a region having a relatively low refractive index, sequentially from the lower part of the film along the film plane.

## Claims

### Claim 1

A light diffusion film comprising a single-layered light diffusion layer including, sequentially from the lower part of the film along a film thickness direction, a first columnar structure region and a second columnar structure region, in which plural pillar-shaped objects having a relatively high refractive index are arranged to stand close together in a region having a relatively low refractive index,
the light diffusion film being a photocured product of a composition for a light diffusion film, and
wherein the light diffusion film comprises an overlapping columnar structure region in which an upper end of the first columnar structure region extends into a lower end of the second columnar structure region so that the upper end of the first columnar structure region and the lower end of the second columnar structure region overlap with each other in a cross-section of the light diffusion film when the light diffusion film is cut at a plane that is perpendicular to a light diffusion film plane and cuts the pillar-shaped objects into two along axial lines in the first columnar structure region and the second columnar structure region.

### Claim 2 (depends on 1)

The light diffusion film according to claim 1, wherein the overlapping columnar structure region is formed by tips of any one side of the pillar-shaped objects respectively originating from the first columnar structure region and the second columnar structure region, being brought into contact with a vicinity of the tips of the pillar-shaped objects originating from the other columnar structure region.

### Claim 3 (depends on 1)

The light diffusion film according to claim 1, wherein a thickness of the overlapping columnar structure region is adjusted to a value within the range of 1 to 40 μm.

### Claim 4 (depends on 1)

The light diffusion film according to claim 1, wherein a thickness of the overlapping columnar structure region is adjusted to a value within the range of 0.1% to 10% relative to a film thickness, taken as 100%.

### Claim 5 (depends on 1)

The light diffusion film according to claim 1, wherein in the overlapping columnar structure region, the absolute value of the difference between angles of inclination of the pillar-shaped objects respectively originating from the first columnar structure region and the second columnar structure region is adjusted to a value of 1° or more.

### Claim 6 (depends on 1)

The light diffusion film according to claim 1, wherein a main component of the pillar-shaped objects in the first columnar structure region and the second columnar structure region is a (meth)acrylic acid ester polymer containing plural aromatic rings, and a main component of the region having a relatively low refractive index is a polymer of urethane (meth)acrylate.

### Claim 7

A method for manufacturing a light diffusion film, the method comprising the following steps (a) to (d):
(a) a step of preparing a composition for light diffusion film;
(b) a step of applying the composition for light diffusion film on a process sheet, and forming a coating layer;
(c) a step of subjecting the coating layer to first active energy ray irradiation, and forming a first columnar structure region in a lower portion of the coating layer, in which plural pillar-shaped objects having a relatively high refractive index are arranged to stand close together in a region having a relatively low refractive index, while leaving a columnar structure-unformed region in an upper portion of the coating layer; and
(d) a step of subjecting the coating layer to second active energy ray irradiation, and forming a second columnar structure region in the columnar structure-unformed region, in which plural pillar-shaped objects having a relatively high refractive index are arranged to stand close together in a region having a relatively low refractive index, and wherein an upper end of the first columnar structure region extends into a lower end of the second columnar structure region so that the upper end of the first columnar structure region and the lower end of the second columnar structure region overlap with each other in a cross-section of the light diffusion film when the light diffusion film is cut at a plane that is perpendicular to a light diffusion film plane and cuts the pillar-shaped objects into two along axial lines in the first columnar structure region and the second columnar structure region.

### Claim 8 (depends on 7)

The method for manufacturing a light diffusion film according to claim 7, wherein the first active energy ray irradiation is performed in an oxygen-containing atmosphere, while the second active energy ray irradiation is performed in a non-oxygen atmosphere.

### Claim 9

A light diffusion film comprising a single-layered light diffusion layer including, sequentially from a lower part of the film along a film thickness direction, a first columnar structure region and a second columnar structure region, in which plural pillar shaped objects having a relatively high refractive index are arranged to stand close together in a region having a relatively low refractive index,
wherein the light diffusion film comprises an overlapping columnar structure region in which an upper end of the first columnar structure region extends into a lower end of the second columnar structure so that the upper end of the first columnar structure region and the lower end of the second columnar structure region overlap with each other in a cross-section of the light diffusion film when the light diffusion film is cut at a plane that is perpendicular to a light diffusion plane and cuts the pillar shaped objects into two along axial lines in the first columnar structure region and the second columnar structure region,
a thickness of the overlapping columnar structure region is adjusted to a value within the range of 0.1% to 10% relative to a film thickness, taken as 100%, and
a value obtained by subtracting the thickness of the overlapping columnar structure region from the sum of the thickness of the first columnar structure region and the second columnar structure region is adjusted to a value of 80% or more relative to the film thickness, taken as 100%.