# US 9,752,965 B2 · Apparatus and method for fast sampling and measurement

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- Number: US 9,752,965 B2
- Document ID: US9752965B2
- Status: Granted
- Kind: B2
- Application number: 14/513,514
- Filed: 2014-10-14
- Published: 2015-04-16
- Granted: 2017-09-05
- Earliest claimed: 2013-10-16
- Assignees: Sensigent LLC
- Applicants: Sensigent LLC
- Inventors: Steven R Foote
- Web page: https://patentgrep.com/patent/US9752965B2

## CPC

- G01N 1/14: Suction devices, e.g. pumps; Ejector devices
- G01N 1/24: Suction devices {(G01N1/22 - G01N1/2294 take precedence)}
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)

## Abstract

Sampling systems for use on production lines with the capability to measure chemical components of a gas, vapor, or liquid sample taken from a product on the line and at a faster rate than the individual sensors alone are capable of. In one embodiment, the system detects the presence of insoluble hydrocarbons in the gas vapor present inside refillable water bottles that have been returned by the consumer. Each sampling system—apparatus—comprises two or more sub-systems each comprising: one or more sensors for performing a measurement of interest on a gas, vapor, or liquid sample, valves and a pump for directing the flow of samples, optionally an enclosed volume to hold the sample, and all under the direction of a control system. The sampling system also automatically acts on the measurement to detect when defective goods have reached a point where they can be ejected from the production line.

## Claims

### Claim 1

A method of detecting one or more chemical components of a gas, vapor, or liquid sample removed from a product on a production line, comprising,
a. providing an apparatus with at least one subsystem, each subsystem comprising components of:
i. a sensor operatively configured to detect one or more chemical components of a gas, vapor, or liquid sample removed from a product on a production line;
ii. a pump operatively configured to circulate the gas, vapor, or liquid sample over the sensor and throughout the subsystem;
iii. an enclosed volume operatively configured as a reservoir for temporarily storing the gas, vapor, or liquid sample;
iv. a plurality of valves under the directional operation of a computerized control system, the valves comprising:
at least one sample inlet valve able to receive the gas, vapor, or liquid sample removed from a product on a production line;
at least one purge inlet valve able to receive a reference sample comprising the one or more chemical components or an agent able to cleanse the subsystem;
at least one exhaust valve configured to release the gas, vapor, or liquid sample or the reference sample, or portions thereof, from the apparatus;
at least one valve configured to direct the flow of the gas, vapor, or liquid sample or the reference sample throughout the apparatus;
v. the computerized control system comprising a computer central processing unit, a program memory, a variable memory and a plurality of input and output circuits for communicating with and controlling the operation of the apparatus components; and,
vi. a tubing configured to circulate the sample throughout the apparatus components;
b. conducting a sampling during a sampling interval comprising, the sample inlet valve directing the gas, vapor, or liquid sample via the tubing into the enclosed volume and releasing an excess amount of the sample through one of the exhaust valves;
c. conducting a sample measurement during a measurement interval on the gas, vapor, or liquid sample comprising, pumping the gas, vapor, or liquid sample from the enclosed volume over the sensor, and electrically transmitting data from the sensor to the computerized control system; and,
d. analyzing the data by the computerized control system or the sensor to determine if a desired chemical component or contaminant is present in the gas, vapor, or liquid sample.

### Claim 2 (depends on 1)

The method of claim 1, further comprising performing a purge or reference sample operation during a purge or reference sample interval if the sensor requires a recovery period or a reference sample between the sample measurements, comprising opening the purge inlet valve and filling the tubing and components to about maximum capacity with a reference sample while blocking access to the sample inlet valve and the exhaust valve connected to the enclosed volume.

### Claim 3 (depends on 2)

The method of claim 2, further comprising performing a recovery or reference operation during a recovery or reference interval if the sensor requires a recovery period or a reference sample between the sample measurements, comprising pumping the reference sample over the sensor, electrically transmitting data from the sensor to the computerized control system; and, analyzing the data to determine the chemical components of the reference sample.

### Claim 4 (depends on 1)

The method of claim 1, further comprising rejecting from the production line products comprising an undesirable amount of a chemical component as detected by the sensor from the gas, vapor, or liquid sample taken from the product.

### Claim 5 (depends on 1)

The method of claim 1, wherein the at least one subsystem comprises a plurality of subsystems which are lying in parallel on the production line and each subsystem is operating under the direction of the respective computerized control system.

### Claim 6 (depends on 5)

The method of claim 5, wherein the apparatus comprises three subsystems.

### Claim 7 (depends on 5)

The method of claim 5, wherein a number of subsystems required is determined by computing a total time and dividing the total time by a fast sample time, and wherein the total time is computed from adding the fast sample time plus a measurement time plus a recovery or reference sample time.

### Claim 8 (depends on 7)

The method of claim 7, wherein the apparatus comprises 10 subsystems, wherein the sensor is a gas sensor, the product is a re-useable drinking bottle, and the sample comprises vapor or gas contained in the bottle prior to the bottle being cleaned for refilling with water, and the apparatus is able to test 1 bottle sample per second and analyze the sensor sample data within about 4 seconds from taking the sample from the bottle.

### Claim 9 (depends on 1)

The method of claim 1, wherein the product is a re-useable water bottle, and further comprising injecting compressed air into the re-useable water bottle to force the gas, vapor, or liquid sample into the sample inlet valve.

### Claim 10 (depends on 8)

The method of claim 8, further comprising a first purging during a first purge interval occurring concurrently with the measurement interval, and comprising opening the purge inlet valve and filling the tubing and components to about maximum capacity with clean dry compressed air while blocking access to the sample inlet valve and the exhaust valve connected to the enclosed -volume.

### Claim 11 (depends on 10)

The method of claim 10, wherein each subsystem further comprises a purge exhaust valve able to release the clean dry air from the subsystem, and the method further comprising a second purging during a second purge interval comprising opening the purge exhaust valve to release the clean dry compressed air after it has purged the sensor of contaminates, and then closing the purge exhaust valve while pumping the dry compressed air throughout the subsystem.

### Claim 12 (depends on 11)

The method of claim 11, further comprising performing a recovery or reference operation during a recovery or reference interval comprising pumping the reference sample over the sensor, electrically transmitting data from the sensor to the computerized control system; and, analyzing the data to determine the chemical components of the reference sample, wherein the recovery or reference interval occurs concurrent with the second purge interval.

### Claim 13 (depends on 1)

The method of detecting of claim 1, wherein the plurality of valves comprises,
one sample inlet valve able to receive the sample removed from a product on a production line;
one purge inlet valve able to receive a sample of a reference of the one or more chemical components, or an agent able to cleanse the subsystem;
two exhaust valves configured to release the product sample or the reference sample, or portions thereof, from the apparatus, comprising one exhaust valve connected to the enclosed volume and one connected to the pump; and
three uni-directional valve(s) configured to direct the flow of the sample or reference throughout the apparatus.

### Claim 14 (depends on 13)

The method of detecting of claim 13, wherein the two exhaust valves comprise, one exhaust valve connected to the enclosed volume and one exhaust valve connected to the pump.