# US 9,751,992 B2 · Elastomeric composition having a very good dispersion of the filler in the elastomeric matrix

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- Number: US 9,751,992 B2
- Document ID: US9751992B2
- Status: Granted
- Kind: B2
- Application number: 14/364,273
- Filed: 2012-12-12
- Published: 2014-12-25
- Granted: 2017-09-05
- Earliest claimed: 2011-12-12
- Assignees: Compagnie Generale Des Etablissements Michelin; Michelin Recherche et Technique S.A.
- Applicants: Compagnie Generale Des Etablissements Michelin; Michelin Recherche Et Technique S.A.
- Inventors: Marc Sevignon; Cécile Belin
- Web page: https://patentgrep.com/patent/US9751992B2

## CPC

- C08J 3/22: using masterbatch techniques
- B60C 1/0016: {Compositions of the tread}
- C08K 3/04: Carbon
- C08K 5/0016: {Plasticisers}
- C08J 2307/02: Latex
- C08J 2321/00: Characterised by the use of unspecified rubbers
- C08K 2201/006: Additives being defined by their surface area
- C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29)
- B60C: VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09)

## Abstract

The invention relates to a rubber composition based on at least one diene elastomer, a reinforcing filler comprising at least carbon black having a CTAB specific surface of greater than or equal to 130 m2/g, a plasticizing oil and also a crosslinking system, the dispersion of the filler in the elastomeric matrix having a Z score of greater than or equal to 70.

## Claims

### Claim 1

A process for the preparation of a rubber composition comprising the steps of:
providing a dried coagulum comprising at least one diene elastomer and a reinforcing filler, the reinforcing filler comprising at least carbon black having a CTAB specific surface of greater than or equal to 130 m2/g;
providing a plasticizing system consisting of a plasticizing oil selected from the group consisting of a polyolefinic oil, a paraffinic oil, a naphthenic oil, an aromatic oil, a mineral oil, or mixtures thereof;
incorporating the dried coagulum and the plasticizing system in a mixer, and kneading everything thermomechanically until a maximum temperature of between 130° C. and 200° C. is reached,
cooling the combined mixture to a temperature of less than 100° C.,
subsequently incorporating a crosslinking system into the mixture,
kneading everything up to a maximum temperature of less than 120° C., wherein the dispersion of the filler in the rubber composition has a Z score of 70 or greater.

### Claim 2 (depends on 1)

The process according to claim 1, wherein a first masterbatch comprising the dried coagulum of the at least one diene elastomer and the carbon black, and exhibiting a dispersion of the carbon black in the first masterbatch having a Z score of greater than or equal to 80, is prepared prior to the incorporation of the dried coagulum in the mixer.

### Claim 3 (depends on 1)

The process according to claim 1, wherein the content of plasticizing oil varies from 2 to 50 parts per hundred parts by weight of elastomer.

### Claim 4 (depends on 1)

The process according to claim 1, further comprising introducing an inorganic filler, a second elastomer, or both into the composition simultaneously with the other constituents during the first kneading step.

### Claim 5 (depends on 1)

The process according to claim 1, wherein an inorganic filler and a second elastomer are introduced into the composition in the form of a second masterbatch prepared prior to its incorporation into the first kneading step.

### Claim 6 (depends on 1)

The process according to claim 1, wherein the diene elastomer is selected from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers and the mixtures of these elastomers.

### Claim 7 (depends on 6)

The process according to claim 6, wherein the diene elastomer is a natural rubber.

### Claim 8 (depends on 1)

The process according to claim 1, wherein an inorganic filler and a second elastomer are introduced separately into the composition, the inorganic filler being introduced before or after the second elastomer.

### Claim 9 (depends on 8)

The process according to claim 8, wherein the introduction of the inorganic filler and/or of the second elastomer is offset in time from a few tens of seconds to a few minutes with respect to the introduction of the dried coagulum into the mixer.