# US 9,750,246 B2 · Insecticidal compounds

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- Number: US 9,750,246 B2
- Document ID: US9750246B2
- Status: Granted
- Kind: B2
- Application number: 15/106,489
- Filed: 2014-12-19
- Published: 2017-01-05
- Granted: 2017-09-05
- Earliest claimed: 2013-12-23
- Assignees: Syngenta Participations AG
- Applicants: Syngenta Participations AG
- Inventors: Andrew Edmunds; Andre Stoller; Thomas Pitterna
- Web page: https://patentgrep.com/patent/US9750246B2

## CPC

- A01N 37/34: Nitriles
- A01N 27/00: Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
- A01N 37/46: N-acyl derivatives
- A01N 43/40: six-membered rings
- C07C 255/56: containing cyano groups and doubly-bound oxygen atoms bound to the carbon skeleton
- C07C 255/57: containing cyano groups and carboxyl groups, other than cyano groups, bound to the carbon skeleton
- C07D 213/81: Amides; Imides
- C07D 213/82: in position 3
- C07D 213/89: with hetero atoms directly attached to the ring nitrogen atom
- A01N: PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF (preservation of food or foodstuff A23); BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES (preparations for medical, dental or toiletry purposes which kill or prevent the growth or proliferation of unwanted organisms A61K); PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07D: HETEROCYCLIC COMPOUNDS (macromolecular compounds C08)

## Abstract

The present invention relates to novel bisamide derivatives of formula (I) having insecticidal activity, to processes and intermediates for preparing them, to insecticidal, acaricidal, nematicidal or molluscicidal compositions comprising them and to methods of using them to combat and control insect, acarine, nematode or mollusc pests wherein X0, X1, X2, Y1, Y2, R1, R2, G1 and G2, and Q are as described in formula 1 or salts and n-Oxides thereof.

## Claims

### Claim 1

A compound of formula (I)
wherein
X0 is bromo, chloro or hydrogen;
X1 is methoxy;
X2 is hydrogen;
Y1 and Y2 are independently chloro, bromo, iodo, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, and C1-C4haloalkoxy;
R1 and R2 are independent of one another hydrogen, C1-C8alkyl, C2-C8alkenyl, C2-C8alkynyl, C1-C8alkylcarbonyl, C1-C8alkoxycarbonyl, hydroxyl, C1-C8-alkyloxy, and aminocarbonyl-C1-C4alkylene;
G1 and G2 are independent of each other oxygen or sulfur;
Q is a group selected from Q2, Q3, Q4 and Q5, where
Q2 is a group of formula (IIb)
where W2 is selected from, hydrogen, halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or C1-C4 haloalkoxy,
Q3 is a group of formula (IIc)
where W3 is selected from, hydrogen, halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or C1-C4 haloalkoxy,
Q4 is a group of formula (IId)
where W4 is selected, hydrogen, halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or C1-C4 haloalkoxy,
Q5 is a group of formula (IIe)
where W5 is selected from hydrogen, halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or C1-C4 haloalkoxy.

### Claim 2 (depends on 1)

A compound of formula (I) according to claim 1 wherein Y1 and Y2 are selected from Cl, Br, I, methyl, ethyl, methoxy, difluoromethoxy, and trifluoromethoxy,
X0 is hydrogen or Br or Cl
R1 is selected from hydrogen or C1-C2alkyl;
R2 is selected from hydrogen, C1-C2alkyl;
and
G1 and G2 are both oxygen.

### Claim 3 (depends on 1)

A compound of formula (III)
wherein X0, Y1, Y2, X1, X2, R1, and R2 are as defined in formula (I) of claim 1.

### Claim 4 (depends on 1)

A method of controlling insects, acarines, nematodes or molluscs which comprises applying to a pest, to a locus of a pest, or to a plant susceptible to attack by a pest an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound of formula (I) as defined in claim 1.

### Claim 5 (depends on 1)

An insecticidal, acaricidal, nematicidal or molluscicidal composition comprising an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound of formula (I) as defined in claim 1 together with an agrochemically acceptable diluent or carrier.

### Claim 6 (depends on 5)

A composition according to claim 5 which further comprises one or more additional insecticidal, acaricidal, nematicidal or molluscicidal compounds.

### Claim 7 (depends on 1)

A method of protecting useful plants from insects, acarines, nematodes or molluscs, comprising applying to said plants, to the locus thereof, or to plant propagation material thereof, an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound of formula I in claim 1.