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US 9,688,035 B2Granted
Optical article and method of forming
AssigneesDow Corning Corporation, Dow Corning Toray Co., Ltd.
InventorsSteven Swier, Masaaki Amako
Life of this patent
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Abstract
A method of forming an optical article includes the step of applying a silicone composition to a surface, wherein the silicone composition is a solid and has a glass transition temperature greater than room temperature. The silicone composition is heated to a temperature at or above the glass transition temperature such that the silicone composition flows. The silicone composition forms a light transmitting sheet upon cooling following the heating.
Claims16
A method of forming an optical article, comprising:
- applying a silicone composition to a surface, wherein the silicone composition is a solid and has a glass transition temperature greater than room temperature;
- and
- heating the silicone composition to a temperature at or above the glass transition temperature such that the silicone composition flows;
- wherein:
- the silicone composition forms a light transmitting sheet upon cooling following the heating;
- and
- the silicone composition comprises an organosiloxane block copolymer having a weight average molecular weight of at least 20,000 g/mole and comprises:
- 40 to 90 mole percent disiloxy units of the formula [R12SiO2/2] arranged in linear blocks each having an average of from 10 to 400 disiloxy units [R12SiO2/2] per linear block;
- 10 to 60 mole percent trisiloxy units of the formula [R12SiO3/2] arranged in non-linear blocks each having a weight average molecular weight of at least 500 g/mole;
- and
- 0.5 to 25 mole percent silanol groups [≡SiOH];
- wherein R1 is independently a C1 to C30 hydrocarbyl and R2 is independently a C1 to C20 hydrocarbyl,
- wherein at least 30 weight percent of the non-linear blocks are crosslinked with another non-linear block and aggregated in nano-domains, and
- wherein each linear block is linked to at least one non-linear block.
11 more elements
Dependencies are inferred from the claim text.