Fluorene-type compound, photopolymerization initiator comprising said fluorene-type compound, and photosensitive composition containing said photopolymerization initiator
AssigneeTokyo Ohka Kogyo Co., Ltd.
InventorsMakoto Harihara, Tomohiko Yamazaki, Katsuji Kuwamura
Life of this patent
Estimating the term…
Abstract
According to an embodiment of the present invention, there is provided a novel fluorene-based compound and a photopolymerization initiator using the fluorene-based compound. The fluorene-based compound according to an embodiment of the present invention is represented by the general formula (1). A photopolymerization initiator having additionally high sensitivity can be provided by using the fluorene-based compound. In addition, a photopolymerization initiator that can impart additionally excellent characteristics can be provided by appropriately selecting, for example, a substituent.
Claims13
A fluorene-based compound, which is represented by the general formula (1):
- in the general formula (1):
- when m represents 0 and n represents 0, R1 represents a hydrogen atom, a halogen atom, a nitro group, a sulfonyloxy group substituted with an alkyl group having 1 to 8 carbon atoms that may be substituted with a halogen atom, a phenylsulfonyloxy group that may be substituted, a sulfonyl group substituted with an alkyl group having 1 to 8 carbon atoms that may be substituted with a halogen atom, a phenylsulfonyl group that may be substituted, a heterocyclic sulfonyl group that may be substituted, or a condensed ring sulfonyl group that may be substituted, when m represents 0 and n represents 1, R1 represents a phenyl group that may be substituted, a heterocyclic group that may be substituted, or a condensed ring group that may be substituted, and when m represents 1 and n represents 1, R1 represents a sulfonyloxy group substituted with an alkyl group having 1 to 8 carbon atoms that may be substituted with a halogen atom, or a phenylsulfonyloxy group that may be substituted;
- R2 and R3 each independently represent, a linear or branched halogenated alkyl group having 1 to 10 carbon atoms, or a linear or branched alkyl group having 2 to 9 carbon atoms interrupted by one or more ether bonds, and R2 and R3 may form a ring together;
- R4 represents a group represented by the formula (2):
- in the formula (2) R5 represents a linear, branched, or cyclic alkyl group having 1 to 17 carbon atoms, a linear or branched halogenated alkyl group having 2 to 5 carbon atoms, a linear or branched alkyl group having 2 to 7 carbon atoms interrupted by one or more ether bonds or thioether bonds, a phenyl group that may be substituted, a phenylalkyl group having 7 to 11 carbon atoms that may be substituted, a phenoxyalkyl group having 7 to 10 carbon atoms that may be substituted, a heterocyclic group that may be substituted, or a condensed ring group that may be substituted,
- in the formula (2), R6 represents a branched, or cyclic alkyl group having 3 to 17 carbon atoms, a linear or branched halogenated alkyl group having 1 to 7 carbon atoms, a linear or branched alkyl group having 2 to 7 carbon atoms interrupted by one or more ether bonds or thioether bonds, a linear or branched aminoalkyl group having 2 to 3 carbon atoms that may be substituted, a phenyl group that may be substituted, a condensed ring group that may be substituted, or a heterocyclic group that may be substituted, and
- m and n each represent 0 or 1, and when m represents 1, n represents 1.
A fluorene-based compound, which is represented by the general formula (1):
- in the general formula (1):
- when m represents 0 and n represents 0, R1 represents a hydrogen atom, a halogen atom, a nitro group, a sulfonyloxy group substituted with an alkyl group having 1 to 8 carbon atoms that may be substituted with a halogen atom, a phenylsulfonyloxy group that may be substituted, a sulfonyl group substituted with an alkyl group having 1 to 8 carbon atoms that may be substituted with a halogen atom, a phenylsulfonyl group that may be substituted, a heterocyclic sulfonyl group that may be substituted, or a condensed ring sulfonyl group that may be substituted, when m represents 0 and n represents 1, R1 represents a phenyl group that may be substituted, a heterocyclic group that may be substituted, or a condensed ring group that may be substituted, and when m represents 1 and n represents 1, R1 represents a sulfonyloxy group substituted with an alkyl group having 1 to 8 carbon atoms that may be substituted with a halogen atom, or a phenylsulfonyloxy group that may be substituted;
- R2 and R3 each independently represent a hydrogen atom, a linear, branched, or cyclic alkyl group having 1 to 22 carbon atoms, a linear or branched halogenated alkyl group having 1 to 10 carbon atoms, or a linear or branched alkyl group having 2 to 15 carbon atoms interrupted by one or more ether bonds or thioether bonds, and R2 and R3 may form a ring together;
- wherein the R4 represents a group represented by the formula (3):
- in the formula (3), R5′ represents a linear, branched, or cyclic alkyl group having 1 to 17 carbon atoms, a linear or branched halogenated alkyl group having 2 to 5 carbon atoms, a linear or branched alkyl group having 2 to 7 carbon atoms interrupted by one or more ether bonds or thioether bonds, a phenyl group that may be substituted, a phenylalkyl group having 7 to 11 carbon atoms that may be substituted, a phenoxyalkyl group having 7 to 10 carbon atoms that may be substituted, a heterocyclic group that may be substituted, or a condensed ring group that may be substituted, and the R7 represents a linear, branched, or cyclic alkyl group having 1 to 6 carbon atoms, a linear or branched halogenated alkyl group having 1 to 4 carbon atoms, a phenyl group that may be substituted, a phenylalkyl group having 7 to 10 carbon atoms that may be substituted, a phenylalkyl group having 7 to 9 carbon atoms that is interrupted by one or more ether bods or thioether bonds and may be substituted, a condensed ring group that may be substituted, or a heterocyclic group that may be substituted.
A fluorene-based compound, which is represented by the general formula (1):
- in the general formula (1):
- when m represents 0 and n represents 0, R1 represents a hydrogen atom, a halogen atom, a nitro group, a sulfonyloxy group substituted with an alkyl group having 1 to 8 carbon atoms that may be substituted with a halogen atom, a phenylsulfonyloxy group that may be substituted, a sulfonyl group substituted with an alkyl group having 1 to 8 carbon atoms that may be substituted with a halogen atom, a phenylsulfonyl group that may be substituted, a heterocyclic sulfonyl group that may be substituted, or a condensed ring sulfonyl group that may be substituted, when m represents 0 and n represents 1, R1 represents a phenyl group that may be substituted, a heterocyclic group that may be substituted, or a condensed ring group that may be substituted, and when m represents 1 and n represents 1, R1 represents a sulfonyloxy group substituted with an alkyl group having 1 to 8 carbon atoms that may be substituted with a halogen atom, or a phenylsulfonyloxy group that may be substituted;
- R2 and R3 each independently represent a hydrogen atom, a linear, branched, or cyclic alkyl group having 1 to 22 carbon atoms, a linear or branched halogenated alkyl group having 1 to 10 carbon atoms, or a linear or branched alkyl group having 2 to 15 carbon atoms interrupted by one or more ether bonds or thioether bonds, and R2 and R3 may form a ring together;
- wherein the R4 represents a group represented by the formula (3):
- in the formula (3), R5′ represents a linear, branched, or cyclic alkyl group having 1 to 17 carbon atoms, a linear or branched halogenated alkyl group having 2 to 5 carbon atoms, a linear or branched alkyl group having 2 to 7 carbon atoms interrupted by one or more ether bonds or thioether bonds, a phenyl group that may be substituted, a phenylalkyl group having 7 to 11 carbon atoms that may be substituted, a phenoxyalkyl group having 7 to 10 carbon atoms that may be substituted, a heterocyclic group that may be substituted, or a condensed ring group that may be substituted, and the R7 represents a linear, branched, or cyclic alkyl group having 1 to 16 carbon atoms, a linear or branched halogenated alkyl group having 1 to 6 carbon atoms, a phenyl group that may be substituted, a phenylalkyl group having 7 to 10 carbon atoms that may be substituted, a phenylalkyl group having 7 to 9 carbon atoms that is interrupted by one or more ether bonds or thioether bonds and may be substituted, a condensed ring group that may be substituted, or a heterocyclic group that may be substituted;
- and
- m and n each represent 0 or 1, and when m represents 1, n represents 1.
Dependencies are inferred from the claim text.