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US 9,678,475 B2Granted
Security elements and method for their manufacture
AssigneeBASF SE
InventorsMichelle Richert, Roland Fleury, Nikolay A. Grigorenko, Frank Knocke
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Abstract
The present invention relates to complex security elements based on recording materials for optical elements with refractive index modulation, in particular, holograms, which are subsequently coated with specific metallic nano-shaped metal particles, a method for their manufacture, in particular on a paper or on a plastic substrate and a security product obtainable using the security element. A further aspect of the invention is the use of such a security element for the prevention of counterfeit or reproduction of a document of value.
Claims20
A security element, comprising:
- a) a substrate;
- b) a volume hologram formed in a refractive index modulated layer, which is obtained by holographically exposing a recording material to actinic radiation and thereon;
- and
- c) an embossed surface relief microstructure on at least a portion of the refractive index modulated layer,
- wherein the embossed surface relief microstructure comprises:
- platelet shaped transition metal particles, wherein the transition metal is Ag and/or Cu;
- and
- a binder,
- wherein the pigment to binder ratio is from 4:1 to 1:1000,
- the security element exhibits a gold color in reflection when viewed from the side of the embossed surface relief microstructure,
- a green color in reflection viewing the volume hologram from the unembossed reverse side, and
- a blue color in transmission, and
- wherein
- when the platelet shaped transition metal particles have a diameter from 15-40 nm and a height of 8-20 nm, the security element shows an angle dependent color change upon viewing from orange to blue,
- when the platelet shaped transition metal particles have a diameter from 30-70 nm and a height of 8-20 nm, the security element shows an angle dependent color change upon viewing from red to green, and
- when the platelet shaped transition metal particles have a diameter from 5-120 nm and a height of 7-17 nm, the security element shows an angle dependent color change upon viewing from blue to gold.
13 more elements
Dependencies are inferred from the claim text.