Introducing mesoporosity into zeolite materials with a modified acid pre-treatment step
AssigneeRive Technology, Inc.
InventorsErnest Senderov, Mohammad Ibrahim Qureshi
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Abstract
Methods for introducing mesoporosity into zeolite materials that employ an acid pretreatment step are provided. By utilizing a non-acidic chelating agent during the acid treatment step, the zeolite material can be pretreated with a strong acid, often in higher concentrations or over shorter contact times, than had previously been contemplated. The resulting acid-treated mesoporous materials retain desirable properties, including Si/Al, UCS, and total mesopore and micropore volume. The ability to use a stronger acid without damaging the zeolite material results in a less expensive process capable of producing mesoporous zeolite materials suitable for a wide range of uses.
Claims34
A method for making a mesoporous zeolite material, said method comprising:
- (a) providing an initial zeolite material;
- (b) contacting said initial zeolite material with at least one strong acid and at least one non-acidic, multi-ligand chelating agent in an acid-containing mixture to thereby provide an acid-treated zeolite material;
- and
- (c) contacting at least a portion of said acid-treated zeolite material with a basic medium under conditions sufficient to increase the mesoporosity of said acid-treated zeolite material to thereby provide a mesoporous zeolite material.
A method for making a mesoporous zeolite material, said method comprising:
- (a) contacting an initial zeolite material with at least one inorganic strong acid and at least one multi-ligand salt in an acid-containing mixture to thereby provide an acid-treated zeolite material;
- (b) separating at least a portion of said acid-treated zeolite material from said acid-containing mixture;
- and
- (c) further treating at least a portion of said acid-treated zeolite material separated in step (b) under conditions sufficient to increase the mesoporosity of said acid-treated zeolite material to thereby provide a mesoporous zeolite material.
Dependencies are inferred from the claim text.