Metal free bleaching composition
AssigneeBASF SE
InventorsMarkus Frey, Hauke Rohwer, Frederique Wendeborn, Menno Hazenkamp
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Abstract
The present invention relates to the use of a composition comprising specific a-amino-ketones, H2O2, a H2O2 precursor or a peracid and optionally an activator as a bleaching mixture for textile materials or dishes either manually or in an automatic washing machine or dish washer. Further aspects of the invention are the composition comprising specific a-aminoketones and H2O2, a H2O2 precursor or a peracid and a process for bleaching of stains or of soiling on textile materials or dishes in the context of a washing process either manually or in an automatic washing machine or dish washer. Also aspects of the invention are detergent formulations comprising such a composition and novel compounds.
Claims7
A process for the bleaching of stains or of soiling on textile materials or dishes in the context of a washing process or by the direct application of a stain remover comprising
- treating a textile material or dishes in an aqueous medium either by hand or in an automatic washing machine or dishwasher, at a pH between 7 and 11, together with a mixture comprising
- a) H2O2, a precursor of H2O2, or a peracid and
- b) a compound of formula (3)
- wherein
- R′1 is SCH3, S(O2)CH3, H, CH3, S(O)CH3, (CH3)2S+BF4− or (CH3)2S+(CH3O)S(O2)O−;
- or a compound of formula (4)
- wherein
- R′1 is H, CH3, SCH3, S(O)CH3 , S(O2)CH3, (CH3)2S+BF4− or (CH3)2S+(CH3O)S(O2)O−;
- or a compound of formula (5)
- wherein
- R′1 is SCH3, S(O2)CH3, H, CH3, S(O)CH3, (CH3)2S+BF4− or (CH3)2S+(CH3O)S(O2)O−;
- or a compound of formula (6)
- wherein
- R′1 =SCH3, S(O)CH3, S(O2)CH3, (CH3)2S+BF4− or (CH3)2S+(CH3O)S(O2)O−;
- or
- a compound of formula (7)
- wherein
- R′1 =H, S(O)CH3, S(O2)CH3, (CH3)(CH3CH2)S+BF4−, (CH3)2S+BF4−, (CH3)2S+PF6− or (CH3)2S+(CH3O)S(O2)O−;
- wherein the mixture is free of metal complexes, and
- wherein component a) is present in an amount of from 2 parts to 90 parts by weight and component b) is present in an amount of from 0.02 parts to 20 parts by weight;
- the sum being 100 parts.
Dependencies are inferred from the claim text.