# US 9,651,511 B2 · Conductivity sensor

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- Number: US 9,651,511 B2
- Document ID: US9651511B2
- Status: Granted
- Kind: B2
- Application number: 14/738,709
- Filed: 2015-06-12
- Published: 2015-10-01
- Granted: 2017-05-16
- Earliest claimed: 2006-12-06
- Assignees: ABB AB
- Applicants: ABB Limited
- Inventors: Colin Howell; David Albone; David Edward Coe
- Web page: https://patentgrep.com/patent/US9651511B2

## CPC

- G01N 27/07: Construction of measuring vessels; Electrodes therefor
- G01N 27/08: which is flowing continuously
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)

## Abstract

A conductivity sensor is described in which electrodes are held in a desired position within a housing of the sensor by a number of slots accurately positioned within the housing. In one embodiment the slots are integrally formed within the housing. Once the electrodes have been inserted into the slots a thermoset resin is poured into the housing and cured. A through bore is then drilled through the housing, the electrodes and the cured resin to form a flow conduit through the sensor. A dual frequency excitation technique is also described that allows a measurement to be obtained of a polarization resistance of the electrodes. In one embodiment this measurement is stored and used to correct subsequent conductivity measurements.

## Claims

### Claim 1

A conductivity sensor comprising:
a housing defining a flow conduit for the passage of a fluid;
first and second electrodes spaced apart along said flow conduit;
excitation circuitry operable to connect to said electrodes and operable to generate excitation signals; and
processing circuitry operable to connect to said electrodes and operable to determine conductivity measurements of fluid flowing through the housing;
wherein said excitation circuitry is operable to apply first and second excitation signals having first and second excitation frequencies respectively, to at least one of said electrodes; and
wherein said measurements include a desired component that varies proportionally with the conductivity to be measured and an undesired component that varies with polarisation effects of the electrodes and wherein the processing circuitry is operable to use the measurements obtained for the first and second frequencies to determine a correction to be applied to said conductivity measurements for correcting for the polarisation effects of the electrodes.

### Claim 2 (depends on 1)

The conductivity sensor according to claim 1, wherein said excitation circuitry is operable to apply said first and second excitation signals at different times.

### Claim 3 (depends on 1)

The conductivity sensor according to claim 1, wherein said excitation circuitry is operable to apply said first and second excitation signals simultaneously to said at least one electrode and wherein said processing circuitry includes filters for obtaining said measurements for the first and second excitation frequencies.

### Claim 4 (depends on 3)

The conductivity sensor according to claim 3, wherein said excitation circuitry is operable to generate a square wave signal and wherein said first and second excitation signals are the first and third harmonics of said square wave signal.

### Claim 5 (depends on 1)

The conductivity sensor according to claim 1, wherein said excitation circuitry is operable to generate sine wave signals at said different frequencies as said first and second excitation signals.

### Claim 6 (depends on 5)

The conductivity sensor according to claim 5, wherein said excitation circuitry comprises:
i) a circuit operable to generate a first square wave signal at said first frequency and a second square wave signal at said second frequency;
ii) a filter operable to filter a selected one of said first and second square wave signals to generate a sine wave signal having the same frequency as the selected square wave signal; and
iii) a selector operable to select one of said first and second square wave signals to be input to said filter.

### Claim 7 (depends on 1)

The conductivity sensor according to claim 1, wherein said excitation circuitry is operable to apply said first and second excitation signals and said processing circuitry is operable to determine said correction during a calibration routine that is performed from time to time and wherein said processing circuitry is operable to store the determined correction for use in correcting subsequent measurements until a further calibration routine is performed and an updated correction is determined.

### Claim 8 (depends on 1)

The conductivity sensor according to claim 1, wherein said excitation circuitry is operable to apply said first and second excitation signals and said processing circuitry is operable to determine said correction for each determined conductivity measurement.

### Claim 9 (depends on 7)

The conductivity sensor according to claim 7, wherein said processing circuitry is operable to determine status information indicative of the operating status of the sensor by comparing the updated correction with one or more previous corrections.

### Claim 10 (depends on 9)

The conductivity sensor according to claim 9, wherein said processing circuitry is operable to output a warning to a user in the event it determines that the updated correction is significantly different from one or more previously determined corrections.

### Claim 11 (depends on 1)

The conductivity sensor according to claim 1, wherein said excitation circuitry is operable to apply said excitation signals to said first electrode and wherein said processing circuitry is operable to determine said conductivity measurements from signals obtained from said second electrode.

### Claim 12 (depends on 1)

The conductivity sensor according to claim 1, wherein the frequencies of said first and second excitation signals are chosen so that said processing circuit can determine said correction by subtracting the measurements obtained for the first and second excitation frequencies.

### Claim 13

A method of determining the conductivity of a fluid, the method comprising:
passing the fluid through a flow conduit of a housing;
using excitation circuitry to generate first and second excitation signals having first and second excitation frequencies respectively and applying the excitation signals to at least one of first and second electrodes that are spaced apart along said flow conduit; and
using processing circuitry that is connected to said electrodes, to determine conductivity measurements of fluid flowing through the housing, wherein said conductivity measurements include a desired component that varies proportionally with the conductivity to be measured and an undesired component that varies with polarisation effects of the electrodes and characterised by using the conductivity measurements obtained for the first and second excitation frequencies to determine a correction for the polarisation effects and by applying the correction to conductivity measurements to generate corrected conductivity measurements that have been corrected for the polarisation effects of the electrodes.
