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US 9,618,844 B2Granted
Reagent and composition of resist
AssigneesToyo Gosei Co., Ltd., Osaka University
InventorSatoshi Enomoto
Life of this patent
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Abstract
Described is a reagent that enhances acid generation of a photoacid generator and a composition containing such reagent.
Claims16
A composition comprising:
- a reagent;
- a first compound that functions as a generation source of acid;
- wherein a feed of an energy to the reagent or to an acceptor for the reagent receiving the energy generates an intermediate from the reagent;
- wherein the intermediate enhances generation of acid from a precursor, wherein the intermediate is a ketyl radical;
- wherein the reagent is selected from the group consisting of a first reagent, a second reagent and a third reagent;
- wherein:
- the first reagent is represented by formula (I);
- wherein:
- R1 is a hydrogen atom;
- R2 is a phenyl group, an alkyl carbonyl group, an aryl carbonyl group, an alkyl group, an alkenyl group, an aralkyl group, an alkynyl group, an alkyl group containing a cyclic or poly cyclic moiety, or a substituent containing at least one atom other than carbon atom and hydrogen atom;
- and
- R3 is a hydrogen atom, a phenyl group, an alkyl carbonyl group, an aryl carbonyl group, an alkyl group, an alkenyl group, an aralkyl group, an alkynyl group, an alkyl group containing a cyclic or poly cyclic moiety, or a substituent containing at least one atom other than carbon atom and hydrogen atom;
- the second reagent is represented by formula (II):
- wherein:
- Z is a carbonyl group, a methylene group, an alkoxymethylene, an aryloxymethylene, or a hydroxymethylene;
- R4 is an aryl group or an aryl group containing an aromatic group and a substituent on the aromatic group containing at least one atom other than carbon atom and hydrogen atom;
- and
- R5 is a hydrogen atom, a phenyl group, an alkyl carbonyl group, an aryl carbonyl group, an alkyl group, an alkenyl group, an aralkyl group, an alkynyl group, an alkyl group containing a cyclic or poly cyclic moiety, or a substituent containing at least one atom other than carbon atom and hydrogen atom;
- the third reagent includes:
- a hydroxyl group;
- and
- a first cyclic moiety that contains a carbon atom bonded to the hydroxyl group and a hydrogen atom.
19 more elements
Dependencies are inferred from the claim text.