Switch element comprising a liquid-crystalline medium
AssigneeMerck Patent GmbH
InventorMichael Junge
Life of this patent
Estimating the term…
Abstract
The present invention relates to a switch element, which is thermoresponsive and which switches between a less transmissive state for radiant energy and a more transmissive state for radiant energy, and which comprises a liquid-crystalline medium. The invention furthermore relates to the use of the switch element for the regulation of radiant energy flow between interior spaces and the environment and for the regulation of the temperature of interior spaces. The invention furthermore relates to a liquid-crystalline medium, characterised in that it comprises 5-95% of a compound of the formula (I), in particular for use in the switch elements according to the invention.
Claims14
Switch element, characterised in that it is thermoresponsive and that it switches between a less transmissive state for radiant energy and a more transmissive state for radiant energy, comprising a liquid-crystalline medium, which comprises one or more compounds of the formula (I)
- where
- R11,R12 are on each occurrence, identically or differently, F, Cl, CN, NCS, R1—O—CO—, R1—CO—O—, an alkyl, alkoxy or thioalkoxy group having 1 to 10 C atoms, or an alkenyl, alkenyloxy or thioalkenyloxy group having 2 to 10 C atoms, or a monocyclic, bicyclic or tricyclic cycloalkyl or cycloalkenyl group having 3 to 10 C atoms, where one or more H atoms in the groups mentioned above may be replaced by F, Cl, CN, and where one or more CH2 groups in the groups mentioned above may be replaced by O, S, —O—CO— or —CO—O—;
- and where
- R1 is, identically or differently on each occurrence, an alkyl or an alkenyl group having 1 to 10 C atoms, in which one or more H atoms may be replaced by F or Cl;
- and
- is selected from
- is selected from
- and
- X is on each occurrence, identically or differently, F, Cl, CN or an alkyl, alkoxy or thioalkoxy group having 1 to 10 C atoms, where one or more H atoms in the groups mentioned above may be replaced by F or Cl and where one or more CH2 groups may be replaced by O or S;
- and
- Z11 is selected from —CF2O—, —OCF2—, —CH2CH2—, —CF2CF2—, —OCH2—, —CH2O—, —O—, and a single bond.
A thermoresponsive optical switch element comprising a liquid-crystalline medium having a phase transition temperature between 20° C. and 50° C., comprising one or more compounds according to formula (I-1a-3) in a total concentration of 5 to 95%, and at least one further compound of the formula (II-2a-2)
- wherein R21 is, identically or differently on each occurrence, an alkyl group having 1 to 10 C atoms, where one or more CH2 groups may be replaced by —O—CO— or —CO—O— so that the total concentration of the compounds of the formulas (I-1a-3), and (II-2a-2) is between 40 and 100%;
- wherein the compound of formula (I-1a-3), is of the formula:
- wherein R11 is, identically or differently on each occurence, an alkyl group having 1 to 10 C atoms, where one or more CH2 groups may be replaced by —O—CO— or —CO—O—.
Dependencies are inferred from the claim text.