Electrochemical process and device for hydrogen generation and storage
AssigneeGM Global Technology Operations LLC
InventorsJohn J. Vajo, Wen Li, Ping Liu, Frederick E. Pinkerton
Life of this patent
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Abstract
Both the reaction of hydride-forming compositions with hydrogen to form hydrides, and the decomposition of such hydrides to release hydrogen may be promoted electrochemically. These reactions may be conducted reversibly, and if performed in a suitable cell, the cell will serve as a hydrogen storage and release device.
Claims14
A method of reversibly storing hydrogen electrochemically, the method comprising applying a suitable electrical potential difference between first and second spaced apart electrodes in facing relation with at least one of the electrodes comprising one or more hydrogen-storing composition precursors selected from the group consisting of a hydride-forming composition, a borohydride-forming composition, an alanate-forming composition, an amide-forming composition, an imide-forming composition, and a hydroxide-forming composition, each of the first and second electrodes being in contact with a non-aqueous electrolyte suited for ionic conduction, the electrodes and electrolyte being maintained under a hydrogen atmosphere, the applied potential difference promoting reaction of the hydrogen with the hydrogen-storing composition precursor to thereby form, in or on, the at least one electrode, a hydrogen-storing composition consisting of at least one of the group consisting of a hydride, a borohydride, an alanate, an amide, an imide and a hydroxide, and,
- continuing to store hydrogen as the just-formed hydrogen-storing composition until hydrogen is needed, then,
- reversing the electrical potential difference between the first and second spaced apart electrodes to release a needed quantity of hydrogen at and from the at least one electrode and to at least partially restore a corresponding portion of the initial hydrogen-storing composition precursor of the at least one electrode to prepare the at least one electrode to again store hydrogen.
A method of reversibly storing hydrogen, the method comprising:
- applying a potential difference between first and second spaced-apart electrodes, immersed in a non-aqueous electrolyte, and in facing relation in an electrochemical cell, in which the first electrode comprises one or more of the metal elements Li, Mg, Na, K and Ca and the second electrode comprises a composition capable of storing a hydrogen-containing composition formed by reaction with hydrogen and cations of the one or more of the metal elements in the presence of the non-aqueous electrolyte, and concurrently contacting the second electrode with hydrogen gas,
- the applied electrical potential causing the electrochemical transport of metal cations of the one or more metal elements from the first electrode through the non-aqueous electrolyte to the second electrode where the metal cations react, under the applied potential, with hydrogen gas to store hydrogen as a hydrogen-containing composition comprising the one or more metals and hydrogen in the second electrode, the thus-formed hydrogen-containing composition being capable of releasing hydrogen gas, and cations of the one or more metals, when an electrical potential of opposite polarity is applied between the first and second electrodes.
A method of reversibly storing hydrogen, the method comprising:
- applying a potential difference between first and second spaced-apart electrodes, immersed in a non-aqueous electrolyte, and in facing relation in an electrochemical cell in which the first electrode comprises lithium and the second electrode comprises a composition capable of forming and/or storing a hydrogen-containing composition upon reaction of hydrogen and lithium cations in the presence of the non-aqueous electrolyte, and concurrently contacting the second electrode with hydrogen gas,
- the applied electrical potential causing the electrochemical transport of lithium cations from the first electrode through the non-aqueous electrolyte to the second electrode where the lithium cations react, under the applied potential, with hydrogen gas to store hydrogen as a hydrogen-containing composition comprising lithium and hydrogen in the second electrode, the thus-formed hydrogen-containing composition being capable of releasing hydrogen gas, and lithium cations, when an electrical potential of opposite polarity is applied between the first and second electrodes.
Dependencies are inferred from the claim text.