Methylidene malonate process

A process for the separation and isolation of methylidene malonates from a crude methylidene malonate comprising:

• a) adding a separation phase polymerization inhibitor to a crude or unpurified methylidene malonate reaction product;
• b) adding at least a portion of a separation phase polymerization inhibitor to the collection vessel used in the separation and/or isolation step,
• c) conducting the separation and/or isolation step to thereby collect the separated or isolated methylidene malonate in the collection vessel, wherein the separation phase polymerization inhibitor comprises at least one primary anionic polymerization inhibitor, at least one free radical polymerization inhibitor, and, optionally, at least one secondary anionic polymerization inhibitor.