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US 9,533,933 B2Granted
Process for preparing cyclododecanone
AssigneeEvonik Degussa GmbH
InventorsKevin Micoine, Ralf Meier, Juergen Herwig, Martin Roos, Harald Haeger, Luca Cameretti, Jens Doering
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Abstract
Cyclododecanone (CDON) is prepared by epoxidizing cyclododecene (CDEN) to epoxycyclododecane (CDAN epoxide), and rearranging the CDAN epoxide to CDON to obtain a mixture comprising said CDON and CDEN, wherein CDEN is separated from the CDON-containing mixture and sent to the epoxidation to CDAN epoxide in step a.
Claims13
A process for preparing cyclododecanone (CDON) by a reaction route I, comprising
- a. epoxidizing cyclododecene (CDEN) to epoxycyclododecane (CDAN epoxide), and
- b. rearranging the CDAN epoxide to CDON to obtain a mixture comprising said CDON and CDEN,
- wherein:
- CDEN is separated from the CDON-containing mixture and sent to the epoxidation to CDAN epoxide in step a;
- the CDAN epoxide from step a comprises cyclododecane (CDAN) which is at least partly removed prior to the rearrangement in step b;
- and
- the CDAN removed prior to the rearrangement in step b is sent to a reaction route II for preparation of CDON, comprising:
- c. hydrogenation of cyclododecatriene (CDT) to CDAN,
- d. oxidation of CDAN to give a mixture comprising cyclododecanol (CDOL) and CDON and
- e. dehydrogenation of CDOL to CDON.
7 more elements
Dependencies are inferred from the claim text.