Pesticidal compositions and related methods

A process comprising applying a pesticidal composition to an area to control a pest, in an amount sufficient to control such pest, wherein the pesticidal composition comprises a compound of formula I or any agriculturally acceptable salt thereof:

• wherein:
• (a) R1, R2, and R4 are independently selected from hydrogen, F, Cl, Br, I, substituted or unsubstituted C1-C6 alkyl, or substituted or unsubstituted C1-C6 haloalkyl,
• wherein each said R1, R2, and R4, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C3-C10 cycloalkyl, or C3-C10 halocycloalkyl, (each of which that may be substituted, may optionally be substituted with R10);
• (b) R3 is selected from hydrogen, F, Cl, Br, I, CN, NO2, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C1-C6 haloalkyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, OR10, C(═X1)R10, C(═X1)OR10, C(═X1)N(R10)2, N(R10)2, N(R10)C(═X1)R10, SR10, S(O)nOR10, or R10S(O)nR10,
• wherein each said R3, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, OR10, S(O)nOR10, C6-C20 aryl, or C1-C20 heterocyclyl, (each of which that may be substituted, may optionally be substituted with R10);
• (c) R5 is selected from H, F, Cl, Br, I, CN, NO2, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, C3-C10 cycloalkyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, OR10, C(═X1)R10, C(═X1)OR10, C(═X1)N(R10)2, N(R10)2, N(R10)C(═X1)R10, SR10, S(O)nOR10, or R10S(O)nR10,
• wherein each said R5, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, OR10, S(O)nOR10, C6-C20 aryl, or C1-C20 heterocyclyl, (each of which that may be substituted, may optionally be substituted with R10);
• (d) R6 is H, F, Cl, Br, I, substituted or unsubstituted C1-C6 alkyl, or C1-C6 haloalkyl,
• wherein each said R6, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, or C3-C10 halocycloalkenyl;
• (e) R7 is selected from hydrogen, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C2-C6 alkynyl, substituted or unsubstituted C1-C6 alkoxy, substituted or unsubstituted C3-C10 cycloalkyl, C1-C6 alkyl C2-C6 alkynyl wherein the alkyl and alkynyl is independently substituted or unsubstituted, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, C1-C6 alkyl C6-C20 aryl wherein the alkyl and aryl is independently substituted or unsubstituted), C1-C6 alkyl-(C3-C10 cyclohaloalkyl) wherein the alkyl and cyclohaloalkyl is independently substituted or unsubstituted, or C1-C6 alkyl-(C3-C10 cycloalkyl) wherein the alkyl and cycloalkyl is independently substituted or unsubstituted,
• wherein each said R7, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, OR10, S(O)nOR10, C6-C20 aryl, or C1-C20 heterocyclyl, R10 aryl, (each of which that may be substituted, may optionally be substituted with R10);
• (f) R8 is selected from substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C3-C10 halocycloalkyl substituted or unsubstituted C3-C10 cycloalkenyl, substituted or unsubstituted C6-C20 aryl, or substituted or unsubstituted C1-C20 heterocyclyl,
• wherein each said R8, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 haloalkyl, substituted or unsubstituted C2-C6 haloalkenyl, substituted or unsubstituted C1-C6 haloalkyloxy, substituted or unsubstituted C2-C6 haloalkenyloxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C3-C10 cycloalkenyl, substituted or unsubstituted C3-C10 halocycloalkyl, substituted or unsubstituted C3-C10 halocycloalkenyl, oxo, OR10, S(O)nR10, substituted or unsubstituted C6-C20 aryl, or substituted or unsubstituted C1-C20 heterocyclyl, (each of which, when substituted, is substituted with R10);
• (g) L is N(R9);
• (h) La is selected from R9, OR9, N(R9)2, N(R9)(R11), N(R9)(OR11), NR9)C(═X1)R9, N(R9)C(═X1)(R11), C(R9)3, C(R9)(R11)(R12), or SR9;
• optionally L and La are connected in a cyclic arrangement, which forms 3-8 membered heterocycles or carbocycles including L and La,
• wherein the cyclic arrangement contains none or at least one of O, S, or N heteroatoms, and the cyclic arrangement is unsubstituted or substituted,
• wherein, when substituted, the cyclic arrangement has one or more substituents selected from F, Cl, Br, I, CN, NO2, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C2-C6 alkynyl, substituted or unsubstituted C1-C6 haloalkyl, substituted or unsubstituted C2-C6 haloalkenyl, substituted or unsubstituted C1-C6 haloalkyloxy, substituted or unsubstituted C2-C6 haloalkenyloxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C3-C10 cycloalkenyl, substituted or unsubstituted C3-C10 halocycloalkyl, substituted or unsubstituted C3-C10 halocycloalkenyl, N(R9)S(O)nR11, oxo, OR9, S(O)nOR9, R9S(O)nR11, S(O)nR9, substituted or unsubstituted C6-C20 aryl, or substituted or unsubstituted C1-C20 heterocyclyl (each of which, when substituted, is substituted with R10);
• (i) R9, R11, R12, and R13 are independently selected from hydrogen, CN, NO2, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C3-C10 halocycloalkyl, substituted or unsubstituted C3-C10 cycloalkenyl, substituted or unsubstituted C6-C20 aryl, or substituted or unsubstituted C1-C20 heterocyclyl,
• wherein each of said R9, R11, and R12, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 haloalkyl, substituted or unsubstituted C2-C6 haloalkenyl, substituted or unsubstituted C1-C6 haloalkyloxy, substituted or unsubstituted C2-C6 haloalkenyloxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C3-C10 cycloalkenyl, substituted or unsubstituted C3-C10 halocycloalkyl, substituted or unsubstituted C3-C10 halocycloalkenyl, oxo, OR10, C(═X1)R10, S(O)nR10, substituted or unsubstituted C6-C20 aryl, or substituted or unsubstituted C1-C20 heterocyclyl, (each of which, when substituted, is substituted with R10);
• (j) R10 is H, F, Cl, Br, I, CN, NO2, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, substituted or unsubstituted C2-C6 alkenyloxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C3-C10 cycloalkenyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, substituted or unsubstituted S(O)nC1-C6 alkyl, or substituted or unsubstituted N(C1-C6)alkyl)2,
• wherein each said R10, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, OC1-C6 alkyl, OC1-C6 haloalkyl, S(O)nC1-C6 alkyl, S(O)nOC1-C6 alkyl, C6-C20 aryl, or C1-C20 heterocyclyl;
• (k) Q is (each independently) O or S;
• (l) Z is (each independently) O, S, CH2, NR_, or NOR13;
• (m) X1 is (each independently) O or S;
• (n) n is 0, 1, or 2;
• and
• (o) x is 0 or 1.