# US 9,520,610 B2 · Method of manufacturing 5-layer MEA having improved electrical conductivity

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- Number: US 9,520,610 B2
- Document ID: US9520610B2
- Status: Granted
- Kind: B2
- Application number: 12/001,004
- Filed: 2007-12-07
- Published: 2010-11-04
- Granted: 2016-12-13
- Earliest claimed: 2007-05-30
- Assignees: Hyundai Motor Company
- Applicants: Young Soo Kim; Ki Sub Lee
- Inventors: Young Soo Kim; Ki Sub Lee
- Web page: https://patentgrep.com/patent/US9520610B2

## CPC

- H01M 8/1004: characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence)
- H01M 4/881: {Electrolytic membranes}
- H01M 2008/1095: {Fuel cells with polymeric electrolytes}
- Y02E 60/50: Fuel cells
- Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

The present invention provides a method of manufacturing a 5-layer MEA having an improved electrical conductivity capable of reducing electrical contact resistance between a catalyst layer and a micro-porous layer (MPL) by forming a new electrical conductive layer between the catalyst layer of a 3-layer MEA and the MPL.

## Claims

### Claim 1

A method of manufacturing a 5-layer MEA having an improved electrical conductivity, the method comprising:
providing a 3-layer MEA having an electrolyte membrane and catalyst layers formed on both sides of the electrolyte membrane, wherein the 3-layer MEA is formed by steps comprising mixing a Nafion solution and a platinum catalyst in a solvent mixture to form a slurry, coating the formed slurry on a release paper, drying the slurry coated on the release paper, cutting the thus-coated electrode into a predetermined size and placing the cut electrode in contact with both sides of a membrane and then connected to one another by a hot press process;
forming a micro-porous layer on a surface of a gas diffusion layer, wherein the micro-porous layer includes a Teflon as a binder;
coating an electrical conductive layer on the micro-porous layer, wherein the electrical conductive layer is formed in a slurry by mixing a Nafion solution as a binder and carbon particles (carbon black) in isopropanol alcohol (IPA) and distilled water (DI water) and the electrical conductive layer including the Nafion as the binder and the micro-porous layer including the Teflon as the binder are first connected to each other;
bringing the gas diffusion layer having the micro-porous layer coated with the electrical conductive layer into contact with each of the catalyst layers of the 3-layer MEA such that the electrical conductive layer is disposed between the catalyst layer of the 3-layer MEA and the micro-porous layer formed on the surface of the gas diffusion layer; and
thermally compressing the contacted layers so as to connect each of the catalyst layers of the 3-layer MEA and the electrical conductive layer, wherein both the electrical conductive layer and the catalyst layer include the Nafion as the binders and are connected to each other as being thermally compressed.

### Claim 2 (depends on 1)

The method of claim 1, wherein the coating of the electrical conductive layer on the micro-porous layer is conducted by a method selected from the group consisting of spray coating, bar coating, and slot die coating.

### Claim 3 (depends on 1)

The method of claim 1, wherein each of the catalyst layers, the electrical conductive layer and the micro-porous layer includes carbon as an electrical conductive material.

### Claim 4 (depends on 1)

The method of claim 1, wherein the slurry for the electrical conductive layer contains the Nafion and the carbon black mixed in a weight ratio of 1:1.

### Claim 5 (depends on 1)

The method of claim 1, wherein the slurry for the electrical conductive layer is coated at 0.3 mg carbon/cm2 on the micro-porous layer.

### Claim 6 (depends on 1)

The method of claim 1, wherein the electrical conductive layer was dried at 80° C. in an oven for 30 minutes.

### Claim 7 (depends on 1)

The method of claim 1, wherein the electrical conductive layers coated on the micro-porous layer of the gas diffusion layer are connected to each of the catalyst layers of the 3-layer MEA by a hot press process at 125° C. for 5 minutes.