# US 9,520,605 B2 · Fuel cell system

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- Number: US 9,520,605 B2
- Document ID: US9520605B2
- Status: Granted
- Kind: B2
- Application number: 14/385,303
- Filed: 2012-03-15
- Published: 2015-06-25
- Granted: 2016-12-13
- Earliest claimed: 2012-03-15
- Assignees: Toyota Jidosha Kabushiki Kaisha
- Applicants: Masaaki Matsusue; Kotaro Ikeda; Yumi Inoue
- Inventors: Masaaki Matsusue; Kotaro Ikeda; Yumi Inoue
- Web page: https://patentgrep.com/patent/US9520605B2

## CPC

- H01M 8/04873: {of the individual fuel cell}
- H01M 8/04223: during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
- H01M 8/04225: during start-up
- H01M 8/04302: applied during start-up
- H01M 8/04313: characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M 8/04559: {of fuel cell stacks}
- H01M 8/04604: {Power, energy, capacity or load}
- H01M 8/0488: {of fuel cell stacks}
- H01M 8/1004: characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence)
- H01M 8/1018: Polymeric electrolyte materials
- H01M 8/2457: with both reactants being gaseous or vaporised
- H01M 8/04238: {Depolarisation}
- H01M 8/04679: {of fuel cell stacks}
- H01M 2008/1095: {Fuel cells with polymeric electrolytes}
- H01M 2250/20: Fuel cells in motive systems, e.g. vehicle, ship, plane
- Y02E 60/50: Fuel cells
- Y02T 90/40: Application of hydrogen technology to transportation, e.g. using fuel cells
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02T: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION

## Abstract

A fuel cell system according to the present invention comprises: a fuel cell including a membrane-electrode assembly in which electrodes, each having a catalyst layer, are arranged on both surfaces of a polymer electrolyte membrane; and a control apparatus which controls an output voltage of the fuel cell. If a target voltage of the fuel cell is set so as to be equal to or higher than a catalyst dissolution voltage at which a catalyst in the catalyst layer is dissolved and the amount of an oxide film formed on the catalyst layer is estimated to be less than a first predetermined amount, the control apparatus controls the output voltage of the fuel cell so as to be equal to an oxide film formation voltage, being lower than the catalyst dissolution voltage, until the amount of the oxide film is estimated to be equal to or greater than the first predetermined amount and then controls the output voltage so as to be equal to the target voltage.

## Claims

### Claim 1

A fuel cell system comprising:
a fuel cell including a membrane-electrode assembly in which electrodes, each having a catalyst layer, are arranged on both surfaces of a polymer electrolyte membrane; and
a control apparatus programmed to control an output voltage of the fuel cell;
wherein, if a target voltage of the fuel cell is set so as to be equal to or higher than a catalyst dissolution voltage at which a catalyst in the catalyst layer is dissolved and an amount of an oxide film formed on the catalyst layer is estimated to be less than a first predetermined amount, the control apparatus programmed to control the output voltage of the fuel cell so as to be equal to an oxide film formation voltage, being lower than the catalyst dissolution voltage, until the amount of the oxide film is estimated to be equal to or greater than the first predetermined amount, and then programmed to control the output voltage so as to be equal to the target voltage.

### Claim 2 (depends on 1)

The fuel cell system according to claim 1, wherein, while the control apparatus is programmed to control the output voltage of the fuel cell so as to be equal to the oxide film formation voltage, being lower than the catalyst dissolution voltage, until the amount of the oxide film is estimated to be equal to or greater than the first predetermined amount, the control apparatus programmed to control the output voltage of the fuel cell such that the oxide film formation voltage is held at a constant voltage.

### Claim 3 (depends on 1)

The fuel cell system according to claim 1, wherein, while the control apparatus is programmed to control the output voltage of the fuel cell so as to be equal to the oxide film formation voltage, being lower than the catalyst dissolution voltage, until the amount of the oxide film is estimated to be equal to or greater than the first predetermined amount, the control apparatus programmed to control the output voltage of the fuel cell so that the oxide film formation voltage increases gradually.

### Claim 4 (depends on 1)

The fuel cell system according to claim 1, wherein, if the target voltage of the fuel cell is set so as to be equal to or higher than the catalyst dissolution voltage at which the catalyst in the catalyst layer is dissolved and the amount of the oxide film formed on the catalyst layer is estimated to be less than the first predetermined amount at a start of operation of the fuel cell, the control apparatus programmed to control the output voltage of the fuel cell so as to be equal to the oxide film formation voltage, being lower than the catalyst dissolution voltage, until the amount of the oxide film is estimated to be equal to or greater than the first predetermined amount, and then programmed to control the output voltage so as to be equal to the target voltage.

### Claim 5 (depends on 1)

The fuel cell system according to claim 1, wherein, if the target voltage of the fuel cell is set so as to be equal to or higher than the catalyst dissolution voltage at which the catalyst in the catalyst layer is dissolved and the amount of the oxide film formed on the catalyst layer is estimated to be less than the first predetermined amount at a start of a scavenging operation for scavenging an inside of the fuel cell, the control apparatus programmed to control the output voltage of the fuel cell so as to be equal to the oxide film formation voltage, being lower than the catalyst dissolution voltage, until the amount of the oxide film is estimated to be equal to or greater than the first predetermined amount, and then programmed to control the output voltage so as to be equal to the target voltage.