# US 9,520,603 B2 · Fuel cell system

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- Number: US 9,520,603 B2
- Document ID: US9520603B2
- Status: Granted
- Kind: B2
- Application number: 13/981,296
- Filed: 2013-01-10
- Published: 2014-09-04
- Granted: 2016-12-13
- Earliest claimed: 2012-03-29
- Assignees: Panasonic Intellectual Property Management Co., Ltd.
- Applicants: Panasonic Corporation
- Inventors: Manabu Takahashi; Motomichi Katou; Masato Kihara
- Web page: https://patentgrep.com/patent/US9520603B2

## CPC

- H01M 8/04225: during start-up
- C01B 3/384: with external heating of the catalyst
- H01M 8/04037: {Electrical heating}
- H01M 8/04373: {of auxiliary devices, e.g. reformers, compressors, burners}
- H01M 8/04604: {Power, energy, capacity or load}
- H01M 8/04664: Failure or abnormal function
- H01M 8/04738: {of auxiliary devices, e.g. reformer, compressor, burner}
- H01M 8/04776: {at auxiliary devices, e.g. reformer, compressor, burner}
- H01M 8/0618: {Reforming processes, e.g. autothermal, partial oxidation or steam reforming}
- H01M 8/0668: Removal of carbon monoxide or carbon dioxide
- H01M 8/0675: {Removal of sulfur}
- H01M 8/2457: with both reactants being gaseous or vaporised
- C01B 2203/0233: the reforming step being a steam reforming step
- C01B 2203/0283: containing a CO-shift step, i.e. a water gas shift step
- C01B 2203/044: Selective oxidation of carbon monoxide
- C01B 2203/047: the impurity being carbon monoxide
- C01B 2203/066: with fuel cells
- C01B 2203/0811: by combustion of fuel
- C01B 2203/085: by electric heating
- C01B 2203/1619: Measuring the temperature
- Y02E 60/50: Fuel cells
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A fuel cell system (100) includes: a fuel cell (60); a fuel processor (41) including a reformer (43) and a CO reducer (44, 45); a combustor (42); a first air supply device (46); an electric heater (50); a power supply device (200); a power outage detector (11); and a controller (10). The controller is configured such that, in a power outage state where the power outage detector has detected the power outage before the fuel cell generates electric power, the controller performs at least one of: increasing a supply amount of the combustion air to be greater than in a power supplied state where the power outage detector does not detect the power outage; and decreasing a supply amount of the combustible gas to be less than in the power supplied state, and decreases an amount of heating by the electric heater.

## Claims

### Claim 1

A fuel cell system interconnected to a system power supply, the fuel cell system comprising:
a fuel cell configured to generate electric power by causing a reaction between a fuel gas containing hydrogen and an oxidizing gas;
a fuel processor including a reformer and a CO reducer, the reformer being configured to generate the fuel gas by causing a reaction between a raw material containing a hydrocarbon component and reforming water, the CO reducer being configured to reduce carbon monoxide in the fuel gas;
a combustor configured to heat the fuel processor by combusting a combustible gas supplied to the combustor;
a first air supply device configured to supply combustion air to the combustor;
an electric heater configured to heat the CO reducer;
a power supply device configured to supply electric power to the electric heater;
a controller; and
a power outage detector configured to detect a power outage in which no electric power is supplied from the system power supply to the fuel cell system, the power outage detector outputting power outage information indicative of a power outage state to the controller;
wherein
the controller is programmed to determine that a current state is the power outage state when the controller receives an input of the power outage information from the power outage detector before the fuel cell generates electric power,
in the power outage state,
the controller is programmed to at least one of: increasing a supply amount of the combustion air to be greater than in a power supplied state where the power outage detector does not detect the power outage; and decreasing a supply amount of the combustible gas to be less than in the power supplied state, and decreases an amount of heating by the electric heater to be less than in the power supplied state in a start-up step at the beginning and during start up.

### Claim 2 (depends on 1)

The fuel cell system according to claim 1, further comprising:
a first temperature detector configured to detect a temperature of the reformer,
wherein the controller is programmed such that, if a first detected temperature detected by the first temperature detector is higher than or equal to a first predetermined temperature, the controller increases the supply amount of the combustion air or increases the amount of heating by the electric heater.

### Claim 3 (depends on 1)

The fuel cell system according to claim 1, further comprising: a second temperature detector configured to detect a temperature of the CO reducer,
wherein the controller is programmed such that, if a second detected temperature detected by the second temperature detector is lower than or equal to a second predetermined temperature, the controller increases the supply amount of the combustion air or increases the amount of heating by the electric heater.

### Claim 4 (depends on 1)

The fuel cell system according to claim 1, further comprising:
a first temperature detector configured to detect a temperature of the reformer; and
a second temperature detector configured to detect a temperature of the CO reducer,
wherein the controller is programmed such that, if a first detected temperature detected by the first temperature detector is higher than a second detected temperature detected by the second temperature detector, and a difference between the first detected temperature and the second detected temperature is greater than or equal to a third predetermined temperature, the controller performs at least one of: increasing the supply amount of the combustion air; decreasing the supply amount of the combustible gas; and increasing the amount of heating by the electric heater.

### Claim 5 (depends on 1)

The fuel cell system according to claim 1, wherein
the controller is programmed such that, if a time elapsed from when the combustor starts the combusting has reached a predetermined time, the controller increases the amount of heating by the electric heater.

### Claim 6 (depends on 1)

The fuel cell system according to claim 1, further comprising:
a first temperature detector configured to detect a temperature of the reformer;
a second temperature detector configured to detect a temperature of the CO reducer; a water supply device configured to supply the reforming water to the fuel processor; and an evaporator configured to perform heat exchange with the CO reducer to generate steam from the reforming water, wherein
the controller is programmed such that, if a second detected temperature detected by the second temperature detector is lower than a fourth predetermined temperature, the controller decreases a supply amount of the reforming water to be less than in the power supplied state.

### Claim 7 (depends on 6)

The fuel cell system according to claim 6, wherein
the controller is programmed such that, if the second detected temperature is higher than or equal to the fourth predetermined temperature, the controller increases the supply amount of the reforming water.

### Claim 8 (depends on 6)

The fuel cell system according to claim 6, wherein
the controller is programmed such that, if the second detected temperature is higher than or equal to the fourth predetermined temperature and a first detected temperature detected by the first temperature detector is higher than or equal to a fifth predetermined temperature, the controller brings the supply amount of the reforming water back to the supply amount of the reforming water in the power supplied state.

### Claim 9 (depends on 1)

The fuel cell system according to claim 1, wherein
the CO reducer includes: a shift converter configured to reduce carbon monoxide by reacting the carbon monoxide with water; and a selective oxidizer configured to reduce carbon monoxide by reacting the carbon monoxide with oxygen,
the fuel cell system further comprising a second air supply device configured to supply air to the selective oxidizer, wherein
the controller is programmed to cause the second air supply device to supply air such that the air supplied to the selective oxidizer is in an amount greater than in the power supplied state.

### Claim 10 (depends on 1)

The fuel cell system according to claim 1, further comprising:
a first desulfurizer configured to remove sulfur from the raw material without reacting the sulfur contained in the raw material with hydrogen; and
a second desulfurizer configured to remove sulfur from the raw material by reacting the sulfur contained in the raw material with hydrogen, wherein
the electric heater heats the CO reducer and the second desulfurizer, and the
controller is programmed to increase a proportion of an amount of the sulfur removed by the first desulfurizer to an amount of the sulfur removed by the second desulfurizer as compared to the proportion in the power supplied state.

### Claim 11 (depends on 1)

The fuel cell system according to claim 1, wherein the fuel processor is configured such that a flue gas generated through the combusting by the combustor heats the CO reducer after heating the reformer.
