# US 9,519,233 B2 · Toner formulations having improved toner usage efficiency and method to make the same > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 9,519,233 B2 - Document ID: US9519233B2 - Status: Granted - Kind: B2 - Application number: 14/580,864 - Filed: 2014-12-23 - Published: 2015-08-20 - Granted: 2016-12-13 - Earliest claimed: 2014-02-14 - Assignees: Lexmark International, Inc. - Applicants: Lexmark International, Inc. - Inventors: Kasturi Rangan Srinivasan - Web page: https://patentgrep.com/patent/US9519233B2 ## CPC - G03G 9/0802: {Preparation methods} - G03G 9/0808: {by dry mixing the toner components in solid or softened state} - G03G 9/081: {by mixing the toner components in a liquefied state; melt kneading; reactive mixing} - G03G 9/0819: {characterised by the dimensions of the particles} - G03G 9/08711: {with esters of acrylic or methacrylic acid} - G03G 9/08755: {Polyesters} - G03G 9/09708: {Inorganic compounds} - G03G 9/09716: {treated with organic compounds} - G03G 9/09725: {Silicon-oxides; Silicates} - G03G: ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY ## Abstract A toner composition and a method of making a toner composition wherein toner particles having an average size in the range of 1-25 μm may be mixed with large fumed silica particles sized 70 nm to 120 nm and medium fumed silica particles sized 30 nm to 60 nm and optionally alumina particles surface treated with an inorganic/organic compound. The large sized fumed silica particles are present in the range of 0.1% to 2% by weight of the toner composition. The medium sized fumed silica particles are present in the range of 0.1% to 2% by weight of the toner composition. The alumina particles surface treated with an inorganic/organic compound may be present in the range of 0.01% to 1.0% by weight of the toner composition. ## Claims ### Claim 1 A method for making a toner composition comprising the steps of: providing toner particles; mixing medium sized fumed silica particles with the toner particles, the medium sized fumed silica particles have a primary particle size in the range of 30 nm to 60 nm and are present in the range of 0.1% to 2.0% by weight of the toner composition; and mixing large sized fumed silica particles with the toner particles and the medium sized fumed silica particles mixture, the large sized fumed silica particles have a primary particle size in the range of 70 nm to about 120 nm, and are present in the range of 0.1% to 2% by weight of the toner composition. ### Claim 2 (depends on 1) The method of claim 1, wherein the medium sized fumed silica particles are treated with a surface treatment selected from the group consisting of hexamethyldisilazane and polydimethylsiloxane. ### Claim 3 (depends on 1) The method of claim 1, wherein the large sized fumed silica particles are treated with a surface treatment selected from the group consisting of hexamethyldisilazane, polydimethylsiloxane, dimethyldichlorosilane, dimethyldiethoxysilane octyltrialkoxysilane and combinations thereof. ### Claim 4 (depends on 1) The method of claim 1, wherein the ratio of the medium sized fumed silica particles to the large sized fumed silica particles is about 95/5 to about 5/95. ### Claim 5 (depends on 4) The method of claim 4, wherein the ratio of the medium sized fumed silica particles to the large sized fumed silica particles is about 95/5 to about 50/50. ### Claim 6 (depends on 1) The method of claim 1, further comprising the step of mixing alumina particles with the toner particles, the medium sized fumed silica particles and the large sized fumed silica particles, wherein the alumina particles are present in the range of 0.01% to 1.0% by weight of the toner composition. ### Claim 7 (depends on 6) The method of claim 6, wherein the alumina particles are surface treated with octylsilane. ### Claim 8 (depends on 1) The method of claim 1, further comprising mixing small sized silica particles with the toner particles, the medium sized fumed silica particles, the large sized fumed silica particles, and the alumina particles, wherein the small sized silica particles have a primary particle size in the range of 2 nm to 20 nm and are present in the range of 0.1% to 0.5% by weight of the toner composition. ### Claim 9 (depends on 1) The method of claim 1, wherein the toner particles comprise a styrene-acrylate copolymer resin. ### Claim 10 (depends on 1) The method of claim 1, wherein the toner particles comprise a polyester resin. ### Claim 11 (depends on 1) The method of claim 1, wherein the large sized fumed silica particles are present in the range of 0.25% to 1% by weight of the toner composition. ### Claim 12 (depends on 1) The method of claim 1, wherein the large sized fumed silica particles are sized 70 nm to 80 nm. ### Claim 13 A method for making a toner composition, comprising the steps of: providing toner particles; mixing medium sized fumed silica particles with the toner particles and the medium sized fumed silica particles have a primary particle size in the range of 30 nm to 60 nm and are present in the range of 0.1% to 2.0% by weight of the toner composition; mixing large sized fumed silica particles with the toner particles and the medium sized fumed silica particles mixture and the large sized fumed silica particles have a primary particle size in the range of 70 nm to about 120 nm and are present in the range of 0.1% to 2% by weight of the toner composition; mixing alumina particles with the toner particles, the medium sized fumed silica particles and the large sized fumed silica particles and the alumina particles are present in the range of 0.01% to 1.0% by weight of the toner composition: and mixing small sized silica particles having a primary particle size in the range of 2 nm to 20 nm and titania with the toner particles, the medium sized fumed silica particles, the large sized fumed silica particles and the alumina particles to form a toner composition. ### Claim 14 (depends on 13) The method of claim 13, wherein the medium sized fumed silica particles are treated with a surface treatment selected from the group consisting of hexamethyldisilazane and polydimethylsiloxane. ### Claim 15 (depends on 13) The method of claim 13, wherein the large sized fumed silica particles are treated with a surface treatment selected from the group consisting of hexamethyldisilazane, polydimethylsiloxane, dimethyldichlorosilane, dimethyldiethoxysilane octyltrialkoxysilane and combinations thereof. ### Claim 16 (depends on 13) The method of claim 13 wherein the titania is acicular titanium oxide.