# US 9,519,031 B2 · Circuits and methods for impedance determination using active measurement cancelation > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 9,519,031 B2 - Document ID: US9519031B2 - Status: Granted - Kind: B2 - Application number: 14/108,068 - Filed: 2013-12-16 - Published: 2015-06-18 - Granted: 2016-12-13 - Earliest claimed: 2013-12-16 - Assignees: Battelle Energy Alliance, LLC - Applicants: Battelle Energy Alliance, LLC - Inventors: David K. Jamison - Web page: https://patentgrep.com/patent/US9519031B2 ## CPC - G01R 31/389: Measuring internal impedance, internal conductance or related variables - G01R 27/02: Measuring real or complex resistance, reactance, impedance, or other two-pole characteristics derived therefrom, e.g. time constant (by measuring phase angle only G01R25/00) - G01R 31/392: Determining battery ageing or deterioration, e.g. state of health - G01R: MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES (indicating correct tuning of resonant circuits H03J3/12) ## Abstract A delta signal and opposite delta signal are generated such that a sum of the two signals is substantially zero. The delta signal is applied across a first set of electrochemical cells. The opposite delta signal is applied across a second set of electrochemical cells series connected to the first set. A first held voltage is established as the voltage across the first set. A second held voltage is established as the voltage across the second set. A first delta signal is added to the first held voltage and applied to the first set. A second delta signal is added to the second held voltage and applied to the second set. The current responses due to the added delta voltages travel only into the set associated with its delta voltage. The delta voltages and the current responses are used to calculate the impedances of their associated cells. ## Claims ### Claim 1 An impedance measurement circuit, comprising: a signal creator configured to generate a delta signal and an opposite delta signal, which is substantially equal and opposite in amplitude to the delta signal, such that a sum of the delta signal and the opposite delta signal is substantially zero at any instant of time; a first application circuit configured to apply the delta signal across a first set of cells comprising one or more electrochemical cells of a plurality of electrochemical cells, wherein the plurality of electrochemical cells are operably coupled in series between a first end terminal and a second end terminal; a second application circuit configured to apply the opposite delta signal while the delta signal is being applied and across a second set of cells comprising one or more electrochemical cells of the plurality of electrochemical cells; and a measurement unit configured to measure a response signal across the second set of cells when the delta signal and the opposite delta signal are being applied; wherein the second set of cells is different from the first set of cells and there is substantially no change in current between the first end terminal and the second end terminal due to the application of the delta signal and the opposite delta signal. ### Claim 2 (depends on 1) The impedance measurement circuit of claim 1, wherein the measurement unit is further configured to measure a held voltage across the second set of cells when the delta signal and the opposite delta signal are not being applied and further comprising an analysis module configured for analyzing the response signal relative to the held voltage to determine an impedance of the second set of cells. ### Claim 3 (depends on 1) The impedance measurement circuit of claim 1, wherein: the first set of cells comprises a first cell of the plurality of electrochemical cells; and the second set of cells comprises a second cell of the plurality of electrochemical cells that is different from the first cell. ### Claim 4 (depends on 3) The impedance measurement circuit of claim 3, wherein the first application circuit and the measurement unit are operably coupled to form an active measurement unit, and the active measurement unit is configured to be selectively coupled to each of the plurality of electrochemical cells as the first cell. ### Claim 5 (depends on 3) The impedance measurement circuit of claim 3, wherein the second application circuit is configured to be selectively coupled to each of the plurality of electrochemical cells as the second cell. ### Claim 6 (depends on 1) The impedance measurement circuit of claim 1, wherein: the second set of cells comprises all of the plurality of electrochemical cells; and the first set of cells comprises fewer than all of the plurality of electrochemical cells. ### Claim 7 (depends on 6) The impedance measurement circuit of claim 6, wherein the first set of cells comprises a single electrochemical cell of the plurality of electrochemical cells. ### Claim 8 (depends on 7) The impedance measurement circuit of claim 7, wherein the first application circuit and the measurement unit are operably coupled to form an active measurement unit and the active measurement unit is configured to be selectively coupled to each of the plurality of electrochemical cells as the first set of cells. ### Claim 9 (depends on 1) The impedance measurement circuit of claim 1, further comprising: a source/load unit for respectively supplying charge pulses and discharge pulses to the plurality of electrochemical cells, wherein the charge pulses and discharge pulses include a transition rate; and wherein the first application circuit includes a transition modifying circuit operably coupled between the source/load unit and a terminal of the plurality of electrochemical cells, the transition modifying circuit comprising at least one circuit element configured to generate an adjusted transition rate on the terminal that is slower than the transition rate and sufficient to reduce degradation of one or more charge capacity characteristics of the plurality of electrochemical cells. ### Claim 10 An impedance measurement circuit, comprising; an active measurement unit configured to: generate a delta signal; apply the delta signal across a first set of cells comprising one or more electrochemical cells of a plurality of electrochemical cells; wherein the plurality of electrochemical cells are operably couples in series between a first end terminal and a second end terminal; and measure a response signal across the first set of cells when the delta signal is being applied; an inverter unit configured to generate an opposite delta signal which is substantially equal and opposite in amplitude to the delta signal, such that a sum of the delta signal and the opposite delta signal is substantially zero at any instant of time; and a cancelation unit configured to apply the opposite delta signal while the delta signal is being applied and across a second set of cells comprising one or more electrochemical cells of the plurality of electrochemical cells; wherein the second set of cells is different from the first set of cells and there is substantially no change in current between the first end terminal and the second end terminal due to the application of the delta signal and the opposite delta signal. ### Claim 11 (depends on 10) The impedance measurement circuit of claim 10, wherein the active measurement unit is further configured to measure a held voltage across the first set of cells when the delta signal and the opposite delta signal are not being applied and further comprising an analysis module configured for analyzing the response signal as a current when the delta signal is applied to determine an impedance of the first set of cells. ### Claim 12 (depends on 10) The impedance measurement circuit of claim 10, wherein: the first set of cells comprises a first cell of the plurality of electrochemical cells; and the second set of cells comprises a second cell of the plurality of electrochemical cells that is different from the first cell. ### Claim 13 (depends on 10) The impedance measurement circuit of claim 10, wherein the active measurement unit is configured to be selectively coupled to each of the plurality of electrochemical cells as the first set of cells. ### Claim 14 (depends on 10) The impedance measurement circuit of claim 10, wherein the cancelation unit is configured to be selectively coupled to each of the plurality of electrochemical cells as the second set of cells. ### Claim 15 (depends on 10) The impedance measurement circuit of claim 10, wherein: the second set of cells comprises all of the plurality of electrochemical cells; and the first set of cells comprises fewer than all of the plurality of electrochemical cells. ### Claim 16 (depends on 15) The impedance measurement circuit of claim 15, wherein the active measurement unit is configured to be selectively coupled to each of the plurality of electrochemical cells as the first set of cells. ### Claim 17 An impedance measurement circuit, comprising: a signal creator configured to generate a delta signal; an application unit configured to apply the delta signal across at least one electrochemical cell of a plurality of electrochemical cells wherein the plurality of electrochemical cells are operably coupled in series between a first end terminal and a second end terminal; an inverter unit configured to generate an opposite delta signal, which is substantially equal and opposite in amplitude to the delta signal, such that a sum of the delta signal and the opposite delta signal is substantially zero at any instant of time; a plurality of cancelation circuits, each cancelation circuit configured to apply a portion of the opposite delta signal across a corresponding electrochemical cell of the plurality of electrochemical cells while the delta signal is being and such that there is substantially no change in current between the first end terminal and the second end terminal due to the application of the delta signal and the opposite delta signal; and a measurement unit configured to measure a response signal across the at least one electrochemical cell when the delta signal and the opposite delta signal are being applied. ### Claim 18 (depends on 17) The impedance measurement circuit of claim 17, wherein the measurement unit is further configured to measure a held voltage across the at least one electrochemical cell when the delta signal and the opposite delta signal are not being applied and further comprising an analysis module configured for analyzing the response signal as a current relative to the held voltage to determine an impedance of the at least one electrochemical cell. ### Claim 19 (depends on 17) The impedance measurement circuit of claim 17, wherein: the signal creator, the application unit, and the measurement unit are operably coupled to form an active measurement unit and the active measurement unit is configured to be selectively coupled to each of the plurality of electrochemical cells as the at least one electrochemical cell; and each cancelation circuit of the plurality of cancelation circuits is configured to apply a portion of the delta signal across a corresponding electrochemical cell, wherein the corresponding electrochemical cells comprise all the electrochemical cells in the plurality except the at least one electrochemical cell. ### Claim 20 (depends on 19) The impedance measurement circuit of claim 19, wherein the portion of the delta signal is substantially equal for each cancelation circuit of the plurality of cancelation circuits. ### Claim 21 (depends on 19) The impedance measurement circuit of claim 19, wherein the portion of the delta signal is different for each cancelation circuit of the plurality of cancelation circuits. ### Claim 22 A method of measuring impedance, comprising: generating a delta signal; generating an opposite delta signal, which is substantially equal and opposite in amplitude to the delta signal, such that a sum of the delta signal and the opposite delta signal is substantially zero at any instant of time during an application period for the delta signal and the opposite delta signal; applying the delta signal across a first set of cells comprising one or more electrochemical cells of a plurality of electrochemical cells, wherein the plurality of electrochemical cells are operably coupled in series between a first end terminal and a second end terminal; applying the opposite delta signal across a second set of cells comprising one or more electrochemical cells of the plurality of electrochemical cells, wherein the second set of cells is different from the first set of cells and such that there is substantially no change in current between the first end terminal and the second end terminal due to the application of the delta signal and the opposite delta signal; and measuring a current response signal into the second set of cells when the delta signal and the opposite delta signal are being applied. ### Claim 23 (depends on 22) The method of claim 22, wherein: applying the delta signal across the first set of cells comprises applying the delta signal across a first cell of the plurality of electrochemical cells; and applying the opposite delta signal across the second set of cells comprises applying the opposite delta signal across a second cell of the plurality of electrochemical cells that is different from the first cell. ### Claim 24 (depends on 23) The method of claim 23, wherein generating the delta signal, applying the delta signal, and measuring the response signal are performed by an active measurement unit and further comprising sequentially and selectively coupling the active measurement unit to each of the plurality of electrochemical cells as the first cell. ### Claim 25 (depends on 23) The method of claim 23, wherein applying the opposite delta signal comprises sequentially and selectively applying the opposite delta signal to each of the plurality of electrochemical cells as the second cell. ### Claim 26 (depends on 22) The method of claim 22, wherein: applying the opposite delta signal across the second set of cells comprises applying the opposite delta signal across all of the plurality of electrochemical cells; and applying the delta signal across the first set of cells comprises applying the delta signal across fewer than all of the plurality of electrochemical cells. ### Claim 27 (depends on 26) The method of claim 26, wherein applying the delta signal across the first set of cells comprises applying the delta signal across a single electrochemical cell of the plurality of electrochemical cells. ### Claim 28 (depends on 27) The method of claim 27, wherein generating the delta signal, applying the delta signal, and measuring the response signal are performed by an active measurement unit and further comprising sequentially and selectively coupling the active measurement unit to each of the plurality of electrochemical cells as the first set of cells. ### Claim 29 (depends on 22) The method of claim 22, wherein applying the delta signal and applying the opposite delta signal comprise applying DC signals. ### Claim 30 (depends on 22) The method of claim 22, wherein applying the delta signal and applying the opposite delta signal comprise applying time-varying signals.