# US 9,518,330 B2 · Electrolyzing cell for generating hydrogen and oxygen and method of use

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- Number: US 9,518,330 B2
- Document ID: US9518330B2
- Status: Granted
- Kind: B2
- Application number: 14/256,424
- Filed: 2014-04-18
- Published: 2014-08-14
- Granted: 2016-12-13
- Earliest claimed: 2011-10-21
- Assignees: Global Hydrogen Technologies, Inc.; Helmuth E. Grimm; Scott L. Harlib
- Applicants: Global Hydrogen Technologies, Inc.
- Inventors: Helmuth E. Grimm
- Web page: https://patentgrep.com/patent/US9518330B2

## CPC

- C25B 9/63: Holders for electrodes; Positioning of the electrodes
- C25B 11/03: perforated or foraminous
- C25B 1/04: by electrolysis of water
- C25B 9/73: of the filter-press type
- C25B 11/00: Electrodes; Manufacture thereof not otherwise provided for
- C25B 11/036: Bipolar electrodes
- C02F 1/46104: {Devices therefor; Their operating or servicing}
- C25B 9/75: having bipolar electrodes
- Y02E 60/36: Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
- C25B: ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR (anodic or cathodic protection C23F13/00; single-crystal growth C30B)
- C02F: TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE (separation in general B01D; special arrangements on waterborne vessels of installations for treating water, waste water or sewage, e.g. for producing fresh water, B63J; adding materials to water to prevent corrosion C23F; treating radioactively-contaminated liquids G21F9/04; regeneration of reactants for recirculation into processes, see the relevant places for the processes)
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

An electrolytic cell used to electrolyze water and produce hydrogen and oxygen. The cell comprises nonconductive dividers, sandwiching neutral electrodes and designed for rapid flow of electrolyte through the cell to limit voltage loss. A positive electrode plate is disposed in the interstitial space of a nonconductive housing, adjacent to the neutral electrodes. At least one terminal connects to the positive electrode. A negative electrode seals the cell and is sealed with an o-ring. The cell may be mounted to a vehicle or other system using a mounting tab, which optionally also functions as a ground. The cell may use gravitic circulation or a circulating pump to cycle electrolyte. The electrolysis cell may be formed of different dimensions, based on the output needs and application, and may be wired in parallel or in series to suit system needs.

## Claims

### Claim 1

An electrolysis cell, comprising
a housing formed of nonconductive material, wherein the housing comprises
a first and second transverse walls, having an opening edge, a base edge, and two longitudinal edges;
a third and fourth longitudinal walls, having an opening edge, a base edge, and two transverse edges, wherein the transverse edges are disposed in communication with the first and second transverse walls;
a base having an interstitial face and exterior face, disposed in communication with the base edge of the first and second transverse walls and third and fourth longitudinal walls, thereby defining an interstitial space;
wherein at least one positive terminal base aperture is disposed in the interstitial face of the base;
a positive electrode plate formed of electroconductive material disposed adjacent to the interstitial face of the base, wherein the positive electrode is adapted to be dimensioned substantially identical to the interstitial face of the base;
wherein at least one positive electrode terminal aperture is disposed on a face of the positive electrode, and where the at least one positive electrode terminal aperture is in communication with the at least one positive terminal base aperture;
at least one positive terminal formed of electroconductive material disposed in the at least one positive electrode terminal aperture and the at least one positive terminal base aperture, and is in electrical communication with the positive electrode plate;
a cassette disposed in the interstitial space, wherein the cassette comprises:
a plurality of dividers, wherein the dividers comprise:
an electrode face, wherein a plurality of electrode slots are disposed on the electrode face;
where the electrode slots are a predetermined size, where the electrode slots are spaced a predetermined distance apart from any other electrode slot or the edge of the divider;
wherein the plurality of dividers are adapted to form electrolyte channels adjacent to two corners of the cassette, where the channels are on one side of the cassette or on opposing corners of the cassette;
a plurality of neutral electrodes disposed in the electrode slots; and
a negative plate formed of electroconductive material disposed and of substantially the same dimensions as the housing, disposed on the opening edge of the housing.

### Claim 2 (depends on 1)

The electrolysis cell of claim 1, further comprising a plurality of electrolyte apertures disposed on one face of a transverse wall, on one face of each transverse wall, on one face of a longitudinal wall, or on one face of each longitudinal wall.

### Claim 3 (depends on 2)

The electrolysis cell of claim 2, further comprising a plurality of electrolyte flow channel disposed on one edge of the positive electrode plate, and adjacent to the electrolyte apertures;
wherein the electrolyte flow channel comprises a cut out from the positive electrode plate having triangular, concave, or convex shape.

### Claim 4 (depends on 2)

The electrolysis cell of claim 2, further comprising a plurality of electrolyte flow fittings disposed in the plurality of electrolyte flow channels.

### Claim 5 (depends on 1)

The electrolysis cell of claim 1, wherein the electroconductive material is stainless steel, titanium, mixed metal oxide, MMO, platinum, carbon, carbon nanofoam, titanium mixed metal oxide comprising RuO2, titanium mixed metal oxide comprising RuO2, titanium mixed metal oxide comprising IrO2, or titanium mixed metal oxide comprising PtO0.12.

### Claim 6 (depends on 1)

The electrolysis cell of claim 1, wherein the nonconductive material is acrylic, acetal, delrin, plastic, lexan, high density polyethylene, polypropylene, nylon, ultra-high molecular weight polyethylene, polyoxybenzylmethylenglycolanhydride, epoxy resin, polyimide, acrylonitrile butadiene styrene, acrylic, celluloid, cellulose acetate, cyclic olefin copolymer, ethylene-vinyl acetate, ethylene vinyl alcohol, polytetrafluoroethylene, fluorinated ethylene propylene, perfluoroalkoxy plastic, chlorotrifluoroethylene, ethylene chlorotrifluoroethylene, ethylene tetrafluoroethylene, polyacrylonitrile, polyamide-imide, polyaryletherketone, polybutadiene, polybutylene, polybutylene terephthalate, polycaprolactone, polychlorotrifluoroethylene, polyethylene terephthalate, polycyclohexylene dimethylene terephthalate, polycarbonate, polyhydroxyalkanoates, polyketone, polyester, polyethylene, polyetheretherketone, polyetherketoneketone, polyetherimide, polyethersulfone, chlorinated polyethylene, polyimide, polylactic acid, polymethylpentene, polyphenylene oxide, polyphenylene sulfide, polyphthalamide, polypropylene, polystyrene, polysulfone, polytrimethylene terephthalate, polyurethane, polyvinyl acetate, polyvinyl chloride, polyvinylidene chloride, or styrene-acrylonitrile.

### Claim 7 (depends on 1)

The electrolysis cell of claim 1, further comprising a groove disposed on the opening edge of the housing and adapted to accept an o-ring or rubber gasket.

### Claim 8 (depends on 7)

The electrolysis cell of claim 7, further comprising an o-ring disposed in the groove.

### Claim 9 (depends on 1)

The electrolysis cell of claim 1, further comprising a plurality of case bolt apertures disposed on the opening edge of the housing, where the case bolt apertures extend through the housing or extend through a portion of the housing and wherein a plurality of plate mounting holes are disposed on the negative plate,
where the plate mounting holes correspond to the case bolt apertures.

### Claim 10 (depends on 9)

The electrolysis cell of claim 9, wherein the plurality of case bolt apertures extend through a portion of the housing, and
wherein the plurality of case bolt apertures are threaded such that the threaded apertures are adapted to accept a case bolt.

### Claim 11 (depends on 1)

The electrolysis cell of claim 1, wherein the cassette comprises five neutral plates.

### Claim 12 (depends on 1)

The electrolysis cell of claim 1, wherein the positive electrode terminal aperture is countersunk and adapted to allow at least one positive terminal to mount flush to the positive plate.

### Claim 13 (depends on 1)

The electrolysis cell of claim 1, wherein the at least one positive electrode terminal apertures further comprises a plurality of positive electrode terminal apertures.

### Claim 14 (depends on 13)

The electrolysis cell of claim 13, wherein the plurality of positive electrode terminal apertures further comprises two apertures.

### Claim 15 (depends on 1)

The electrolysis cell of claim 1, further comprising a terminal screw o-ring disposed on the at least one positive terminal.

### Claim 16 (depends on 1)

The electrolysis cell of claim 1, further comprising a plurality of plate mounting holes disposed on a face of the negative plate.

### Claim 17 (depends on 16)

The electrolysis cell of claim 16, wherein the plurality of plate mounting holes are countersunk.

### Claim 18 (depends on 1)

The electrolysis cell of claim 1, further comprising at least one mounting tab further comprising
a first face and a second face, wherein the first face is adapted to contact the negative plate; and
a plurality of mounting holes disposed on the second face, wherein the mounting holes correspond to a plurality of holes on the negative plate.

### Claim 19 (depends on 18)

The electrolysis cell of claim 18, wherein the plurality of mounting holes are countersunk.

### Claim 20 (depends on 18)

The electrolysis cell of claim 18, wherein the plurality of mounting holes correspond to a plurality of plate mounting holes disposed on the negative plate, and wherein
a plurality of case bolt apertures disposed on the opening edge of the housing, where the case bolt apertures extend through the housing or extend through a portion of the housing and wherein the plurality of plate mounting holes correspond to the case bolt apertures.

### Claim 21 (depends on 1)

The electrolysis cell of claim 1, further comprising a sealant disposed on the opening edge of the housing, wherein the sealant is silicone sealant, silicon sealant, epoxy sealant, urethane sealant, polyisobutylene sealant, or acrylic sealant.
