# US 9,518,157 B2 · Preparation of rubber composition containing graphite platelets and tire with component

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- Number: US 9,518,157 B2
- Document ID: US9518157B2
- Status: Granted
- Kind: B2
- Application number: 14/062,099
- Filed: 2013-10-24
- Published: 2015-04-30
- Granted: 2016-12-13
- Earliest claimed: 2013-10-24
- Assignees: The Goodyear Tire & Rubber Company
- Applicants: The Goodyear Tire & Rubber Company
- Inventors: Junling Zhao; Xiaoping Yang; Carl Trevor Ross Pulford
- Web page: https://patentgrep.com/patent/US9518157B2

## CPC

- C08J 3/24: Crosslinking, e.g. vulcanising, of macromolecules (mechanical aspects B29C35/00; crosslinking agents C08K)
- C08J 3/212: {and solid additives}
- C08J 2309/00: Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
- C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29)

## Abstract

Preparation of a rubber composition containing a dispersion of aligned exfoliated graphite platelets. Such rubber composition is prepared by a method comprised of a sequential combination of concentrated solvent or dry masterbatching of elastomer and exfoliated graphite platelets, followed by blending the masterbatch (after removing the solvent from the solvent based masterbatch) with additional elastomer(s) and then followed by processing the resulting rubber composition to align the dispersed exfoliated graphite platelets in a substantially parallel relation to each other. Such processing may comprise as least one of extrusion and calendaring the rubber composition. The invention further relates to a tire containing a component comprised of such rubber composition containing a dispersion of aligned exfoliated graphite platelets prepared by the aforesaid method.

## Claims

### Claim 1

A method of preparing a sulfur curable rubber composition is comprised of:
(A) preparing a masterbatch comprised of
blending from about 3 to about 20 parts by weight of graphite platelets consisting of exfoliated graphite platelets with an organic solvent solution containing 100 parts by weight of at least one conjugated diene-based elastomer to form the masterbatch after which the masterbatch is dried by removing the organic solvent, wherein said diene-based elastomer consists of at least one of cis 1,4-polyisoprene, cis 1,4-polybutadiene and styrene/butadiene elastomer,
(B) preparing a subsequent sulfur curable rubber composition comprised of blending with said masterbatch up to about 40 parts by weight of at least one additional conjugated diene-based elastomer, where said additional diene-based elastomer consists of at least one of cis 1,4-polyisoprene, cis 1,4-polybutadiene and styrene/butadiene elastomer, and from about 20 to about 120 parts by weight of reinforcing filler per 100 parts by weight of the total of said conjugated diene-based elastomer(s) comprised of a combination of rubber reinforcing carbon black and precipitated silica together with a coupling agent for said precipitated silica having a moiety reactive with hydroxyl groups on said precipitated silica and another different moiety interactive with said conjugated diene-based elastomer(s), and
(C) processing said prepared sulfur curable rubber composition by at least one of extrusion, calendaring, and milling to provide a rubber composition containing a dispersion of said graphite platelets in parallel alignment with each other.

### Claim 2 (depends on 1)

The method of claim 1 wherein said rubber composition is sulfur cured.

### Claim 3 (depends on 1)

The method of claim 1 wherein said rubber composition is used for a tire having a component.