# US 9,517,431 B2 · Method for smoothing time-varying concentration of a fluid stream > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 9,517,431 B2 - Document ID: US9517431B2 - Status: Granted - Kind: B2 - Application number: 14/492,386 - Filed: 2014-09-22 - Published: 2016-03-24 - Granted: 2016-12-13 - Earliest claimed: 2014-09-22 - Assignees: Uop LLC - Applicants: Uop LLC - Inventors: Shain-Jer Doong; Christopher B. McIlroy - Web page: https://patentgrep.com/patent/US9517431B2 ## CPC - B01D 53/04: with stationary adsorbents {(B01D53/025 takes precedence)} - C10L 3/101: {Removal of contaminants} - C10L 3/103: {Sulfur containing contaminants} - C10L 3/104: {Carbon dioxide} - B01D 53/0476: {Vacuum pressure swing adsorption} - B01D 2256/24: Hydrocarbons - B01D 2256/245: Methane - B01D 2257/304: Hydrogen sulfide - B01D 2257/306: Organic sulfur compounds, e.g. mercaptans - B01D 2257/308: Carbonoxysulfide COS - B01D 2257/504: Carbon dioxide - B01D 2257/602: Mercury or mercury compounds - B01D 2257/702: Hydrocarbons - B01D 2257/80: Water - B01D 2259/40086: by using a purge gas (B01D2259/4009 takes precedence) - B01D 2259/4009: using hot gas - C10L 3/106: {of water} - C10L 2290/08: Drying or removing water - C10L 2290/12: Regeneration of a solvent, catalyst, adsorbent or any other component used to treat or prepare a fuel - C10L 2290/542: Adsorption of impurities during preparation or upgrading of a fuel - C10L 2290/58: Control or regulation of the fuel preparation of upgrading process - Y02C 20/40: of CO2 - B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28) - C10L: FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS - Y02C: CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG] ## Abstract A process for reducing the size of sulfur removal units is presented. The process includes passing a regeneration gas from a regenerated contaminant adsorption unit through a fixed bed adsorber. The fixed bed adsorber adsorbs sulfur compounds above an equilibrium condition and releases adsorbed sulfur compounds below the equilibrium condition. The peak levels of sulfur in the regeneration gas are reduced and the processing of the regeneration gas reduces the size of sulfur removal units. ## Claims ### Claim 1 A process for removing sulfur compounds from a natural gas stream comprising: passing a natural gas feed stream to an acid gas removal unit to generate a partially sweetened natural gas stream and an acid gas stream; passing the partially sweetened natural gas stream to an adsorption unit for adsorbing water and sulfur compounds to generate a treated natural gas stream; passing a regenerator gas stream to the adsorption unit to generate a regen gas enriched with sulfur compounds; passing the regen gas enriched with sulfur compounds to a fixed-bed adsorber to generate a regen gas effluent stream with a reduced level of peak sulfur concentration; and passing the regen gas with the reduced level of peak sulfur compounds to a sulfur removal unit. ### Claim 2 (depends on 1) The process of claim 1 wherein the fixed-bed adsorber adsorbs sulfur compounds from the regen gas above an equilibrium adsorption concentration, and desorbs sulfur compounds from the adsorbent below the equilibrium adsorption concentration. ### Claim 3 (depends on 1) The process of claim 1 wherein the fixed-bed adsorber adsorbs hydrocarbon compounds from the regen gas above an equilibrium adsorption concentration, and desorbs hydrocarbon compounds from the adsorbent below the equilibrium adsorption concentration. ### Claim 4 (depends on 1) The process of claim 1 further comprising passing the treated natural gas stream to a natural gas liquids recovery unit to generate a treated gas stream, a C2 stream, a C3 stream, and a C4 stream. ### Claim 5 (depends on 4) The process of claim 4 further comprising: passing the C3 stream to a mercaptan treater to generate a treated C3 stream; passing a regen gas to the mercaptan treater to generate a sulfur enriched regen gas; passing the sulfur enriched regen gas to the fixed-bed adsorber to generate a regen gas with a reduced level of peak sulfur compounds; and passing the regen gas with the reduced level of peak sulfur compounds to the sulfur removal unit. ### Claim 6 (depends on 4) The process of claim 4 further comprising: passing the C4 stream to a mercaptan treater to generate a treated C4 stream; passing a regen gas to the mercaptan treater to generate a sulfur enriched regen gas; passing the sulfur enriched regen gas to the fixed-bed adsorber to generate a regen gas with a reduced level of peak sulfur compounds; and passing the regen gas with the reduced level of peak sulfur compounds to the sulfur removal unit. ### Claim 7 (depends on 1) The process of claim 1 further comprising passing the acid gas to a sulfur recovery unit. ### Claim 8 (depends on 1) The process of claim 1 wherein the sulfur removal unit generates a second acid gas stream and a fuel stream, further comprising: passing the second acid gas stream to a second fixed-bed adsorber to generate a reduced level of peak sulfur acid gas stream; and passing the reduced level of peak sulfur acid gas stream to a sulfur recovery unit. ### Claim 9 (depends on 1) The process of claim 1 further comprising: testing the sulfur level in the regenerator gas stream before passing the regenerator gas stream to the fixed-bed adsorber; splitting the regenerator gas stream into a first portion and a second portion when the sulfur level in the regenerator gas stream is below a preselected value; passing the first portion to the fixed-bed adsorber to generate the regen gas effluent stream; and combining the second portion with the regen gas effluent stream to generate a combined stream. ### Claim 10 (depends on 9) The process of claim 9 further comprising passing the combined stream to the sulfur removal unit. ### Claim 11 A process for removing sulfur compounds from a natural gas stream comprising: passing the natural gas stream to an acid gas removal unit to generate a first stream comprising sulfur compounds, and a second stream comprising natural gas with reduced sulfur compounds; passing the second stream to a gas treatment unit to generate a treated gas stream; passing a regenerator gas stream to the gas treatment unit to generate a regen gas comprising sulfur compounds; splitting the regen gas into two portions, and passing a first portion to a fixed bed adsorption unit, having an adsorbent, to generate an adsorber effluent gas with a reduced level of peak sulfur concentration, wherein the adsorption unit adsorbs sulfur compounds when the sulfur compound concentration in the regen gas is above an equilibrium concentration and desorbs sulfur compounds when the sulfur compound concentration in the regen gas is below the equilibrium concentration; combining the adsorber effluent gas with a second portion of the regen gas to form a combined stream; and passing the combined stream to a sulfur removal unit, to generate a second acid gas stream, and a sweet gas stream. ### Claim 12 (depends on 11) The process of claim 11 wherein the first portion is between 1% and 99% of the regen gas, and wherein the first portion can be adjusted to a preset level. ### Claim 13 (depends on 11) The process of claim 11 wherein the gas treatment unit comprises: passing the second stream to a dehydration and a mercury (Hg) removal unit to generate a third stream comprising a dried natural gas; and passing the third stream to a natural gas liquids recovery unit to generate the treated gas stream, a fourth stream comprising C4 and higher hydrocarbons, a fifth stream comprising C3 hydrocarbons, and a sixth stream comprising C2 hydrocarbons. ### Claim 14 (depends on 13) The process of claim 13 further comprising: passing the fourth stream to an RSH treater to generate a clean C4 stream; and periodically passing a regen gas to the RSH treater to generate a first used regen gas. ### Claim 15 (depends on 14) The process of claim 14 further comprising combining the first used regen gas with the first portion of the first regen effluent gas and to form a combined first regen gas and passing the combined first regen gas to the fixed-bed adsorption unit. ### Claim 16 (depends on 14) The process of claim 14 further comprising passing the first used regen gas to the acid gas removal unit. ### Claim 17 (depends on 13) The process of claim 13 further comprising: passing the fifth stream to a second RSH treater to generate a clean C3 stream; and periodically passing a regen gas to the second RSH treater to generate a second used regen gas. ### Claim 18 (depends on 17) The process of claim 17 further comprising combining the second used regen gas with the first portion of the first regen effluent gas and to form a combined first regen gas and passing the combined first regen gas to the fixed-bed adsorption unit. ### Claim 19 (depends on 18) The process of claim 18 further comprising passing the second used regen gas to the acid gas removal unit.