Particles for electrophoretic displays
AssigneeMerck Patent GmbH
InventorsLouise Diane Farrand, Mark James, Emily Jane Thomas, Claire Topping, Jonathan Henry Wilson
Life of this patent
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Abstract
This invention relates to colored polymer particles preferably with surface functionality for charge retention, a process for their preparation, the use of these particles for the preparation of an electrophoretic device, color electrophoretic displays comprising such particle, and new polymerisable dyes.
Claims23
Colored polymer particles comprising monomer units of a) at least one polymerisable dye comprising a chromophore, at least two polymerisable groups, wherein said polymerizable groups are selected from methacrylates, acrylates, methacrylamides, acrylamides, acrylonitriles, α-substituted acrylates, styrenes and vinyl ethers, vinyl esters, propenyl ethers, oxetanes and epoxys;
- optionally fixed by at least one linker group, and optional groups to modify physical properties and optionally charged group(s), b) at least one co-monomer, c) optionally at least one charged co-monomer, and d) optionally at least one crosslinking co-monomer wherein
- the polymerisable dye is an anthraquinone dye selected from formulae (XII) to (XIV);
- wherein
- R selected from the group consisting of H, alkyl, substituted or non-substituted aryl, —F, —Cl, —Br, —I, —OR′, —SR′, —C(O)R′, —C(O)OR′, —NHCOR′, —NO2, —CN, —SO3H, —NR′R″, with R′ and R″ independently of one another equal to H or alkyl,
- and L1 and L2 are independently of one another a single bond, optionally substituted cycloalkyl or aromatic ring, linear or branched, optionally substituted, alkylene, where one or more non-adjacent C atoms may be replaced by O, S and/or N, and/or one or more double and/or triple bonds may be present in the chain and/or side chain or a combination thereof, and Y1 and Y2 are independently of one another, polymerisable group.
Colored polymer particles comprising monomer units of a) at least one polymerisable dye comprising a chromophore, at least two polymerisable groups, wherein said polymerizable groups are selected from methacrylates, acrylates, methacrylamides, acrylamides, acrylonitriles, α-substituted acrylates, styrenes and vinyl ethers, vinyl esters, propenyl ethers, oxetanes and epoxys;
- optionally fixed by at least one linker group, and optional groups to modify physical properties and optionally charged group(s), b) at least one co-monomer, c) optionally at least one charged co-monomer, and d) optionally at least one crosslinking co-monomer wherein at least one of the following polymerisable dyes are used
Dependencies are inferred from the claim text.