A method for preparing an organosiloxane polymer having an alkoxysilyl-ethylene group at its terminal which comprises subjecting an organopolysiloxane compound which is either a linear or a branched, and having at least one unit of the following formula (1′) as a partial structure and an alkoxysilane to addition reaction according to the following reaction formula, to prepare an organosiloxane polymer which is either a linear or a branched, and having an alkoxysilyl-ethylene group at its terminal having at least one unit of the following formula (1″) in a molecule,
- wherein R represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 20 carbon atoms which may have a substituent;
- each R may be the same or different from each other;
- “m′” represents an integer of 0 to 2,000, parts of a repeating unit of the siloxane bond may be crosslinked to form a branched chain structure;
- “n” represents an integer of 0 to 20;
- R1 represents an alkyl group having 1 to 20 carbon atoms which may have a substituent, and those having 3 or more carbon atoms among the alkyl groups may be a cycloalkyl group which is cyclic;
- R2 represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 20 carbon atoms which may have a substituent;
- and “a” represents an integer of 1 to 3.