Liquid crystal compounds containing deuterium
AssigneeShijiazhuang Chengzhi Yonghua Display Materials Co., Ltd.
InventorsZe Feng Hou, Wen Hai Lu, Xing Zhang, Guo Liang Yun, Rui Mao Hua, Ming Li, Lei Zhao
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Abstract
This invention relates to liquid crystal compound of formula I containing benzene derivatives group that hydrogen substituted by deuterium. Liquid crystal compounds of formula I have not only large positive dielectric anisotropy, but also moderate optical anisotropy and driving voltage, thereby having great significance to formulate a liquid crystal mixture. A liquid crystal mixture containing such type of liquid crystal compounds can be applied in various display devices, which is particularly suitable for TN and STN display devices, and can also be used in IPS and VA display devices.
Claims17
A compound comprising:
- a compound of formula I:
- wherein R1, R2 are selected from the group consisting of H, Cl, F, CN, OCN, OCF3, CF3, CHF2, CH2F, OCHF2, SCN, NCS, SF5 and alkyl having 1 to 15 carbons, fluorinated alkyl having 1 to 15 carbons, chlorinated alkyl having 1 to 15 carbons, deuterated alkyl having 1 to 15 carbons, alkoxy having 1 to 15 carbons, fluorinated alkoxy having 1 to 15 carbons, chlorinated alkoxy having 1 to 15 carbons, deuterated alkoxy having 1 to 15 carbons, alkenyl having 2 to 15 carbons, fluorinated alkenyl having 2 to 15 carbons, chlorinated alkenyl having 2 to 15 carbons, deuterated alkenyl having 2 to 15 carbons, alkenoxy having 2 to 15 carbons, fluorinated alkenoxy having 2 to 15 carbons, chlorinated alkenoxy having 2 to 15 carbons, deuterated alkenoxy having 2 to 15 carbons, cyclopropane, cyclobutane, cyclopentane, cyclohexane, cycloheptane wherein one or more —CH2— independently of one another are replaced by —CH═CH—, —C≡C—, —COO—, —OOC—, —O— or —S—;
- wherein rings A1, A2 and A3 are independently selected from the group consisting of:
- a single bond,
- wherein ring B is selected from selected from the group consisting of 1,4-phenylene and 1,4-phenylene, which may be monosubstituted or polysubstituted by fluorine, deuterium, chlorine;
- wherein 1 is 0, 1;
- m is 0, 1;
- n is 0, 1;
- wherein Z1, Z2 and Z3 are selected from the group consisting of a single bond, —CH2—, —CH2—CH2—, —(CH2)3—, —(CH2)4—, —CH═CH—, —C≡C—, —COO—, —OOC—, —CF2O—, —OCH2—, —CH2O—, —OCF2—, —CF2CH2—, —CH2CF2—, —C2F4— and —CF═CF—;
- and
- wherein L1, L2 and L3 are selected from the group consisting of H, F, Cl and D.
Dependencies are inferred from the claim text.