A process for preparing textile fibers at least partially covered with a semiconductive material with photocatalytic properties for degrading organic compounds, wherein the semiconductive material is in the form of nanostructures (10, 12) of one-dimensional morphology of said semiconductive material, and/or of nanoparticles (16) of said semiconductive material that are attached to nanostructures (14, 18) of one-dimensional morphology of a support material chosen from a semiconductive material and a non-semiconductive material, wherein:
- the process consists of synthesizing nanotubes (12) or nanofibers (10) of semiconductive material, and combining said nanotubes or nanofibers with nanoparticles (16) of semiconductive or non-semiconductive material to form a first nanocomposite, or synthesizing nanotubes (18) or nanofibers (14) of non-semiconductive support material, and combining said nanotubes or nanofibers with nanoparticles (16) of semiconductive material to form a second nanocomposite, and covering the textile fibers with said first or second nanocomposite via layer-by-layer technique.