# US 9,437,904 B2 · Lithium ion secondary battery

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- Number: US 9,437,904 B2
- Document ID: US9437904B2
- Status: Granted
- Kind: B2
- Application number: 14/186,451
- Filed: 2014-02-21
- Published: 2014-06-19
- Granted: 2016-09-06
- Earliest claimed: 2012-03-15
- Assignees: Kabushiki Kaisha Toshiba
- Applicants: Kabushiki Kaisha Toshiba
- Inventors: Kenichi Takahashi; Hirokiyo Mamyoda; Tatsuya Hashimoto
- Web page: https://patentgrep.com/patent/US9437904B2

## CPC

- H01M 10/637: characterised by the use of reversible temperature-sensitive devices, e.g. NTC, PTC or bimetal devices; characterised by control of the internal current flowing through the cells, e.g. by switching (means for preventing undesired use or discharge H01M50/572)
- H01M 10/0587: of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
- H01M 50/581: in response to temperature
- H01M 10/052: Li-accumulators
- H01M 2200/10: Temperature sensitive devices
- H01M 2200/103: Fuse
- H01M 2220/20: Batteries in motive systems, e.g. vehicle, ship, plane
- H02J 7/61: against overcharge
- Y02E 60/10: Energy storage using batteries
- Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H02J: ELECTRIC POWER NETWORKS; CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

A lithium ion secondary battery has a battery can, an electrode assembly in the battery can formed by rolling up a positive electrode, a separator, and a negative electrode, an organic electrolyte solution in the battery can, a positive electrode lead in the battery can connected to the positive electrode, a negative electrode lead in the battery can connected to the negative electrode, an overcharge preventer, a cap body sealing the battery can, a positive electrode terminal fixed to the cap body and connected to the positive electrode lead, and a negative electrode terminal fixed to the cap body and connected to the negative electrode lead.

## Claims

### Claim 1

A lithium ion secondary battery comprising:
a battery can:
an electrode assembly in the battery can formed by rolling up a positive electrode, a separator, and a negative electrode;
an organic electrolyte solution in the battery can;
a positive electrode tab in the battery can connected to the positive electrode;
a negative electrode tab in the battery can connected to the negative electrode;
an overcharge preventer in the battery can;
a cap body sealing the battery can;
a positive electrode terminal fixed to the cap body and connected to the positive electrode tab; and
a negative electrode terminal fixed to the cap body and connected to the negative electrode tab,
wherein the overcharge preventer comprises: a temperature-sensitive deformation member configured to detect the internal temperature of the electrode assembly to undergo shape change; a switch member configured to be driven by the shape change of the temperature-sensitive deformation member; a fuse member connected in series between the positive electrode terminal and the positive electrode or the negative electrode terminal and the negative electrode; and a short circuit configured to connect the electrode assembly, the fuse member, and the switch member, and when the switch member is driven and turned on by the shape change of the temperature-sensitive deformation member, the short circuit becomes a closed circuit, and the fuse member is melted down by electrical energy accumulated in the electrode assembly to shut off a charging current path,
wherein the switch member comprises at least one of a positive electrode lead member and a negative electrode lead member,
the positive electrode lead member is connected to the positive electrode tab,
the negative electrode lead member is connected to the negative electrode tab,
when the short circuit is not closed before the shape change of the temperature-sensitive deformation member, the positive electrode lead member and the negative electrode lead member are not connected to the battery can,
when the switch member is driven and turned on by the shape change of the temperature-sensitive deformation member, and the positive electrode lead member and the negative electrode lead member are connected to the battery can forced by the shape change of the temperature-sensitive deformation member, the short circuit becomes a closed circuit, and the fuse member is melted down by electrical energy accumulated in the electrode assembly to shut off a charging current path.

### Claim 2 (depends on 1)

The battery according to claim 1, wherein the temperature-sensitive deformation member comprises at least one of a shape-memory alloy, a bimetal, and a wax.

### Claim 3 (depends on 1)

The battery according to claim 1, wherein the short circuit comprises two switch members in contact with the battery can, and when the short circuit is a closed circuit, a short-circuit current passes through the battery can.

### Claim 4 (depends on 1)

The battery according to claim 1, wherein the fuse member comprises a thin part formed on either a positive electrode lead or a negative electrode lead extracted from the electrode assembly, and the thin part is thinner than one or more other portion of the lead.

### Claim 5 (depends on 1)

The battery according to claim 1, wherein the switch member further comprises: a spring a spring locking member; and a push rod member configured to push out the spring locking member, the spring is compressively fixed by the locking member, in the case of overcharge, the compression of the spring is released in association with a movement of the push rod member depending on a deformation of the temperature-sensitive deformation member, and a repulsion force of the spring instantaneously brings the switch member and the battery can into contact with each other to close the short circuit, and melt down the fuse member.

### Claim 6 (depends on 1)

The battery according to claim 1, wherein the temperature-sensitive deformation member has a substantially C-ring shape formed from a shape-memory alloy.
