# US 9,437,880 B2 · Method of manufacturing a fuel cell stack having an electrically conductive interconnect

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- Number: US 9,437,880 B2
- Document ID: US9437880B2
- Status: Granted
- Kind: B2
- Application number: 13/623,455
- Filed: 2012-09-20
- Published: 2015-10-22
- Granted: 2016-09-06
- Earliest claimed: 2006-08-04
- Assignees: Delphi Technologies, Inc.; Battelle Memorial Institute
- Applicants: Subhasish Mukerjee; Karl Jacob Haltiner, Jr.; Kerry D. Meinhardt; Jin Yong Kim; Eric S. Mast; Vincent L. Sprenkle
- Inventors: Subhasish Mukerjee; Karl Jacob Haltiner, Jr.; Kerry D. Meinhardt; Jin Yong Kim; Eric S. Mast; Vincent L. Sprenkle
- Web page: https://patentgrep.com/patent/US9437880B2

## CPC

- H01M 8/0228: in the form of layered or coated products
- H01M 8/021: Alloys based on iron
- H01M 8/1246: the electrolyte consisting of oxides
- H01M 8/2404: Processes or apparatus for grouping fuel cells
- H01M 8/2425: High-temperature cells with solid electrolytes
- H01M 8/2432: Grouping of unit cells of planar configuration
- H01M 8/124: characterised by the process of manufacturing or by the material of the electrolyte
- H01M 2008/1293: {Fuel cells with solid oxide electrolytes}
- H01M 2300/0071: Oxides
- Y02E 60/50: Fuel cells
- Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

A method of manufacturing a solid oxide fuel cell stack having an electrically conductive interconnect, including the steps of: (a) providing a first fuel cell and a second fuel cell, (b) providing a substrate having an iron-chromium alloy, (c) depositing a layer of metallic cobalt over a portion of substrate surface, (d) subjecting the layer of metallic cobalt to reducing conditions, (e) then exposing the remaining portion of the layer of metallic cobalt to oxidizing conditions for a predetermined time and temperature, such that the surface portion of the layer of metallic cobalt is oxidized to cobalt oxide, thereby forming the electrically conductive interconnect having a layer of metallic cobalt sandwiched between a surface layer of cobalt oxide and the layer of cobalt-iron-chromium alloy, and (f) sandwiching the substrate between the first and second fuel cells.

## Claims

### Claim 1

A method of manufacturing a solid oxide fuel cell stack having an electrically conductive interconnect, comprising the steps of:
(a) providing a first fuel cell and a second fuel cell, wherein each of said fuel cells include an electrolyte sandwiched between an anode and a cathode;
(b) providing a substrate comprising an iron-chromium alloy, wherein said substrate includes a first surface and a second surface opposite of said first surface;
(c) depositing a layer of metallic cobalt over at least a portion of at least one of said first and second surfaces;
(d) subjecting said layer of metallic cobalt to reducing conditions for a predetermined time and temperature, such that a portion of said metallic cobalt is diffused into said iron-chromium alloy substrate, thereby forming a layer of cobalt-iron-chromium alloy;
(e) then exposing the remaining portion of said layer of metallic cobalt to oxidizing conditions for a predetermined time and temperature, such that the surface portion of said layer of metallic cobalt is oxidized to cobalt oxide, thereby forming said electrically conductive interconnect comprising said layer of metallic cobalt sandwiched between a surface layer of cobalt oxide and said layer of cobalt-iron-chromium alloy; and
(f) sandwiching said substrate between said first and second fuel cells, wherein said first surface of substrate is in electrical contact said anode of first fuel cell and said second surface of substrate is in electrical contact with said cathode of said second fuel cell.

### Claim 2 (depends on 1)

A method according to claim 1, wherein said reducing conditions comprise heating said layer of metallic cobalt to about 800° C. in a vacuum atmosphere for a time period of about 15 minutes to about 8 hours.

### Claim 3 (depends on 2)

A method according to claim 2, wherein said oxidizing conditions comprise heating the remaining portion of said layer of metallic cobalt in an oxygen-containing atmosphere to a temperature of about 800° C. for a time period of about 15 minutes to about 8 hours.

### Claim 4 (depends on 3)

A method according to claim 3 wherein said layer of metallic cobalt has a thickness of about 0.5 micron to about 10 microns.

### Claim 5 (depends on 4)

A method according to claim 4 wherein said layer of metallic cobalt has a thickness of about 2.5 microns to about 5 microns.