# US 9,437,410 B2 · System and method for applying curtain gas flow in a mass spectrometer

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- Number: US 9,437,410 B2
- Document ID: US9437410B2
- Status: Granted
- Kind: B2
- Application number: 14/359,853
- Filed: 2012-11-21
- Published: 2014-10-30
- Granted: 2016-09-06
- Earliest claimed: 2011-11-21
- Assignees: DH Technologies Development Pte. Ltd.
- Applicants: DH Technologies Development Pte. Ltd.
- Inventors: Bruce A. Thomson; Mircea Guna
- Web page: https://patentgrep.com/patent/US9437410B2

## CPC

- H01J 49/0422: {for gaseous samples (interfaces to gas chromatographs G01N30/7206)}
- H01J 49/044: {with means for preventing droplets from entering the analyzer; Desolvation of droplets}
- H01J 49/26: Mass spectrometers or separator tubes
- H01J: ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS (spark-gaps H01T; electric arc lamps H05B31/00; particle accelerators H05H)

## Abstract

A system of mass spectrometry is disclosed having an ion source for generating ions at substantially atmospheric pressure. The system has a sampling member with an orifice disposed therein. The sampling member forms a vacuum chamber with a mass spectrometer. The system also has a curtain plate between the ion source and the sampling member. The curtain plate has an aperture therein, having a cross-section and being spaced from the sampling member to define a flow passage between the curtain plate and the sampling member, and to define an annular gap between the orifice and the aperture. The area of the annular gap is less than the cross-sectional area of the aperture. The system also has a power supply for applying a voltage to the curtain plate, and a curtain gas flow mechanism for directing a curtain gas into the flow passage and the annular gap.

## Claims

### Claim 1

A mass spectrometer system comprising:
an ion source for generating ions at substantially atmospheric pressure;
a sampling member having an orifice therein, the sampling member forming a vacuum chamber with a mass spectrometer;
a curtain plate between the ion source and the sampling member, the curtain plate having an aperture therein, the curtain plate aperture being coaxially aligned with the sampling member orifice, the aperture having a cross-section and being spaced from the sampling member to define a flow passage between the curtain plate and the sampling member, and to define an annular gap between the orifice and the aperture, the area of the annular gap being less than the cross-sectional area of the aperture;
a power supply for applying a voltage to the curtain plate to direct ions from the ion source to the aperture in the curtain plate; and
a curtain gas flow mechanism for directing a curtain gas into the flow passage and the annular gap, wherein the curtain gas forms a high velocity jet in front of the orifice.

### Claim 2 (depends on 1)

The mass spectrometer of claim 1, wherein the area of the annular gap is less than 50% of the area of the aperture.

### Claim 3 (depends on 1)

The mass spectrometer of claim 1, wherein the annular gap is less than 0.5 mm.

### Claim 4 (depends on 1)

The mass spectrometer of claim 1, wherein the annular gap is less than 0.3 mm.

### Claim 5

A mass spectrometer system comprising:
an ion source for generating ions at substantially atmospheric pressure;
at least two curtain plates, each curtain plate of the at least two curtain plates having an aperture, each curtain plate spaced to form a plurality of flow passages therebetween;
a sampling member having an orifice therein, at least one of the curtain plate apertures being coaxially aligned with the sampling member orifice, the sampling member forming a vacuum chamber with a mass spectrometer, the sampling member being spaced away from the at least two curtain plates forming a flow passage therebetween;
a power supply voltage for applying independent voltages to each curtain plate to direct ions through each of the apertures of each curtain plate;
at least one gas flow mechanism for directing curtain gases into each of the plurality of flow passages.

### Claim 6 (depends on 5)

The mass spectrometer of claim 5 wherein the curtain gases have different composition.

### Claim 7

An ion sampling interface for receiving ions from an ion source, the ion sampling interface comprising:
a first curtain plate having a first aperture therein for receiving the ions from the ion source;
a second curtain plate having a second aperture therein, the second curtain plate spaced from the first curtain plate to form a curtain chamber therebetween;
a sampling member having an orifice therein, at least one of the curtain plate apertures being coaxially aligned with the sampling member orifice, the sampling member forming a vacuum chamber with a mass spectrometer; the sampling member, spaced from the second curtain plate to form a curtain flow channel therebetween, the sampling member defining an annular gap between the orifice and the second aperture, the area of the annular gap being less than the cross-sectional area of the aperture;
a first power supply for applying a voltage to the curtain plate to direct ions from the ion source to the first aperture in the first curtain plate;
a second power supply for applying a voltage to the second curtain plate to direct ions to the orifice; and
a curtain gas flow mechanism for directing a curtain gas into the flow passage and the annular gap, the curtain gas generating a high velocity jet of gas across the orifice as the curtain gas flow passes through the annular gap.