# US 9,436,060 B2 · Islands-in-sea type photorefractive polymer composite, and photorefractive device and optical device including the same > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 9,436,060 B2 - Document ID: US9436060B2 - Status: Granted - Kind: B2 - Application number: 14/011,077 - Filed: 2013-08-27 - Published: 2014-09-11 - Granted: 2016-09-06 - Earliest claimed: 2013-03-06 - Assignees: Samsung Electronics Co., Ltd. - Applicants: Samsung Electronics Co., Ltd. - Inventors: Chil-sung Choi; Kyoung-seok Pyun - Web page: https://patentgrep.com/patent/US9436060B2 ## CPC - G02F 1/29: for the control of the position or the direction of light beams, i.e. deflection - G02B 1/04: made of organic materials, e.g. plastics (G02B1/08 takes precedence) - G02F 1/0126: {Opto-optical modulation, i.e. control of one light beam by another light beam, not otherwise provided for in this subclass} - G02F 1/0338: {structurally associated with a photoconductive layer or having photo-refractive properties (G02F1/05 takes precedence)} - G02F 1/3511: {Self-focusing or self-trapping of light; Light-induced birefringence; Induced optical Kerr-effect} - G02F 1/3611: {containing Nitrogen} - G02F 1/3612: {Heterocycles having N as heteroatom} - G02F 1/3613: {containing Sulfur} - G02F 2203/52: Optical limiters - G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS - G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS ## Abstract Provided are an islands-in-sea type photorefractive polymer composite, and a photorefractive device and an optical device including the same. The islands-in-sea type photorefractive polymer composite includes at least a photoconductive polymer matrix, a nonlinear optical chromophore, and a plasticizer, as a sea component, and includes at least a photocharge generator as an island component. ## Claims ### Claim 1 An islands-in-sea type photorefractive polymer composite comprising: a sea component comprising a photoconductive polymer matrix, a nonlinear optical chromophore, and a plasticizer; and an island component comprising a photocharge generator; wherein an average particle diameter of the island component is in a range of about 0.5 μm to about 50 μm; wherein the photocharge generator is configured to be separately agglomerated from the photoconductive polymer matrix to form the island component when the photocharge generator is drive after being dissolved in a solvent with the photoconductive polymer matrix; wherein, when an internal electric field is present in the islands-in-sea type photorefractive polymer composite, an amount of electrons in the island component is larger than an amount of electrons in the sea component; and wherein the islands-in-sea type photorefractive polymer composite transmits substantially all incident light when an internal electric field is absent, and the islands-in-sea type photorefractive polymer composite exhibits a beam fanning effect when an internal electric field is present. ### Claim 2 (depends on 1) The islands-in-sea type photorefractive polymer composite of claim 1, wherein the photoconductive polymer matrix comprises polyvinylcarbazole (PVK), polysiloxane carbazole, polysiloxane benzocarbazole, polyparaphenylenevinylene, polyaniline, polypyrrole, polyacetylene, polythiophene, polyalkylthiophene, carbazole-substituted polysiloxane (PSX-Cz), poly(p-phenylene terephthalate) carbazole (PPT-CZ), polyacrylate triphenylamine (TATPD), a derivative thereof, a mixture thereof, or a copolymer thereof. ### Claim 3 (depends on 1) The islands-in-sea type photorefractive polymer composite of claim 1, wherein a weight-average molecular weight of the photoconductive polymer matrix is in a range of about 5,000 to about 500,000. ### Claim 4 (depends on 1) The islands-in-sea type photorefractive polymer composite of claim 1, wherein a content of the photoconductive polymer matrix is in a range of about 30 parts by weight to about 60 parts by weight based on 100 parts by weight of the islands-in-sea type photorefractive polymer composite. ### Claim 5 (depends on 1) The islands-in-sea type photorefractive polymer composite of claim 1, wherein the nonlinear optical chromophore comprises one or more of a group consisting of: 2-[3-[(E)-2-(piperidino)-1-ethenyl]-5,5-dimethyl-2-cyclohexenyliden] malononitrile (P-IP-DC), 2-{3-[(E)-2-(dibutylamino)-1-ethenyl]-5,5-dimethyl-2-cyclohexenyliden } malononitrile (DB-IP-DC), dicyanostyrene derivative 4-piperidinobenzylidene-malonitrile (PDCST), 2,5-dimethyl-4-(p-phenylazo) anisole (DMNPAA), 4-di(2-methoxyethyl)aminobenzylidene malononitrile (AODCST), 3-(N,N-di-n-butylaniline-4-yl)-1-dicyanomethylidene-2-cyclohexene (DBDC), 2-dicyanomethylene-3-cyano-2,5-dihydrofuran (DCDHF), 2,N,N-dihexylamino-7-dicyanomethylidenyl-3,4,5,6,10-pentahydronaphthalene (DHADC-MPN), amino-thienyl-dioxocyano-pyridine (ATOP), 3-(2-(4-(N,N-diethylamino)phenyl)ethenyl)-5,5-dimethyl-1,2-cyclohexenylidene)propanedinitrile (Lemke-E), 1-n-butoxyl-2,5-dimethyl-4-(4′-nitrophenylazo) benzene (BDMNPAB), fluorinated cyano-tolane chromophore (FTCN), and diethylamino-nitrostyrene (DEANST). ### Claim 6 (depends on 1) The islands-in-sea type photorefractive polymer composite of claim 1, wherein a content of the nonlinear optical chromophore is in a range of about 50 parts by weight to about 90 parts by weight based on 100 parts by weight of the photoconductive polymer matrix. ### Claim 7 (depends on 1) The islands-in-sea type photorefractive polymer composite of claim 1, wherein the plasticizer comprises one or more of a group consisting of benzyl butyl phthalate (BBP), diphenyl phthalate (DPP), di-2-ethylhexyl phthalate (DOP), N-ethylcarbazole (ECZ), n-(2-ethylhexyl)-n-(3-methylphenyl)-aniline (EHMPA), dimethylphthalate (DMP), diethylphthalate (DEP), diisobutylphtalate (DIBP), dibutylphtalate (DBP), diheptylphtalate (DHP), dioctyl phthalate (DIOP), di-n-octyl phthalate (DnOP), dinonylphthalate (DNP), diisodecylphthalate (DIDP), ditridecylphthalate (DTDP), dicyclohexyl phthalate (DCHP), butyllauryl phthalate (BLP), dioctyl adipate (DOA), diisodecyl adipate (DIDA), dioctyl azelate (DOZ), dibutyl sebacate (DBS), dioctyl sebacate (DOS), dioctyl terephthalate (DOTP), diethylene glycol dibenzoate (DEDB), butyl oleate (BO), tricresyl phosphate (TCP), trioctyl phosphate (TOP), triphenyl phosphate (TPP), and trichloroethyl phosphate (TCEP),. ### Claim 8 (depends on 1) The islands-in-sea type photorefractive polymer composite of claim 1, wherein a content of the plasticizer is in a range of about 25 parts by weight to about 45 parts by weight based on 100 parts by weight of the photoconductive polymer matrix. ### Claim 9 (depends on 1) The islands-in-sea type photorefractive polymer composite of claim 1, wherein the photocharge generator comprises one or more of a group consisting of graphite, graphene, graphene oxide (GO), and reduced graphene oxide (RGO). ### Claim 10 (depends on 1) The islands-in-sea type photorefractive polymer composite of claim 1, wherein a content of the photocharge generator is in a range of about 0.1 parts by weight to about 1.5 parts by weight based on 100 parts by weight of the photoconductive polymer matrix. ### Claim 11 A photorefractive device comprising: a first electrode; a second electrode; and an islands-in-sea type photorefractive polymer composite disposed between the first electrode and the second electrode, the islands-in-sea type photorefractive polymer composite comprising: a sea component comprising a photoconductive polymer matrix, a nonlinear optical chromophore, and a plasticizer; and an island component comprising a photocharge generator; wherein an average particle diameter of the island component is in a range of about 0.5 μm to about 50 μm; wherein the photocharge generator is configured to be separately agglomerated from the photoconductive polymer matrix to form the island component when the photocharge generator is drive after being dissolved in a solvent with the photoconductive polymer matrix; wherein, when an internal electric field is present in the islands-in-sea type photorefractive polymer composite, an amount of electrons in the island component is larger than an amount of electrons in the sea component; and wherein the islands-in-sea type photorefractive polymer composite transmits substantially all incident light when an internal electric field is absent, and the islands-in-sea type photorefractive polymer composite exhibits a beam fanning effect when an internal electric field is present. ### Claim 12 An optical device comprising an islands-in-sea type photorefractive polymer composite comprising: a sea component comprising a photoconductive polymer matrix, a nonlinear optical chromophore, and a plasticizer; and an island component comprising a photocharge generator; wherein an average particle diameter of the island component is in a range of about 0.5 μm to about 50 μm; wherein the photocharge generator is configured to be separately agglomerated from the photoconductive polymer matrix to form the island component when the photocharge generator is drive after being dissolved in a solvent with the photoconductive polymer matrix; wherein, when an internal electric field is present in the islands-in-sea type photorefractive polymer composite, an amount of electrons in the island component is larger than an amount of electrons in the sea component; and wherein the islands-in-sea type photorefractive polymer composite transmits substantially all incident light when an internal electric field is absent, and the islands-in-sea type photorefractive polymer composite exhibits a beam fanning effect when an internal electric field is present. ### Claim 13 An optical beam splitter comprising: an islands-in-sea type photorefractive polymer composite comprising: a sea component comprising: a photoconductive polymer matrix, a nonlinear optical chromophore, and a plasticizer; and a plurality of island components each comprising a photocharge generator; wherein an average particle diameter of the island component is in a range of about 0.5 μm to about 50 μm; wherein the photocharge generator is configured to be separately agglomerated from the photoconductive polymer matrix to form the island component when the photocharge generator is drive after being dissolved in a solvent with the photoconductive polymer matrix; wherein, when an internal electric field is present in the islands-in-sea type photorefractive polymer composite, an amount of electrons in the island component is larger than an amount of electrons in the sea component; and wherein the islands-in-sea type photorefractive polymer composite transmits substantially all incident light when an internal electric field is absent, and the islands-in-sea type photorefractive polymer composite exhibits a beam fanning effect when an internal electric field is present.