# US 9,436,040 B2 · Liquid crystal display devices and methods of manufacturing the same

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- Number: US 9,436,040 B2
- Document ID: US9436040B2
- Status: Granted
- Kind: B2
- Application number: 14/531,098
- Filed: 2014-11-03
- Published: 2015-12-03
- Granted: 2016-09-06
- Earliest claimed: 2014-05-28
- Assignees: Samsung Display Co., Ltd.
- Applicants: Samsung Display Co., Ltd.
- Inventors: Taek-Joon Lee; Tae-Jin Kong; Sang-Gyun Kim
- Web page: https://patentgrep.com/patent/US9436040B2

## CPC

- G02F 1/133723: {Polyimide, polyamide-imide}
- G02F 1/133753: {with different alignment orientations or pretilt angles on a same surface, e.g. for grey scale or improved viewing angle}
- G02F 1/133742: {for homeotropic alignment}
- G02F 1/133761: {with different pretilt angles}
- G02F 1/133788: {by light irradiation, e.g. linearly polarised light photo-polymerisation}
- G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS

## Abstract

A liquid crystal display device includes an upper substrate and a lower substrate facing each other, alignment layers, and a liquid crystal layer. An alignment layer is disposed on the upper substrate and an alignment layer is disposed on the lower substrate. The alignment layer includes a vertical alignment layer and a tilting alignment layer. The vertical alignment layer includes a polyimide-based polymer resin having an imidization ratio of about 65% to about 90%. The tilting alignment layer is present on an upper portion of the vertical alignment layer and includes a pattern. The liquid crystal layer is interposed between the upper substrate and the lower substrate.

## Claims

### Claim 1

A liquid crystal display device, comprising:
an upper substrate and a lower substrate facing each other;
an alignment layer on the upper substrate and an alignment layer on the lower substrate, wherein each alignment layer is phase-separated into a vertical alignment layer and a tilting alignment layer:
wherein the vertical alignment layer comprises a polyimide-based polymer resin, wherein the polyimide-based polymer resin has an imidization ratio of about 65% to about 90%; and
wherein the tilting alignment layer is on an upper portion of the vertical alignment layer, wherein the tilting alignment layer comprises a pattern; and
a liquid crystal layer interposed between the upper substrate and the lower substrate.

### Claim 2 (depends on 1)

The liquid crystal display device of claim 1, wherein the imidization ratio of the polyimide-based polymer resin is about 75% to about 90% and a mura level of an image of a display screen of the liquid crystal display is substantially zero.

### Claim 3 (depends on 1)

The liquid crystal display device of claim 1, wherein the polyimide-based polymer resin comprises a mixture of polyimide and polyamic acid.

### Claim 4 (depends on 1)

The liquid crystal display device of claim 1, further comprising an electrode on the upper substrate and an electrode on the lower substrate,
wherein the vertical alignment layer of the alignment layer on the upper substrate is in contact with the electrode on the upper substrate, and the tilting alignment layer of the alignment layer on the upper substrate is spaced apart from the electrode on the upper substrate; and
wherein the vertical alignment layer of the alignment layer on the lower substrate is in contact with the electrode on the lower substrate, and the tilting alignment layer of the alignment layer on the lower substrate is spaced apart from the electrode on the lower substrate.

### Claim 5 (depends on 4)

The liquid crystal display device of claim 4, wherein the liquid crystal layer is in contact with each tilting alignment layer, and wherein the liquid crystal layer comprises liquid crystal molecules which are pre-tilted and vertically aligned.

### Claim 6 (depends on 1)

The liquid crystal display device of claim 1, wherein the pattern of the tilting alignment layer comprises a plurality of islands spaced apart from each other and at least partially buried in the vertical alignment layer.

### Claim 7 (depends on 6)

The liquid crystal display device of claim 6,
wherein spaces between islands in the tilting alignment layer expose portions of a top surface of the vertical alignment layer, and
wherein the exposed portions of the top surface of the vertical alignment layer is in contact with the liquid crystal layer.

### Claim 8 (depends on 1)

The liquid crystal display device of claim 1, wherein the tilting alignment layer comprises a reactive mesogen and a polyimide-based polymer resin having an imidization ratio which is different from the imidization ratio of the vertical alignment layer.

### Claim 9 (depends on 8)

The liquid crystal display device of claim 8, wherein the imidization ratio of the tilting alignment layer is less than the imidization ratio of the vertical alignment layer.

### Claim 10 (depends on 8)

The liquid crystal display device of claim 8, wherein the tilting alignment layer further comprises a monomer or an oligomer of a polyimide precursor.

### Claim 11

A liquid crystal display device, comprising:
two substrates facing each other;
an electrode on each of the two substrates;
a liquid crystal layer between the two substrates; and
an alignment layer between the electrode and the liquid crystal layer, wherein the alignment layer comprises a polyimide-based polymer having an imidization ratio,
wherein the imidization ratio at the portion of the alignment layer adjacent to the electrode is about 65% to about 90%, and
the imidization ratio of the portion of the alignment layer adjacent to the liquid crystal layer is less than the imidization ratio at the portion of the alignment layer adjacent to the electrode.

### Claim 12 (depends on 11)

The liquid crystal display device of claim 11, wherein the imidization ratio at the portion of the alignment layer adjacent to the electrode is about 75% to about 90%.

### Claim 13 (depends on 11)

The liquid crystal display device of claim 11, wherein the alignment layer includes a polyimide-based polymer resin, and the portion of the alignment layer adjacent to the liquid crystal layer further comprises a reactive mesogen.

### Claim 14 (depends on 13)

The liquid crystal display device of claim 13, wherein the portion of the alignment layer adjacent to the liquid crystal layer comprises a pattern comprising a plurality of islands.

### Claim 15

A method of manufacturing a liquid crystal display device, comprising:
forming an electrode on each of two substrates;
coating an alignment layer composition comprising a polyimide-based polymer resin on the electrode to form a preliminary alignment layer, wherein the polyimide-based polymer resin has an imidization ratio of about 65% to about 90%;
thermally treating the preliminary alignment layer to form an alignment layer, wherein the alignment layer is phase-separated into a vertical alignment layer and a tilting alignment layer, wherein the vertical alignment layer is adjacent to the electrode and the tilting alignment layer is spaced apart from the electrode, and wherein the tilting alignment layer comprises a pattern comprising a plurality of islands;
forming a liquid crystal layer between the two substrates, wherein the liquid crystal layer comprises liquid crystal molecules; and
aligning the liquid crystal molecules.

### Claim 16 (depends on 15)

The method of claim 15, wherein an imidization ratio of the alignment layer composition is about 75% to about 90%.

### Claim 17 (depends on 15)

The method of claim 15, wherein the forming of the liquid crystal layer comprises dropping a liquid crystal composition on the alignment layer formed on one of the two substrates.

### Claim 18 (depends on 15)

The method of claim 15, wherein the aligning of the liquid crystal molecules comprises performing at least one of exposure to an ultraviolet light and a generation of an electrical field.