# US 9,434,891 B2 · Apparatus for recovering oligomerate

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- Number: US 9,434,891 B2
- Document ID: US9434891B2
- Status: Granted
- Kind: B2
- Application number: 14/074,681
- Filed: 2013-11-07
- Published: 2014-05-15
- Granted: 2016-09-06
- Earliest claimed: 2012-11-12
- Assignees: Uop LLC
- Applicants: Uop LLC
- Inventors: Christian D. Freet; Charles P. Luebke; Clayton C. Sadler
- Web page: https://patentgrep.com/patent/US9434891B2

## CPC

- C10G 50/00: Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
- B01D 3/009: {in combination with chemical reactions}
- B01D 3/143: {by two or more of a fractionation, separation or rectification step}
- C10G 7/02: Stabilising gasoline by removing gases by fractioning
- C10G 11/18: according to the "fluidised-bed" technique
- C10L 1/06: for spark ignition
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)
- C10L: FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS

## Abstract

A process and apparatus that uses a debutanizer with a side stripper can recover a light stream, an intermediate stream and a liquid stream. One of the intermediate stream and the liquid stream can be recycled to oligomerization or to fluid catalytic cracking.

## Claims

### Claim 1

An apparatus for producing olefins comprising:
an oligomerization zone for oligomerizing an oligomerization feed stream to produce an oligomerate stream;
a fractionation column in communication with said oligomerization zone, said fractionation column providing a side stream from a side outlet;
a side stripper column in communication with said side outlet of said fractionation column;
said fractionation column in communication with an overhead line from said side stripper column.

### Claim 2 (depends on 1)

The apparatus of claim 1 wherein said oligomerization zone is in downstream communication with said side outlet.

### Claim 3 (depends on 1)

The apparatus of claim 1 wherein said oligomerization zone is in downstream communication with a bottom line of said fractionation column.

### Claim 4 (depends on 1)

The apparatus of claim 1 wherein an FCC zone is in downstream communication with a bottom line of said fractionation column.

### Claim 5 (depends on 1)

The apparatus of claim 1 wherein a gasoline tank or a gasoline blending line is in communication with a bottom line of said fractionation column.

### Claim 6 (depends on 1)

The apparatus of claim 1 wherein a distillate separator column is in communication with a bottom line of said fractionation column.

### Claim 7 (depends on 1)

The apparatus of claim 1 wherein said feed inlet to said fractionation column is at a lower elevation than a feed inlet from said overhead line from said side stripper.

### Claim 8 (depends on 1)

The apparatus of claim 1 wherein said feed inlet from said overhead line from said side stripper is at a higher elevation than said side outlet.

### Claim 9

An apparatus for producing olefins comprising:
an oligomerization zone for oligomerizing an oligomerization feed stream to produce an oligomerate stream;
a debutanizer column in communication with said oligomerization zone at a feed inlet, said debutanizing column providing a side stream from a side outlet;
a side stripper column in communication with said side outlet of said fractionation column;
said debutanizer column in communication with an overhead line from said side stripper column at a side inlet at an elevation above said side outlet.

### Claim 10 (depends on 9)

The apparatus of claim 9 wherein said oligomerization zone is in downstream communication with said side outlet.

### Claim 11 (depends on 9)

The apparatus of claim 9 wherein said oligomerization zone is in downstream communication with a bottom line of said debutanizer column.

### Claim 12 (depends on 9)

The apparatus of claim 9 wherein an FCC zone is in downstream communication with a bottom line of said fractionation column.

### Claim 13 (depends on 9)

The apparatus of claim 9 wherein a gasoline tank or a gasoline blending line is in communication with a bottom line of said fractionation column.

### Claim 14 (depends on 9)

The apparatus of claim 9 wherein a distillate separator column is in communication with a bottom line of said fractionation column.

### Claim 15 (depends on 9)

The apparatus of claim 9 wherein said feed inlet to said fractionation column is at a lower elevation than a feed inlet from said overhead line from said side stripper.

### Claim 16

An apparatus for producing olefins comprising:
an oligomerization zone for oligomerizing an oligomerization feed stream to produce an oligomerate stream;
a debutanizer column in communication with said oligomerization zone at a feed inlet, said debutanizer column providing a side stream from a side outlet;
a side stripper column in communication with said side outlet of said fractionation column;
said debutanizer column in communication with an overhead line from said side stripper column at a side inlet at an elevation above said side outlet.

### Claim 17 (depends on 16)

The apparatus of claim 16 wherein said oligomerization zone is in downstream communication with said side outlet.

### Claim 18 (depends on 16)

The apparatus of claim 16 wherein said oligomerization zone is in downstream communication with a bottom line of said debutanizer column.

### Claim 19 (depends on 16)

The apparatus of claim 16 wherein an FCC zone is in downstream communication with a bottom line of said fractionation column.

### Claim 20 (depends on 16)

The apparatus of claim 16 wherein a gasoline tank or a gasoline blending line is in communication with a bottom line of said fractionation column.
