# US 9,434,815 B2 · Method for making carbon nanotube composite structure > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 9,434,815 B2 - Document ID: US9434815B2 - Status: Granted - Kind: B2 - Application number: 14/261,562 - Filed: 2014-04-25 - Published: 2015-07-23 - Granted: 2016-09-06 - Earliest claimed: 2014-01-22 - Assignees: Tsinghua University; Hon Hai Precision Industry Co., Ltd. - Applicants: Tsinghua University; Hon Hai Precision Industry Co., Ltd. - Inventors: Yan-Li Yin; Chang-Hong Liu; Shou-Shan Fan - Web page: https://patentgrep.com/patent/US9434815B2 ## CPC - C08G 73/0266: {Polyanilines or derivatives thereof} - C01B 32/168: After-treatment - C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS - C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C} ## Abstract A method for making a carbon nanotube composite structure includes suspending a carbon nanotube layer in a reactor. A polymer monomer solution and an oxidant solution are gasified by a pressure to form polymer monomer solution gas and oxidant solution gas. The polymer monomer solution gas is polymerized and chemically bonded to the carbon nanotube layer in initiation of the oxidant solution gas. ## Claims ### Claim 1 A method for making a carbon nanotube composite structure comprising: providing a polymer monomer solution and an oxidant solution formed by dissolving an oxidant in a solvent; gasifying the polymer monomer solution and the oxidant solution to form a polymer monomer solution gas and an oxidant solution gas by a pressure; and suspending a carbon nanotube layer comprising a plurality of carbon nanotubes combined by van der Waals attractive force in the polymer monomer solution gas and the oxidant solution gas. ### Claim 2 (depends on 1) The method of claim 1, comprising suspending the carbon nanotube layer in a reactor by two separate supporters or a ring shaped substrate. ### Claim 3 (depends on 2) The method of claim 2, wherein the carbon nanotube layer is perpendicular to a lower sidewall and parallel to two sidewalls of the reactor. ### Claim 4 (depends on 1) The method of claim 1, wherein the carbon nanotube layer comprises at least one drawn carbon nanotube film, at least one flocculated carbon nanotube film, or at least one pressed carbon nanotube film. ### Claim 5 (depends on 1) The method of claim 1, wherein the carbon nanotube layer comprises two drawn carbon nanotube films comprising the plurality of carbon nanotubes, and an angle between aligned directions of the plurality of carbon nanotubes in the two drawn carbon nanotube films is in a range from about 0 degrees to about 90 degrees. ### Claim 6 (depends on 1) The method of claim 1, comprising providing the polymer monomer solution in a first vessel located on upside of a first pipe and connected to the first pipe, and making the polymer monomer solution flow into the first pipe from the first vessel. ### Claim 7 (depends on 6) The method of claim 6, comprising applying the pressure so that the polymer monomer solution in the first pipe become the polymer monomer solution gas, and directing the polymer monomer solution gas into a reactor connected to the first pipe. ### Claim 8 (depends on 1) The method of claim 1, wherein the oxidant solution is in a second vessel located on upside of a second pipe and connected to the second pipe, and the oxidant solution flow into the second pipe from the second vessel. ### Claim 9 (depends on 8) The method of claim 8, comprising applying the pressure so that the oxidant solution in the second pipe become the oxidant solution gas, and directing the oxidant solution gas into a reactor connected to the second pipe. ### Claim 10 (depends on 1) The method of claim 1, wherein the pressure is provided by a compressed air source or ultrasonic generator. ### Claim 11 (depends on 1) The method of claim 1, wherein the pressure is applied so that a flow speed of the polymer monomer solution gas and the oxidant solution gas is in a range from about 25 sccm to about 50 sccm, and the pressure is applied for from about 0.5 minutes to about 15 minutes. ### Claim 12 (depends on 1) The method of claim 1, wherein the polymer monomer solution is aniline solution, and the oxidant solution is ammonium persulphate solution. ### Claim 13 (depends on 12) The method of claim 12, wherein the pressure is applied so that a flow speed of aniline solution gas and ammonium persulphate solution gas is in a range from about 30 sccm to about 40 sccm, and the pressure is applied for from about 1 minute to about 4 minutes. ### Claim 14 (depends on 1) The method of claim 1, wherein the polymer monomer solution gas is polymerized and chemically bonded to each of the plurality of carbon nanotubes by covalent bond. ### Claim 15 A method for making a carbon nanotube composite structure comprising: gasifying a polymer solution to form a polymer solution gas by a pressure; and suspending a carbon nanotube layer comprising a plurality of carbon nanotubes joined end-to-end by van der Waals attractive force and arranged approximately along a same direction in the polymer solution gas. ### Claim 16 (depends on 15) The method of claim 15, wherein the polymer solution is in a first vessel located on upside of a first pipe and connected to the first pipe, and the polymer solution flow into the first pipe from the first vessel. ### Claim 17 (depends on 16) The method of claim 16, comprising applying the pressure so that the polymer solution in the first pipe become the polymer solution gas, and directing the polymer solution gas into a reactor connected to the first pipe. ### Claim 18 (depends on 15) The method of claim 15, wherein the pressure is provided by a compressed air source or ultrasonic generator. ### Claim 19 A method for making a carbon nanotube composite structure comprising: suspending a carbon nanotube layer comprising a plurality of carbon nanotubes parallel to a surface of the carbon nanotube layer in a reactor; and gasifying a polymer monomer solution and an oxidant solution to form a polymer monomer solution gas and an oxidant solution gas by a pressure, and filling the reactor with the polymer monomer solution gas and the oxidant solution gas, wherein the oxidant solution is formed by dissolving an oxidant in a solvent.