# US 9,433,917 B2 · Alkylation unit and process > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 9,433,917 B2 - Document ID: US9433917B2 - Status: Granted - Kind: B2 - Application number: 14/669,435 - Filed: 2015-03-26 - Published: 2015-07-16 - Granted: 2016-09-06 - Earliest claimed: 2013-05-10 - Assignees: Uop LLC - Applicants: Uop LLC - Inventors: Mark L. Gravley; Martyn E. Pfile - Web page: https://patentgrep.com/patent/US9433917B2 ## CPC - B01J 19/245: {placed in series} - C07C 2/58: Catalytic processes - B01J 2219/00051: Controlling the temperature - B01J 2219/24: Stationary reactors without moving elements inside - C07C 2527/1206: Hydrogen fluoride - B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS - C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS ## Abstract A process for producing alkylated hydrocarbons includes the steps of: (a) combining a first feed stream comprising an olefin and an isoparaffin with an alkylation catalyst stream in a first alkylation reactor, (b) removing heat of reaction from the first alkylation reactor, (c) passing an effluent of the first alkylation reactor to a first reaction zone of a second alkylation reactor operating adiabatically to thereby form a first reaction zone effluent, (d) passing the first reaction zone effluent to a second reaction zone of the second alkylation reactor for mixture with a second feed stream comprising an olefin and an isoparaffin, and (e) passing an effluent of the second alkylation reactor to a settler for separation into a hydrocarbon stream and an alkylation catalyst effluent stream. An alkylation unit for carrying out the process is also disclosed. ## Claims ### Claim 1 An alkylation unit comprising: an olefin source in fluid communication with a first isoparaffin-olefin admixture conduit and a second isoparaffin-olefin admixture conduit; an isoparaffin source in fluid communication with the first isoparaffin-olefin admixture conduit and the second isoparaffin-olefin admixture conduit; a first alkylation reactor in fluid communication with the first isoparaffin-olefin admixture conduit and an alkylation catalyst feed conduit supplying an alkylation catalyst, the first alkylation reactor including a heat transfer device for removing heat of reaction from the first alkylation reactor; a second alkylation reactor having a plurality of reaction zones, a first reaction zone of the plurality of reaction zones being in fluid communication with the first alkylation reactor for receiving an effluent of the first alkylation reactor, a second reaction zone of the plurality of reaction zones being in fluid communication with the first reaction zone for receiving a first reaction zone effluent, the second reaction zone of the plurality of reaction zones also being in fluid communication with the second isoparaffin-olefin admixture conduit; and a settler in fluid communication with the second alkylation reactor, the settler receiving an effluent of the second alkylation reactor, the settler separating the effluent of the second alkylation reactor into a hydrocarbon stream and an alkylation catalyst effluent stream. ### Claim 2 (depends on 1) The alkylation unit of claim 1 further comprising a fractionation unit in fluid communication with the settler, the fractionation unit receiving the hydrocarbon stream from the settler and separating the hydrocarbon stream into an alkylate stream and an isoparaffin recycle stream in fluid communication with the first and second isoparaffin-olefin admixture conduit. ### Claim 3 (depends on 1) The alkylation unit of claim 1 wherein a ratio of isoparaffin to olefin in terms of total flow rate in the first isoparaffin-olefin admixture conduit and the second isoparaffin-olefin admixture conduit is about 3:1 and about 1:3. ### Claim 4 (depends on 1) The alkylation unit of claim 1 wherein the first isoparaffin-olefin admixture conduit is in fluid communication with the first alkylation reactor via a plurality of inlet loci comprising four to eight inlet points longitudinally spaced intermediate ends of the first alkylation reactor. ### Claim 5 (depends on 1) The alkylation unit of claim 1, wherein the isoparaffin source comprises a C4-C5 alkane and the olefin source comprises a C3-C5 alkene. ### Claim 6 (depends on 1) The alkylation unit of claim 1 wherein the settler is in fluid communication with the first alkylation reactor, the first alkylation reactor receiving the alkylation catalyst effluent stream. ### Claim 7 (depends on 1) The alkylation unit of claim 1 wherein the second alkylation reactor is operated adiabatically. ### Claim 8 (depends on 1) The alkylation unit of claim 1 wherein the second isoparaffin-olefin admixture conduit is in fluid communication with a third isoparaffin-olefin admixture conduit; and a third reaction zone of the plurality of reaction zones of the second alkylation reactor is in fluid communication with the second reaction zone for receiving a second reaction zone effluent, the third reaction zone also being in fluid communication with the third isoparaffin-olefin admixture conduit. ### Claim 9 (depends on 1) The alkylation unit of claim 1 wherein a molar ratio of isoparaffin to olefin in the first isoparaffin-olefin admixture conduit and the second isoparaffin-olefin admixture conduit is between about 5:1 and about 20:1. ### Claim 10 (depends on 1) The alkylation unit of claim 1 wherein a volume ratio of the alkylation catalyst to a first feed stream in the first isoparaffin-olefin admixture conduit is between about 1:1 and about 4:1. ### Claim 11 An alkylation unit comprising: an olefin source in fluid communication with a first isoparaffin-olefin admixture conduit and a second isoparaffin-olefin admixture conduit; an isoparaffin source in fluid communication with the first isoparaffin-olefin admixture conduit and the second isoparaffin-olefin admixture conduit; a first alkylation reactor in fluid communication with the first isoparaffin-olefin admixture conduit and an alkylation catalyst feed conduit supplying an alkylation catalyst, the first alkylation reactor including a heat transfer device for removing heat of reaction from the first alkylation reactor, wherein the first isoparaffin-olefin admixture conduit is in fluid communication with the first alkylation reactor via a plurality of inlet loci comprising four to eight inlet points longitudinally spaced intermediate ends of the first alkylation reactor; a second alkylation reactor having a plurality of reaction zones, a first reaction zone of the plurality of reaction zones being in fluid communication with the first alkylation reactor for receiving an effluent of the first alkylation reactor, a second reaction zone of the plurality of reaction zones being in fluid communication with the first reaction zone for receiving a first reaction zone effluent, the second reaction zone of the plurality of reaction zones also being in fluid communication with the second isoparaffin-olefin admixture conduit; and a settler in fluid communication with the second alkylation reactor, the settler receiving an effluent of the second alkylation reactor, the settler separating the effluent of the second alkylation reactor into a hydrocarbon stream and an alkylation catalyst effluent stream. ### Claim 12 (depends on 11) The alkylation unit of claim 11 further comprising a fractionation unit in fluid communication with the settler, the fractionation unit receiving the hydrocarbon stream from the settler and separating the hydrocarbon stream into an alkylate stream and an isoparaffin recycle stream in fluid communication with the first and second isoparaffin-olefin admixture conduit.