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US 9,431,649 B2Granted
Coated electroactive materials
AssigneeUchicago Argonne, LLC
InventorsKhalil Amine, Ali Abouimrane
Life of this patent
Estimating the term…
Abstract
A process includes suspending an electroactive material in a solvent, suspending or dissolving a carbon precursor in the solvent; and depositing the carbon precursor on the electroactive material to form a carbon-coated electroactive material. Compositions include a graphene-coated electroactive material prepared from a solution phase mixture or suspension of an electroactive material and graphene, graphene oxide, or a mixture thereof.
Claims16
A process comprising:
- suspending an electroactive material in a solvent;
- dissolving a carbon precursor in the solvent;
- and
- depositing the carbon precursor on the electroactive material to form a carbon-coated electroactive material, wherein the carbon coating is present from about 0.001 wt % to about 55 wt % based on the weight of the electroactive material;
- wherein:
- the electroactive material is a positive electroactive material or a negative electrode material;
- the positive electrode material is selected from the group consisting of a spinel, a olivine, LiFePO4, LiMnPO4, LiCoPO4, LiNiPO4, LiCoO2, LiNiO2, LiNi1−xCoyMetzO2, LiMn0.5Ni0.5O2, LiMn0.3Co0.3Ni0.3O2, LiMn2O4, LiFeO2, LiMet0.5Mn1.5O4, Li1+x′NiαMnβCoγMet′δO2−z′Fz′, An′B2(XO4)3, vanadium oxide, and a mixture of any two or more thereof;
- wherein:
- Met is Al, Mg, Ti, B, Ga, Si, Mn, or Co;
- Met′ is Mg, Zn, Al, Ga, B, Zr, or Ti;
- A is Li, Ag, Cu, Na, Mn, Fe, Co, Ni, Cu, or Zn;
- B is Ti, V, Cr, Fe, or Zr;
- X is P, S, Si, W, or Mo;
- 0≦x≦0.3;
- 0≦y≦0.5;
- 0≦z≦0.5;
- 0≦x′≦0.4;
- 0≦α≦1;
- 0≦β≦1;
- 0≦γ≦1;
- 0≦δ≦0.4;
- 0≦z′≦0.4;
- and 0≦n′≦3;
- and
- the negative electroactive material is selected from the group consisting of Li4Ti5O12, TiO2, metal nitrides, metal phosphides, metal oxides, lithium metal oxides, and a mixture of any two or more thereof;
- wherein the carbon precursor is selected from the group consisting of graphene, graphene oxide, carbon nano-tubes, derivatives thereof, and a combination of any two or more thereof.
23 more elements
A process comprising:
- suspending an electroactive material in a solvent selected from the group consisting of an alcohol, ether, ester, ketone, aromatic, heterocyclic, or a mixture of any two or more thereof;
- dissolving a carbon precursor in the solvent;
- and
- depositing the carbon precursor on the electroactive material to form a carbon-coated electroactive material, wherein the carbon coating is present from about 0.001 wt % to about 55 wt % based on the weight of the electroactive material;
- wherein:
- the electroactive material is a positive electroactive material or a negative electroactive material;
- the positive electroactive is selected from the group consisting of a spinel, a olivine, LiFePO4, LiMnPO4, LiCoPO4, LiNiPO4, LiCoO2, LiNiO2, LiNi1−xCoyMetzO2, LiMn0.5Ni0.5O2, LiMn0.3Co0.3Ni0.3O2, LiMn2O4, LiFeO2, LiMet0.5Mn1.5O4, LiMet0.5Mn1O4, Li1+x′NiαMnβCoγMet′δO2−zFz′, An′B2(XO4)3, vanadium oxide, and a mixture of any two or more thereof;
- wherein:
- Met is Al, Mg, Ti, B, Ga, Si, Mn, or Co;
- Met′ is Mg, Zn, Al, Ga, B, Zr, or Ti;
- A is Li, Ag, Cu, Na, Mn, Fe, Co, Ni, Cu, or Zn;
- B is Ti, V, Cr, Fe, or Zr;
- X is P, S, Si, W, or Mo;
- 0≦x≦0.3;
- 0≦y≦0.5;
- 0≦z≦0.5;
- 0≦x′≦0.4;
- 0≦α≦1;
- 0≦β≦1;
- 0≦γ≦1;
- 0≦δ≦0.4;
- 0≦z′≦0.4;
- and 0≦n′≦3 and
- the negative electroactive material is selected from the group consisting of amorphous carbon, Li4Ti5O12, TiO2, tin, tin alloys, silicon, silicon alloys, metal nitrides, metal phosphides, intermetallic compounds, metal oxide, lithium metal oxide, and a mixture of any two or more thereof.
21 more elements
Dependencies are inferred from the claim text.