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US 9,431,159 B2Granted
Iron cobalt ternary alloy nanoparticles with silica shells and metal silicate interface
AssigneeToyota Motor Engineering & Manufacturing North America, Inc.
InventorsMichael Paul Rowe, Ryan Daniel Desautels
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Abstract
Superparamagnetic core-shell nanoparticles having a core of an iron cobalt ternary alloy, a shell of a silicon oxide on the core and a metal silicate interface layer between the core and the shell layer are provided. Methods to prepare the nanoparticles are also provided.
Claims19
A core-shell nanoparticle, comprising:
- a core of an iron cobalt ternary alloy;
- a shell of a silicon oxide coating the core;
- and
- a metal silicate interface in a region between the core and the shell;
- wherein
- the third component of the ternary alloy is a transition metal selected from the group consisting of scandium, titanium, vanadium, chromium, manganese, nickel, copper and zinc,
- a particle size of the nanoparticle is from 2 to 200 nm, and
- the metal silicate of the metal silicate interface comprises at least one of iron silicate, cobalt silicate and the third component transition metal silicate.
5 more elements
Dependencies are inferred from the claim text.