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US 9,428,433 B2Granted
Control of the viscosity of reaction solutions in hydroformylation processes
AssigneeEvonik Degussa GmbH
InventorsDirk Fridag, Udo Lenz, Hans-Gerd Lueken, Robert Franke, Markus Rudek, Klaus-Diether Wiese, Soenke Broecker, Markus Priske, Christoph Patalong
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Abstract
The present invention relates to a method and a device for controlling the viscosity of reaction solutions in the hydroformylation of olefin-containing mixtures.
Claims9
A method for controlling the viscosity of reaction solutions in the hydroformylation of olefin-containing mixtures, the method comprising:
- i) contacting a mixture comprising saturated and olefinically unsaturated hydrocarbons, a composition which is catalytically active in hydroformylation, a gas mixture comprising carbon monoxide and hydrogen, and at least one solvent, in at least one reaction zone;
- ii) separating off products, with a gas stream comprising a mixture of saturated and olefinically unsaturated hydrocarbons, carbon monoxide and hydrogen being introduced into the at least one reaction zone, with the proviso that the products are discharged via a gas phase from the reaction zone;
- iii) condensing the products which have been separated off via the gas phase and passing them to further work-up;
- and
- iv) passing a bottom stream from at least one reaction zone to at least one membrane filtration,
- wherein the composition which is catalytically active in hydroformylation is retained in a retentate and recirculated to the at least one reaction zone and degradation products of the composition which are catalytically active in hydroformylation are removed via a permeate.
3 more elements
Dependencies are inferred from the claim text.