Multiple catalyst system and polymerization process for use thereof

A catalyst system comprising activator, support, catalyst compound represented by Formula I and catalyst compound represented by Formula II where:

• Formula I is
• where
• T is a bridging group;
• N is nitrogen;
• M* is Cr, Mo, or W, where M* is in a +3 oxidation state prior to contacting with activator;
• each X, is independently, selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halides, dienes, amines, phosphines, ethers, and a combination thereof, two X's optionally form a part of a fused ring or a ring system;
• each R1, R2, R3, and R4 is independently, hydrogen, a C1 to C12 hydrocarbyl, a substituted C1 to C12 hydrocarbyl, a heteroatom, or substituted heteroatom group;
• and each R5 and R6 is, independently, a C1 to C12 hydrocarbyl, a substituted C1 to C12 hydrocarbyl, a heteroatom, or substituted heteroatom group, where the R5 and R6 groups optionally form a fused ring or multicenter fused ring system where the rings are aromatic, partially saturated or saturated;
• and
• Formula II is:
• where
• M is Hf or Zr;
• z is 0 or 1;
• R1, R2, R3, R4, T and X, are as described above;
• and
• each R8, R9, R10, and R11 is, independently, hydrogen, a C1 to C12 hydrocarbyl, a substituted C1 to C12 hydrocarbyl, a heteroatom, or substituted heteroatom group.