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US 9,416,071 B2Granted
Hydrocarbon conversion processes using lactamium-based ionic liquids
AssigneeUop LLC
InventorsErin M. Broderick, Stuart Smith, Alakananda Bhattacharyya, Susie C. Martins
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Abstract
A hydrocarbon conversion process is described. The process involves contacting a hydrocarbon feed with a lactamium based ionic liquid catalyst in a reaction zone under reaction conditions to form a mixture comprising reaction products, and the lactamium based ionic liquid catalyst. Typical hydrocarbon conversion processes include alkylation, oligomerization, isomerization, disproportionation, and reverse disproportionation.
Claims20
A hydrocarbon conversion process comprising:
- contacting a hydrocarbon feed with a lactamium based ionic liquid catalyst in a hydrocarbon conversion zone under hydrocarbon conversion conditions to form a mixture comprising reaction products, and the lactamium based ionic liquid catalyst.
A hydrocarbon conversion process comprising:
- contacting a hydrocarbon feed with a lactamium based ionic liquid catalyst in a hydrocarbon conversion zone under hydrocarbon conversion conditions to form a mixture comprising conversion reaction products, and the lactamium based ionic liquid catalyst, wherein the hydrocarbon conversion processes comprises at least one of alkylation, oligomerization, isomerization, disproportionation, and reverse disproportionation;
- separating the conversion reaction products from the lactamium based ionic liquid catalyst;
- recovering the conversion reaction products;
- and
- recycling the lactamium based ionic liquid to the reaction zone;
- wherein the lactamium based ionic liquid catalyst comprises at least one of:
- a reaction product of a lactam compound having a general formula
- wherein R is hydrogen, an alkyl group having from 1 to 12 carbon atoms, an amine, an ether, or a silyl group, n is 1 to 8;
- and a Brønsted acid HX;
- or a Brønsted acid HX, where X is a halide, and a metal halide;
- or
- a reaction product of a lactam compound having a general formula
- wherein the ring has at least one C≡C double bond, R is hydrogen, an alkyl group having from 1 to 12 carbon atoms, an amine, an ether, or a silyl group, n is 1 to 8;
- and a Brønsted acid HX;
- or a Brønsted acid HX, where X is a halide, and a metal halide;
- or
- a reaction product of a lactam compound having a general formula
- wherein R is hydrogen, an alkyl group having from 1 to 12 carbon atoms, an amine, an ether, or a silyl group, n is 1 to 8, m is 1 to 8, and the rings can be saturated or unsaturated;
- and a Brønsted acid HX;
- or a Brønsted acid HX, where X is a halide, and a metal halide.
17 more elements
Dependencies are inferred from the claim text.