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US 9,403,848 B2Granted
Organometallic catalyst complex and polymerization method employing same
AssigneeBridgestone Corporation
InventorsSteven Luo, Zengquan Qin
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Abstract
A novel class of organometallic complexes can be used as an ingredient of a catalyst system. The catalyst system can be used in polymerizations of ethylenically unsaturated hydrocarbon monomers that include both olefins and polyenes.
Claims20
A process for providing a polymer, said process comprising contacting one or more ethylenically unsaturated hydrocarbon compounds with a catalyst composition that comprises a complex having the general formula
- where
- M represents a Group 3 metal atom;
- L represents a neutral Lewis base;
- z is an integer of from 0 to 2 inclusive;
- R1 is H or a monovalent organic group;
- each R2 is H, a halogen atom, or a monovalent organic group;
- each R3 independently is H, a halogen atom, a hydrocarbyl group, a hydrocarbyloxy group, a hydrocarbylthio group, a dihydrocarbylamino group, a disilylamino group, or a dihydrocarbylphosphino group;
- Q is a —N(CH3)2 group;
- and
- R4 is a divalent organic group,
- with the proviso that either or both of the following can be true:
- (1) two R2 groups can join so as to provide a substituted or unsubstituted hydrocarbylene group and (2) Rl can join with an R2 so as to provide a substituted or unsubstituted hydrocarbylene group, wherein said one or more ethylenically unsaturated hydrocarbon compounds comprise at least one polyene, said polymer constituting the polymerization product of said compounds.
9 more elements
Dependencies are inferred from the claim text.