Core-sheath composite fiber and method for producing same
AssigneeToray Industries, Inc.
InventorsJunichi Mizota, Takashi Ida, Hidetoshi Takanaga
Life of this patent
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Abstract
A core-sheath composite fiber includes a core component including an easily alkaline elutable polyester with a main repeating unit constructed of ethylene terephthalate containing 2.0 to 5.5 mol % of an isophthalic acid component containing a metal sulfonate group relative to a total acid component and 3.0 to 6.0 mol % of an adipic acid component relative to the total acid component, and a sheath component including a polyamide.
Claims16
A core-sheath composite fiber comprising a core component comprising an easily alkaline elutable polyester with a main repeating unit constructed of ethylene terephthalate containing 2.0 to 5.5 mol % of an isophthalic acid component containing a metal sulfonate group relative to a total acid component and 3.0 to 6.0 mol % of an adipic acid component relative to the total acid component, and a sheath component comprising a polyamide, wherein the easily alkaline elutable polyester and the polyamide react in an ester-amide exchange reaction at an interface of the easily alkaline elutable polyester and the polyamide and a unit reaction rate of a terephthalic acid that caused the ester-amide exchange reaction is 0.0005 to 0.0025%·mm, wherein the unit reaction rate is calculated from Equation (1):
- A(%·mm)=T/S (1)
- where A is the unit reaction rate, T is the reaction rate (%) of the terephthalic acid that caused the ester-amide exchange reaction, and S is the surface area of the core of the fiber axis portion per 1 mm3 of the core-sheath type composite section fiber (mm2/mm3);
- and
- wherein the S is calculated from Equation (2):
- S(mm2/mm3)=X(mm)×Y(mm/mm3)×correction coefficient (2)
- where (a) Core portion's circumference length (mm):
- X,
- (b) Fiber length (mm) for unit volume (1 mm3):
- Y (mm/mm3),
- (c) Correction coefficient=fiber diameter (calculated value)/fiber diameter (actually measured value);
- Y(mm/mm3)=1±fiber sectional area(calculated value);
- Fiber sectional area(mm2)=[fiber diameter(calculated value)/2]2×π;
- Fiber diameter(calculated value)(mm)=11.28×√(single yarn fineness degree/specific gravity of core-sheath composite fiber)×10−3;
- and
- Specific gravity of core-sheath composite fiber(g/cm3)specific gravity of core polymer×ratio of core+specific gravity of sheath polymer×ratio of sheath.
Dependencies are inferred from the claim text.