Method for separating lignin from black liquor, a lignin product, and use of a lignin product for the production of fuels or materials
AssigneeValmet Aktiebolag
InventorsFredrik Ohman, Hans Theliander, Per Tomani, Peter Axegard
Life of this patent
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Abstract
The method is for controlling a sodium and sulphur balance of a pulp mill while separating lignin from black liquor. Lignin is precipitated by using an acid followed by filtration. The lignin filter cake thus obtained is re-suspended in acidic liquid and dewatered to form a second cake. The filtrate obtained after dewatering of the second cake is returned for washing and suspension of the first cake. Sodium sulphate-rich ESP (electrostatic precipitator) dust produced in the recovery boiler is used in the washing of the precipitated lignin cake.
Claims12
A method for separation of lignin from black liquor, comprising:
- precipitating lignin by acidifying black liquor with carbon dioxide resulting in a first lignin suspension;
- separation to form a lignin cake of a solid material of a first filter cake and a first filtrate,
- suspending the first filter cake to obtain a second lignin suspension,
- separating the second lignin suspension to form a second lignin cake of a solid material of the second filter cake and a second filtrate,
- adding a washing liquid for displacement washing of the second filter cake,
- enhancing a dryness of the second filter cake,
- obtaining filtrate from the displacement washing, the filtrate forming a part of the second filtrate,
- increasing an ionic strength by adding recovery boiler precipitator dust to at least a first portion of the second filtrate and adjusting the pH of the second filtrate to a value below 6,
- washing the first filter cake with the first portion of the second filtrate,
- the recovery boiler precipitator dust of the second filtrate keeping lignin in the first filter cake in solid form, and
- sending the first portion of the second filtrate to recovery after use as washing liquid, and
- adding a second portion of the second filtrate to the washed first filter cake to form the second lignin suspension, adjusting the pH level of the second lignin suspension to a value below 6 and approximately the pH level of the washing liquid added to the second filter cake.
Dependencies are inferred from the claim text.