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US 9,376,559 B2Granted
Reverse staged impact copolymers
AssigneeExxonMobil Chemical Patents Inc.
InventorsMatthew W. Holtcamp, Laughlin G. McCullough, Celestino M. Perez, Jr., Sarah J. Mattler
Life of this patent
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Abstract
This invention relates to processes to prepare impact copolymers having an ethylene content of greater than 20 wt % using a process where ethylene polymer is made in the first stage and propylene polymer is made in the second stage.
Claims22
A process for producing ethylene-based in-reactor compositions comprising:
- a) contacting ethylene and optionally a C3 to a C12 alpha-olefin comonomer under polymerization conditions in a first stage in the presence of a first metallocene catalyst system to form Component A;
- b) contacting Component A of step (a) with a C3 to a C12 alpha-olefin monomer under polymerization conditions in a second stage in the presence of a second metallocene catalyst system to form Component B, wherein the first metallocene catalyst system is present in both steps a and b and/or additional metallocene catalyst is added to the reaction mixture between steps a and b and the first metallocene catalyst system may be the same as the second metallocene catalyst system;
- and
- c) obtaining an ethylene-based in-reactor composition comprising Component A and Component B, wherein the ethylene-based in-reactor composition has from greater than 20% to about 85% of ethylene on a mole percentage basis and wherein the polymer composition has a multimodal melting point.
1 more element
Dependencies are inferred from the claim text.